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rose absolute (rosa damascena) bulgaria

Rose absolute (Rosa damascena) Bulgaria is a fragrant concentrate derived from Rosa damascena flowers, used in flavor and fragrance applications for its floral aroma.

General Material Description

Rose absolute (Rosa damascena) Bulgaria is a natural aroma concentrate obtained from the petals of the Rosa damascena flower. This absolute typically appears as a rich, viscous liquid possessing a pronounced floral scent distinguished by waxy, honeyed, spicy, green, and occasionally metallic undertones according to sensory evaluations. Known by numerous synonyms including rose otto and attar of rose, this absolute is widely valued in perfumery and flavor formulations. The chemical composition contains complex mixtures of aromatic compounds, and it is soluble in alcohol but not in water, enhancing its versatility in various carriers. For detailed chemical information, see the PubChem entry. It is primarily sourced from Rosa damascena flowers cultivated in Bulgaria, renowned for their fragrance profile. The absolute is obtained through solvent extraction methods, yielding a concentrated essence used extensively in the flavor and fragrance industries.

Occurrence, Applicability & Potential Uses

Rose absolute originates from the Rosa damascena flower, commonly cultivated in Bulgaria, which provides optimal climatic conditions for its aromatic qualities. This absolute finds broad applicability as a flavor and fragrance agent in perfumery, cosmetics, and flavorings due to its distinctive floral aroma. It is employed in a range of products to impart rose, floral, sweet, spicy, and green notes, blending well with accords such as amber, jasmine, vanilla, and patchouli. Notable perfumes incorporating this absolute include classics like Chanel #5 and Shalimar. In regulatory terms, its usage is governed by standards such as IFRA (Global), which restricts certain constituents like methyl eugenol for safety reasons. The permitted concentration in fragrance concentrates typically does not exceed 5%, ensuring compliance with cosmetic and flavoring safety guidelines.

Physico-Chemical Properties Summary

Rose absolute exhibits physical properties typical of aromatic solvent-extracted absolutes, with a specific gravity ranging from 0.94 to 0.986 at 25 °C and a refractive index between 1.5 and 1.56 at 20 °C, reflecting its dense and viscous nature. Its flash point is measured at approximately 83 °C (183 °F), indicating moderate flammability. The absolute is soluble in alcohol and has limited solubility in water (estimated 255.8 mg/L at 25 °C), which affects formulation strategies, favoring alcoholic or oil-based carriers. It maintains stability without discoloration in various media, including powders, lotions, and lipsticks when stored in cool, dry, and light-protected environments. The shelf life under appropriate conditions extends beyond 24 months, supporting its long-term use in formulations.

FAQ

What is rose absolute (Rosa damascena) Bulgaria?
Rose absolute (Rosa damascena) Bulgaria is a concentrated natural aroma derived from the petals of the Rosa damascena flower, primarily grown in Bulgaria. It is obtained through solvent extraction processes, resulting in a viscous liquid with a rich floral scent characterized by waxy, honey, spicy, and green notes. This absolute is widely used in flavor and fragrance applications to impart rose and floral aromas. It is also known by various names such as rose otto, attar of rose, and oil of rose.
How is rose absolute produced and where is it commonly used?
The production of rose absolute involves the solvent extraction of fresh Rosa damascena flowers, capturing the complex essential aromatic compounds that define its scent profile. The flowers are predominantly cultivated in Bulgaria, a region renowned for cultivating highly fragrant roses suited for this purpose. Rose absolute serves as a critical ingredient in perfumery and flavor formulations, where it enhances compositions with its floral and slightly spicy aroma. It blends harmoniously with other fragrance notes like jasmine, vanilla, and patchouli and appears in classic perfumes such as Chanel #5 and Shalimar. Due to its solubility in alcohol and resistance to discoloration, it is suitable for incorporation into various product types.
What safety and regulatory considerations apply to the use of rose absolute?
Rose absolute is subject to safety assessments and regulatory standards such as those from IFRA (International Fragrance Association, Global), which limit concentrations of certain constituents like methyl eugenol due to potential sensitization and carcinogenic concerns identified in animal studies. Usage in fragrance concentrates is typically restricted to a maximum of 5%. The material is classified as a combustible liquid with mild skin and eye irritant properties and requires appropriate handling measures including wearing protective gloves and eye protection. It has defined toxicological parameters such as oral and dermal LD50 values in animal studies and should be stored in cool, well-ventilated areas away from heat sources. Manufacturers and formulators consult safety dossiers such as those from RIFM and FEMA (US) for compliance and safe usage guidance.

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Other Information

FDA Substances Added to Food (formerly EAFUS):View
Export Tariff Code:3301.90.5000
Wikipedia:View

General Material Information

Trivial Name rose absolute (rosa damascena) bulgaria
Short Description rosa damascena flower absolute bulgaria
CAS Number 8007-01-0
FEMA Number 2988
FDA UNII Search
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 977091-93-2 ; ROSE, ABSOLUTE (ROSA SPP.)
Synonyms
  • rosa damascena flower absolute bulgaria
  • rose abs bulgarian low methyl eugenol
  • rose absolue, damascena bulgaria
  • rose absolute bulgaria
  • rose absolute bulgarian
  • rose absolute MD
  • rose bulgaria absolute
  • rose bulgarian absolute
  • rose concentred abs T 23/45 (Charabot)
  • rose low methyl eugenol absolute
  • rosa damascena mill. flower absolute
  • Oils, rose
  • Attar of rose
  • Attar rose
  • Essence of rose
  • Oil of rose
  • Otto of rose
  • Otto rose
  • Rosenol
  • Rose oil
  • Rose otto
  • Oils, rosaceae
  • Oil of rose blossom
  • Rose de grasse
  • Rose de mai
  • Rosa centifolia oil

PhysChem Properties

Material listed in food chemical codex No
Specific gravity @ 25 °C
Pounds per Gallon 7.822 to 8.205
Refractive Index 1.5 to 1.56 @ 20 °C
Flash Point TCC Value 83.89 °C TCC
Shelf life 24 months (or longer if stored properly.)
Storage notes Store in cool, dry place in tightly sealed containers, protected from heat and light.
Solubility
alcohol Yes
water, 255.8 mg/L @ 25 °C (est) Yes
water No
Stability
lipstick Unspecified
lotion Unspecified
non-discoloring in most media Unspecified
powder Unspecified

Organoleptic Properties

Odor Type: Floral
floral, rose, waxy, honey, spicy, green, cortex, geranium, metallic
Odor strength medium
Substantivity 168 hour(s) at 100.00 %
Luebke, William tgsc, (1983) At 100.00 %. floral rose waxy honey spicy green cortex geranium metallic
Flavor Type: Floral
floral, green, spicy, waxy, honey, fatty, metallic, tropical
Luebke, William tgsc, (1983) Floral green spicy waxy honey fatty metallic tropical
General comment Floral green spicy waxy honey fatty metallic tropical

Occurrences

Safety Information

Safety information

European information :
Most important hazard(s):
Xn - Harmful.
R 21/22 - Harmful in contact with skin and if swallowed.
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 - Wear suitable gloves and eye/face protection.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Flammable liquids (Category 4), H227
GHS Label elements, including precautionary statements
Pictogramexclamation-mark.jpg
Signal word Warning
Hazard statement(s)
H227 - Combustible liquid
H303 - May be harmfulif swallowed
H313 - May be harmful in contact with skin
H316 - Causes mild skin irritation
Precautionary statement(s)
P233 - Keep container tightly closed.
P264 - Wash skin thouroughly after handling.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P403 + P235 - Store in a well-ventilated place. Keep cool.
P501 - Dispose of contents/ container to an approved waste disposal plant.
Oral/Parenteral Toxicity:
intraperitoneal-rat LD50 1045 mg/kg
MBI, Mediko Biologicheskaya Informatsiya. Medical-Biological Information. Vol. (3), Pg. 8, 1988.

oral-rat LD50 2975 mg/kg
BEHAVIORAL: COMA SENSE ORGANS AND SPECIAL SENSES: PTOSIS: EYE LUNGS, THORAX, OR RESPIRATION: CYANOSIS
MBI, Mediko Biologicheskaya Informatsiya. Medical-Biological Information. Vol. (3), Pg. 8, 1988.

Dermal Toxicity:
skin-rabbit LD50 2500 mg/kg
Food and Cosmetics Toxicology. Vol. 12, Pg. 979, 1974.

Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
methyl eugenol Max. Found: 0.5 % and Reason: Potential carcinogenic activity in animals
eugenol Max. Found: 2.3 % and Reason: Sensitization
citronellol Max. Found: 6.00 % and Reason: Sensitization
farnesol Max. Found:
geraniol Max. Found: 5.00 % and Reason: Sensitization
benzaldehyde Max. Found: 1.00 % and Reason: Sensitization
benzyl alcohol Max. Found: 0.1 % and Reason: Sensitization
citral Max. Found: 0.05 % and Reason: Sensitization
farnesal Max. Found: 0.01 % and Reason: Sensitization
Recommendation for rose absolute (rosa damascena) bulgaria usage levels up to:
5.0000 % in the fragrance concentrate.
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -1.60000
beverages(nonalcoholic): -0.63000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -1.20000
fruit ices: -1.20000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -2.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

EPI System: View
ClinicalTrials.gov:search
Daily Med:search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):8007-01-0
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
rosa damascena mill. flower absolute
Chemidplus:0008007010
RTECS:VL0457000 for cas# 8007-01-0