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cassia leaf oil

Cassia leaf oil is a steam-distilled essential oil from cinnamomum cassia leaves and twigs, noted for its spicy cinnamon scent used in flavoring and perfumery.

General Material Description

Cassia leaf oil is a volatile essential oil obtained by steam distillation from the leaves and twigs of the Chinese cinnamon plant, Cinnamomum cassia (L.), belonging to the Lauraceae family. It appears as a pale yellow to reddish-brown liquid with a potent spicy cinnamon scent characterized by woody, sweet, and cinnamon spicy notes. This oil is known under various synonyms including camphorina cassia leaf oil, cinnamon leaf oil (cinnamomum cassia), and oil of Chinese cinnamon. The scent profile makes it valuable in both flavor and fragrance industries. Detailed compositional data for cassia leaf oil is catalogued in controlled-vocabulary databases such as PubChem. Due to its natural extraction through steam distillation, it reflects the aromatic quality inherent to the plant source and is widely used as a natural flavoring and fragrance ingredient.

Occurrence, Applicability & Potential Uses

Cassia leaf oil originates from the leaves and twigs of the cassia tree, primarily Cinnamomum cassia, found in subtropical regions such as China. Its biological occurrence is linked to the aromatic components present in this tree species. Due to its intense spicy cinnamon aroma, the oil is applied extensively as a flavoring agent in food products and as a fragrance component in perfumery and cosmetics. It serves various odor purposes including as a replacement for benzoin absolute and for notes resembling almond, carnation, sandalwood, and musk. Its use also extends into creating complex bouquets and enhancing woody or herbal scent accords. Under the IFRA (Global) standards, usage levels are regulated to mitigate sensitization risks, particularly due to constituents like cinnamaldehyde. These regulations inform safe formulation limits both in fragrance concentrates and flavor applications.

Physico-Chemical Properties Summary

Cassia leaf oil exhibits physical properties that influence its handling and formulation. At 25 °C, its specific gravity ranges between 1.045 and 1.063, indicating a density slightly greater than water, while its refractive index at 20 °C varies from 1.602 to 1.614. The oil is soluble in alcohol and fixed oils but shows limited solubility in water, approximately 2150 mg/L at 25 °C. Its flash point, determined by the tag closed cup method, is 194 °F (about 90 °C), signalling moderate volatility. These properties necessitate careful consideration in blending and storage. Its strong odor intensity, with a substantivity around 160 hours at 100%, lends durability in fragrance compositions. The oil's chemical profile includes components responsible for its spicy cinnamon character, which must be considered for both sensory impact and safety in product development.

FAQ

What is cassia leaf oil and how is it obtained?
Cassia leaf oil is an essential oil extracted predominantly by steam distillation from the leaves and twigs of the Cinnamomum cassia tree, commonly known as Chinese cinnamon. The process involves passing steam through the plant material, vaporizing volatile constituents which are then condensed back to liquid form. The resulting oil contains a characteristic spicy cinnamon aroma with woody and sweet notes. It is used widely for its fragrance and flavor properties.
Where does cassia leaf oil naturally occur and what are its main applications?
Cassia leaf oil naturally occurs in the leaves and twigs of the cassia tree native to subtropical regions of Asia, especially China. It finds applications primarily as a flavoring agent in food and beverage products and as a fragrance ingredient in perfumes, soaps, and cosmetics. Its distinctive spicy cinnamon scent is valued in odor compositions including herbal and woody notes. The oil can substitute benzoin absolute and enhances bouquets involving musk, sandalwood, or floral accords. It is used in both flavor and fragrance formulations under standards such as IFRA (Global).
What safety considerations and regulations apply to cassia leaf oil usage?
Cassia leaf oil is classified as toxic and can cause skin sensitization and irritation to eyes and respiratory systems based on European safety information. Toxicity studies indicate moderate oral and dermal toxicity in animal models. Regulatory frameworks like IFRA (Global) provide guidelines limiting cassia leaf oil to a maximum of 5% in fragrance concentrates and 25 ppm in finished flavor products to reduce sensitization risk, mainly due to constituents such as cinnamaldehyde. Appropriate handling measures include avoiding skin and eye contact, and usage should comply with published safety standards and fragrance material assessments.

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Other Information

FDA Substances Added to Food (formerly EAFUS):View
Export Tariff Code:3301.29.6000
Typical G.C.
Wikipedia:View
FAO:BASIC PRINCIPLES OF STEAM DISTILLATION
FAO:CINNAMOMUM OILS (INCLUDING CINNAMON AND CASSIA)

General Material Information

Preferred name cassia leaf oil
Trivial Name Essential oils, cassia
Short Description volatile oil obtained by steam distillation from the leaves and twigs of the chinese cinnamom, cinnamomum cassia (l.), lauraceae
CAS Number 8007-80-5
FDA UNII A4WO0626T5
MDL MFCD00130805
COE Number 131
FDA Mainterm 8007-80-5 ; CINNAMON BARK, OIL (CINNAMOMUM SPP.)
Synonyms
  • camphorina cassia leaf oil
  • cinnamomum aromaticum leaf oil
  • cinnamomum cassia leaf oil
  • cinnamomum longifolium leaf oil
  • cinnamomum medium leaf oil
  • cinnamomum nitidum leaf oil
  • cinnamon leaf oil (cinnamomum cassia)
  • laurus cassia leaf oil
  • persea cassia leaf oil
  • volatile oil obtained by steam distillation from the leaves and twigs of the chinese cinnamom, cinnamomum cassia (l.), lauraceae
  • cinnamomum cassia blume leaf oil
  • Essential oils, cassia
  • Cassia oil
  • Oil of cassia
  • Oils, cassia
  • Oils, essential, cassia
  • Cinnamomum cassia, essential oil
  • Oil of Chinese cinnamon
  • Cassia oils
  • Cinnamomum cassia oil
  • Chinese cinnamon oil
  • Oils, Chinese cinnamon
  • Cinnamomum cassia bark oil
  • Cinnamomum cassia twig oil
  • Cassia bark oil

PhysChem Properties

Material listed in food chemical codex No
Specific gravity @ 25 °C
Pounds per Gallon 8.695 to 8.845
Refractive Index 1.602 to 1.614 @ 20 °C
Flash Point TCC Value 90 °C TCC
Solubility
alcohol Yes
fixed oils Yes
water, 2150 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Spicy
woody, sweet, cinnamon, spicy
Odor strength high , recommend smelling in a 10.00 % solution or less
Substantivity 160 hour(s) at 100.00 %
Luebke, William tgsc, (1987) At 10.00 % in dipropylene glycol. woody sweet cinnamon spicy
Flavor Type: Spicy
cinnamon
General comment Cinnamon

Occurrences

Safety Information

Safety information

European information :
Most important hazard(s):
T - Toxic.
R 21 - Harmful in contact with skin.
R 24 - Toxic in contact with skin.
R 36/37 - Irritating to eyes and respiratory system.
R 43 - May cause sensitisation by skin contact.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 2800 mg/kg
Food and Cosmetics Toxicology. Vol. 13, Pg. 109, 1975.

intraperitoneal-mouse LD50 500 mg/kg
VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA
Pharmacologist. Vol. 3, Pg. 62, 1961.

oral-mouse LD50 2670 mg/kg
Tokishikoroji Foramu. Toxicology Forum. Vol. 8, Pg. 91, 1985.

Dermal Toxicity:
skin-rabbit LD50 320 mg/kg
Food and Cosmetics Toxicology. Vol. 13, Pg. 109, 1975.

Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
benzyl benzoate Max. Found:
cinnamaldehyde Max. Found: 1.5 % and Reason: Sensitization
cinnamyl alcohol Max. Found:
eugenol Max. Found:
methyl eugenol Max. Found:
benzaldehyde Max. Found:
Recommendation for cassia leaf oil usage levels up to:
5.0000 % in the fragrance concentrate.
Recommendation for cassia leaf oil flavor usage levels up to:
25.0000 ppm in the finished product.

Safety references

EPI System: View
ClinicalTrials.gov:search
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):8007-80-5
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
cinnamomum cassia blume leaf oil
Chemidplus:0008007805
RTECS:FI4050000 for cas# 8007-80-5