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bitter orange peel oil brazil
General Material Information
| Preferred name | bitter orange peel oil brazil |
| Trivial Name | Sour orange oil |
| Short Description | bitter citrus aurantium peel oil brazil |
| CAS Number | 68916-04-1 |
| FEMA Number | 2823 |
| FDA UNII | 9TLV70SV6I |
| FDA Patent | No longer provide for the use of these seven synthetic flavoring substances |
| FDA Mainterm | 68916-04-1 ; ORANGE PEEL, BITTER, OIL (CITRUS AURANTIUM L.) |
| Synonyms |
|
US / EU / FDA / JECFA / FEMA / Scholar / Patents
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Literature & References
| citrus aurantium l. peel oil bitter brazil | |
| Canada Domestic Sub. List: | 68916-04-1 |
| Pubchem (sid): | 135326045 |
Other Information
| FDA Substances Added to Food (formerly EAFUS): | View |
| Export Tariff Code: | 3301.12.0000 |
| Typical G.C. | |
| Wikipedia: | View |
| FAO: | BASIC PRINCIPLES OF STEAM DISTILLATION |
Suppliers
PhysChem Properties
| Material listed in food chemical codex | No |
| Specific gravity | @ 25 °C |
| Pounds per Gallon | 7.031 to 7.081 |
| Refractive Index | 1.469 to 1.478 @ 20 °C |
| Flash Point TCC Value | 47.78 °C TCC |
| Shelf life | 12 months (or longer if stored properly.) |
| Storage notes | Store in cool, dry place in tightly sealed containers, protected from heat and light. |
| Solubility | |
| alcohol | Yes |
| fixed oils | Yes |
| paraffin oil, slightly cloudy | Yes |
| water, 4.581 mg/L @ 25 °C (est) | Yes |
| water | No |
| Stability | |
| bath foam | Unspecified |
| hair spray | Unspecified |
| lipstick | Unspecified |
| soap | Unspecified |
Organoleptic Properties
| Odor Type: Citrus | |
| citrus, orange, dry, woody, mandarin, cognac, terpenic, aromatic, brown, fruity | |
| Odor strength | medium |
| Substantivity | 32 hour(s) at 100.00 % |
| Luebke, William tgsc, (1996) | At 100.00 %. citrus orange dry woody mandarin cognac terpenic aromatic |
| Mosciano, Gerard P&F 22, No. 2, 69, (1997) | Citrus, brown, fruity, pound cake and Madeira-like |
| Flavor Type: Fruity | |
| orange, citrus, fruity, bitter, mandarin, tangerine, cognac, woody, aromatic | |
| Luebke, William tgsc, (1996) | Orange citrus fruity bitter mandarin tangerine cognac woody aromatic |
| Mosciano, Gerard P&F 22, No. 2, 69, (1997) | At 1000.00 ppm. Bitter, fruity, Madeira, cognac and woody with aromatic nuances |
| General comment | Orange citrus fruity bitter mandarin tangerine cognac woody aromatic |
Occurrences
| (data available) |
Potential Uses
| Applications | |
| Odor purposes | Aldehydic, Amber, Bergamot, Cedrat, Citrus, Fern, Floral, Grapefruit, Green, Orange, Oriental, Violet, Woody |
| Flavoring purposes | Tea, Tonic, Wine madeira wine |
| Other purposes | Fixer, Leaf, Skin conditioning |
| Cosmetic purposes | Fragrance, Skin conditioning, Tonic |
Safety Information
Safety information
| European information : | |
| Most important hazard(s): | |
| Xi - Irritant | |
| R 10 - Flammable. R 38 - Irritating to skin. R 43 - May cause sensitisation by skin contact. S 02 - Keep out of the reach of children. S 16 - Keep away from sources of ignition - No Smoking. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 - Wear suitable gloves and eye/face protection. | |
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| Flammable liquids (Category 3), H226 Skin irritation (Category 2), H315 | |
| GHS Label elements, including precautionary statements | |
| Pictogram |   |
| Signal word | Warning |
| Hazard statement(s) | |
| H226 - Flammable liquid and vapour H315 - Causes skin irritation | |
| Precautionary statement(s) | |
| P210 - Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/…/equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P264 - Wash skin thouroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P321 - Specific treatment (see supplemental first aid instructions on this label). P332 + P313 - IF SKIN irritation occurs: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P403 + P235 - Store in a well-ventilated place. Keep cool. P501 - Dispose of contents/ container to an approved waste disposal plant. | |
| Oral/Parenteral Toxicity: | |
| oral-rat LD50 > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 12, Pg. 735, 1974. | |
| Dermal Toxicity: | |
| skin-rabbit LD50 > 10000 mg/kg Food and Cosmetics Toxicology. Vol. 12, Pg. 735, 1974. | |
| Inhalation Toxicity: | |
| Not determined | |
Safety in use information
| Category: | |||
| flavor and fragrance agents | |||
| RIFM Fragrance Material Safety Assessment: Search | |||
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
| IFRA Critical Effect: | |||
| Phototoxicity | |||
| IFRA fragrance material specification: | |||
| Where the bergapten (5-methoxypsoralen) content of all relevant oils present in a compound has been determined, it is recommended that for applications on areas of skin exposed to sunshine, excluding bath preparations, soaps and other products which are washed off the skin, the total level of bergapten in the consumer products should not exceed 0.0015% (15 ppm). This is equivalent to 0.0075% (75 ppm) in a fragrance compound used at 20% in the consumer product. Where the level of bergapten has not been determined by appropriate methods, the limits specified in the guidelines on individual oils should apply. In those cases, where such oils are used in combination with other phototoxic ingredients, the additive effect has to be taken into consideration and the use levels have to be reduced accordingly. The sum of the concentrations of all phototoxic fragrance ingredients, expressed in % of their recommended maximum level in the consumer product, shall not exceed 100. | |||
| contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only) | |||
| citral | Max. Found: 0.1 % and Reason: Sensitization | ||
| citronellol | Max. Found: trace to | ||
| geraniol | Max. Found: 0.04 % and Reason: Sensitization | ||
| perillaldehyde | Max. Found: 0.02 % and Reason: Sensitization | ||
| View the IFRA Standard | |||
| View IFRA Standards Library for complete information. | |||
| Please review Amendment 49 IFRA documentation for complete information. | |||
| IFRA RESTRICTION LIMITS IN THE FINISHED PRODUCT (%): | |||
| Category 1: Products applied to the lips | |||
| 1.25 % | |||
| Category 2: Products applied to the axillae | |||
| 1.25 % | |||
| Category 3: Products applied to the face/body using fingertips | |||
| 1.25 % | |||
| Category 4: Products related to fine fragrance | |||
| 1.25 % | |||
| Category 5: Products applied to the face and body using the hands (palms), primarily leave-on | |||
| Category 5A: Body lotion products applied to the body using the hands (palms), primarily leave-on | |||
| 1.25 % | |||
| Category 5B: Face moisturizer products applied to the face using the hands (palms), primarily leave-on | |||
| 1.25 % | |||
| Category 5C: Hand cream products applied to the hands using the hands (palms), primarily leave-on | |||
| 1.25 % | |||
| Category 5D: Baby Creams, baby Oils and baby talc | |||
| 1.25 % | |||
| Category 6: Products with oral and lip exposure | |||
| 1.25 % | |||
| Category 7: Products applied to the hair with some hand contact | |||
| Category 7A: Rinse-off products applied to the hair with some hand contact | |||
| No Restriction % | |||
| Category 7B: Leave-on products applied to the hair with some hand contact | |||
| 1.25 % | |||
| Category 8: Products with significant anogenital exposure | |||
| 1.25 % | |||
| Category 9: Products with body and hand exposure, primarily rinse off | |||
| No Restriction % | |||
| Category 10: Household care products with mostly hand contact | |||
| Category 10A: Household care excluding aerosol products (excluding aerosol/spray products) | |||
| No Restriction % | |||
| Category 10B: Household aerosol/spray products | |||
| 1.25 % | |||
| Category 11: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate | |||
| Category 11A: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure | |||
| No Restriction % | |||
| Category 11B: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure | |||
| 1.25 % | |||
| Category 12: Products not intended for direct skin contact, minimal or insignificant transfer to skin | |||
| No Restriction | |||
| Notes: | |||
| IFRA FLAVOR REQUIREMENTS: | |||
Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards. | |||
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). | |||
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library | |||
| publication number: 3 | |||
| Click here to view publication 3 | |||
| average usual ppm | average maximum ppm | ||
| baked goods: | - | 110.00000 | |
| beverages(nonalcoholic): | - | 67.00000 | |
| beverages(alcoholic): | - | 4.00000 | |
| breakfast cereal: | - | - | |
| cheese: | - | - | |
| chewing gum: | - | 500.00000 | |
| condiments / relishes: | - | - | |
| confectionery froastings: | - | - | |
| egg products: | - | - | |
| fats / oils: | - | - | |
| fish products: | - | - | |
| frozen dairy: | - | 71.00000 | |
| fruit ices: | - | 71.00000 | |
| gelatins / puddings: | - | 300.00000 | |
| granulated sugar: | - | - | |
| gravies: | - | - | |
| hard candy: | - | 150.00000 | |
| imitation dairy: | - | - | |
| instant coffee / tea: | - | - | |
| jams / jellies: | - | - | |
| meat products: | - | - | |
| milk products: | - | - | |
| nut products: | - | - | |
| other grains: | - | - | |
| poultry: | - | - | |
| processed fruits: | - | - | |
| processed vegetables: | - | - | |
| reconstituted vegetables: | - | - | |
| seasonings / flavors: | - | - | |
| snack foods: | - | - | |
| soft candy: | - | - | |
| soups: | - | - | |
| sugar substitutes: | - | - | |
| sweet sauces: | - | - | |
Safety references
| European Food Safety Authority (EFSA) reference(s): |
| Safety and efficacy of a feed additive consisting of a flavonoid-rich dried extract of Citrus × aurantium L. fruit (bitter orange extract) for use in all animal species (FEFANA asbl) View page or View pdf |
| EPI System: View |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA Substance Registry Services (TSCA):68916-04-1 |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| National Institute of Allergy and Infectious Diseases:Data |
| WISER:UN 1993 |
| WGK Germany:2 |
| citrus aurantium l. peel oil bitter brazil |
| Chemidplus:0068916041 |