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petitgrain oil paraguay

Petitgrain oil Paraguay is an essential oil derived from Citrus aurantium leaves, exhibiting floral and herbal characteristics used primarily in flavor and fragrance industries.

General Material Description

Petitgrain oil Paraguay is an essential oil extracted from the leaves and green twigs of Citrus aurantium, commonly known as bitter orange. It presents as a clear to pale yellow liquid with a fresh, herbal, and floral aroma profile. Synonyms include citrus aurantium leaf oil Paraguay and petitgrain Paraguay essential oil. This oil is classified under essential oils and is documented with identifiers such as CAS number 8014-17-3, and is known for contributing green, citrus, and woody notes in perfumery. It is typically sourced by steam distillation from the leaves and twigs of the bitter orange tree indigenous to Paraguay and surrounding regions. Detailed compound data can be referenced via PubChem.

Occurrence, Applicability & Potential Uses

Petitgrain oil naturally occurs from the leaves and twigs of Citrus aurantium trees. This oil is widely used as a flavoring and fragrance agent, especially in perfumery to impart fresh, herbal, and floral notes reminiscent of orange blossoms. It finds application in colognes, soaps, lotions, and other personal care products. It pairs well with notes such as bergamot, jasmine, sandalwood, and amber in complex fragrance structures. The oil is recognized within the FEMA (US) registry under number 2855 for flavor and fragrance uses. Its use is compliant with IFRA (Global) standards, which regulate concentrations to avoid sensitization.

Physico-Chemical Properties Summary

Petitgrain oil Paraguay has a specific gravity ranging approximately from 0.878 to 0.889 measured at 25°C, and a refractive index of 1.45 to 1.46 at 20°C, indicators relevant for quality control and formulation. The oil is combustible with a flash point around 67°C (152°F). It is moderately soluble in alcohol and fixed oils, is slightly soluble in paraffin oil, and negligibly soluble in water at ambient temperature. Shelf life extends to at least 24 months when stored in sealed containers away from heat and light. The oil remains stable without discoloration in various cosmetic bases including creams, shampoos, and lotions, which is essential for maintaining product consistency.

FAQ

What is petitgrain oil Paraguay and how is it characterized?
Petitgrain oil Paraguay is an essential oil obtained by steam distillation from the leaves and green twigs of the Citrus aurantium tree. It exhibits a fresh, floral, and herbal aroma with subtle citrus and woody undertones. The oil is clear to pale yellow and is valued for its medium-strength floral scent with a 28-hour substantivity. Its flavor profile is herbal and green, often described as fresh and sweet, making it suitable for various fragrance and flavor applications.
In what industries and products is petitgrain oil Paraguay commonly used?
This essential oil is primarily utilized in the flavor and fragrance industries. It serves as a key perfuming agent in products such as colognes, soaps, lotions, and hair care formulations. Petitgrain oil’s aromatic qualities complement citrus and floral notes in complex blends. It is also applied in flavorings for baked goods, beverages, and confectionery within safe concentration limits. Its compatibility with other essential oils like bergamot and sandalwood enhances its versatility in creating nuanced scent profiles.
What are the regulatory considerations and safety measures for using petitgrain oil Paraguay?
Petitgrain oil Paraguay is regulated under multiple frameworks, including IFRA (Global) which sets limits to mitigate potential skin sensitization. It is classified as an irritant to skin and eyes and may cause allergic reactions upon contact. Proper storage in cool, dark conditions is advised to preserve quality and safety. Users should employ protective measures like gloves and eye protection when handling the oil. The FEMA (US) number 2855 lists it for flavoring, and safety data indicates it is combustible with precautions necessary to avoid ignition sources.

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Other Information

FDA Substances Added to Food (formerly EAFUS):View
Export Tariff Code:3301.29.6000
Typical G.C.
Wikipedia:View
FAO:BASIC PRINCIPLES OF STEAM DISTILLATION

General Material Information

Preferred name petitgrain oil paraguay
Trivial Name Petitgrain oil
Short Description citrus aurantium leaf oil paraguay
CAS Number 8014-17-3
Deleted CAS Number 68606-98-4
FEMA Number 2855
ECHA Number 277-143-2
FDA UNII 59JDQ5VT0T
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 8014-17-3 ; PETITGRAIN, OIL (CITRUS AURANTIUM L.)
Synonyms
  • citrus aurantium leaf oil paraguay
  • oil petitgrain S.A. cordillera extra FCC
  • oil petitgrain S.A. perfumery
  • petinerol paraguay
  • petitgrain oil paraguay FCC
  • petitgrain oil paraguay, organic
  • petitgrain oil redisitlled FCC
  • petitgrain oil S.A.
  • petitgrain oil SA FCC
  • petitgrain oil, paraguay
  • petitgrain oil, S.A.
  • petitgrain paraguay EO
  • petitgrain paraguay essential oil
  • petitgrain paraguay oil (citrus aurantium)
  • citrus aurantium l. leaf oil
  • Petitgrain oil
  • Oils, petitgrain
  • Essential oils, orange, sour
  • Oils, essential, orange, sour
  • Essential oils, Citrus bigaradia
  • Oil of Pettitgrain
  • Mandarin petitgrain oil
  • Petitgrain mandarin oil
  • Orange leaf water
  • Bitter orange oil
  • Orange oil
  • FG 8855
  • Essential oils, orange
  • Bitter orange oils
  • Citrus bigaradia oil
  • Citrus oils, Citrus bigaradia

PhysChem Properties

Material listed in food chemical codex No
Specific gravity @ 25 °C
Pounds per Gallon 7.306 to 7.397
Refractive Index 1.45 to 1.46 @ 20 °C
Flash Point TCC Value 66.67 °C TCC
Shelf life 24 months (or longer if stored properly.)
Storage notes Store in cool, dry place in tightly sealed containers, protected from heat and light.
Solubility
alcohol Yes
fixed oils Yes
paraffin oil, slightly coudy Yes
water, 20.12 mg/L @ 25 °C (est) Yes
water No
glycerin No
Stability
bath foam Unspecified
cream Unspecified
hair spray Unspecified
lipstick Unspecified
lotion Unspecified
non-discoloring in most media Unspecified
powder Unspecified
shampoo Unspecified
soap Unspecified

Organoleptic Properties

Odor Type: Floral
sweet, floral, neroli, herbal, terpenic, green, citrus, woody
Odor strength medium
Substantivity 28 hour(s) at 100.00 %
Luebke, William tgsc, (1982) At 100.00 %. sweet floral neroli herbal terpenic green citrus woody
Flavor Type: Herbal
herbal, floral, lavender, terpenic, green, citrus, woody
Luebke, William tgsc, (1982) Herbal floral lavender terpenic green citrus woody
General comment Fresh, sweet, green, citrus
Useful for citrus tonalities, mainly orange and mandarin Earthy floral green soapy woody

Occurrences

Safety Information

Safety information

European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
R 43 - May cause sensitisation by skin contact.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 - Wear suitable gloves and eye/face protection.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Flammable liquids (Category 4), H227
Skin irritation (Category 2), H315
Skin sensitisation (Category 1), H317
Eye irritation (Category 2A), H319
Chronic aquatic toxicity (Category 2), H411
GHS Label elements, including precautionary statements
Pictogramexclamation-mark.jpghealth-hazard.jpg
Signal word Warning
Hazard statement(s)
H227 - Combustible liquid
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H411 - Toxic to aquatic life with long lasting effects
Precautionary statement(s)
P210 - Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P264 - Wash skin thouroughly after handling.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P403 + P235 - Store in a well-ventilated place. Keep cool.
P501 - Dispose of contents/ container to an approved waste disposal plant.
Oral/Parenteral Toxicity:
oral-rat LD50 > 5000 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 101S, 1992.

Dermal Toxicity:
skin-rabbit LD50 > 2000 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 101S, 1992.

Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
IFRA Critical Effect:
Sensitization
IFRA Other Specification:
IFRA fragrance material specification:
Linalool and natural products known to be rich in linalool, such as bois de rose, coriander or ho wood oil, should only be used when the level of peroxides is kept to the lowest practical level. It is recommended to add antioxidants at the time of production of the raw material. The addition of 0.1% BHT or alpha-tocopherol for example has shown great efficiency. The maximum peroxide level for products in use should be 20 mmol/l.
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
citral Max. Found:
geraniol Max. Found: 3.00 % and Reason: Sensitization
(E)-2-hexen-1-al Max. Found: trace to
View IFRA Standards Library for complete information.
Please review Amendment 49 IFRA documentation for complete information.
IFRA RESTRICTION LIMITS IN THE FINISHED PRODUCT (%):
Category 1: Products applied to the lips
Category 2: Products applied to the axillae
Category 3: Products applied to the face/body using fingertips
Category 4: Products related to fine fragrance
Category 5: Products applied to the face and body using the hands (palms), primarily leave-on
Category 5A: Body lotion products applied to the body using the hands (palms), primarily leave-on
Category 5B: Face moisturizer products applied to the face using the hands (palms), primarily leave-on
Category 5C: Hand cream products applied to the hands using the hands (palms), primarily leave-on
Category 5D: Baby Creams, baby Oils and baby talc
Category 6: Products with oral and lip exposure
Category 7: Products applied to the hair with some hand contact
Category 7A: Rinse-off products applied to the hair with some hand contact
Category 7B: Leave-on products applied to the hair with some hand contact
Category 8: Products with significant anogenital exposure
Category 9: Products with body and hand exposure, primarily rinse off
Category 10: Household care products with mostly hand contact
Category 10A: Household care excluding aerosol products (excluding aerosol/spray products)
Category 10B: Household aerosol/spray products
Category 11: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate
Category 11A: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure
See Note %
Category 11B: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure
Category 12: Products not intended for direct skin contact, minimal or insignificant transfer to skin
Notes:
IFRA FLAVOR REQUIREMENTS:

Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards.

Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -17.00000
beverages(nonalcoholic): -1.50000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: -4.10000
condiments / relishes: -15.00000
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -1.40000
fruit ices: -1.40000
gelatins / puddings: -0.20000
granulated sugar: --
gravies: --
hard candy: -5.30000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):8014-17-3
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
citrus aurantium l. leaf oil
Chemidplus:0008014173
RTECS:RJ3696700 for cas# 8014-17-3