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General Material Information

Preferred name cade oil
Trivial Name juniperus oxycedrus l. tar oil
Short Description juniperus oxycedrus tar oil
CAS Number 8013-10-3
FDA UNII Search
Synonyms
  • cade essential oil
  • cade oil crude
  • cade oil rectified
  • cade oil USP
  • cade rectified ess. oil (for fragrance) (Robertet)
  • cade´ EO rectified
  • cade' eo crude
  • prickly cedar tar oil
  • spanish cedar tar oil
  • holland balsam
  • prickly juniper tar oil
  • red juniper tar oil
  • juniper tar oil (juniperus oxycedrus)
  • juniperus oxycedrus tar oil

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Other Information

Export Tariff Code:3301.29.6000
Wikipedia:View
FAO:BASIC PRINCIPLES OF STEAM DISTILLATION

PhysChem Properties

Material listed in food chemical codex No
Specific gravity @ 25 °C
Pounds per Gallon 7.905 to 8.779
Refractive Index 1.51 to 1.525 @ 20 °C
Flash Point TCC Value 93.33 °C TCC
Solubility
alcohol Yes
water, 0.02173 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Smoky
smoky, burnt, grilled, leathery, resinous
Odor strength high , recommend smelling in a 1.00 % solution or less
Substantivity 400 hour(s) at 100.00 %
Luebke, William tgsc, (1989) At 1.00 % in dipropylene glycol. smoky birch tar burnt grilled leather resinous
Blends-well-with - +Thyme +Clove Bud +Rosemary +Origanum +Labdanum thyme origanum clove cassia tea tree pine and medicinal-type bases. Birch tar smoke burnt woody smoke tar leather burnt woody smoky leather-like
Produced by destructive distillation of the twigs and leaves of Juniperus oxycedrus and then rectified to meet the IFRA standard: crude Cade Oil should not be used in fragrances. Smoky, phenolic, bonfire

Occurrences

Potential Uses

Applications
Odor purposes Castoreum, Fern, Forest, Leather, Leather russian leather, Moss, Smoke
Flavoring purposes Burnt
Cosmetic purposes Hair conditioning

Safety Information

Safety information

Preferred SDS: View
European information :
Most important hazard(s):
Xi - Irritant
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Skin irritation (Category 2), H315
Eye irritation (Category 2A), H319
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
GHS Label elements, including precautionary statements
Pictogramexclamation-mark.jpg
Signal word Warning
Hazard statement(s)
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H335 - May cause respiratory irritation
Precautionary statement(s)
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash skin thouroughly after handling.
P271 - Use only outdoors or in a well-ventilated area.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P332 + P313 - IF SKIN irritation occurs: Get medical advice/attention.
P337 + P313 - IF eye irritation persists: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 - Store in a well-ventilated place. Keep cool.
P405 - Store locked up.
P501 - Dispose of contents/ container to an approved waste disposal plant.
Oral/Parenteral Toxicity:
oral-rat LD50 8014 mg/kg
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) GASTROINTESTINAL: GASTRITIS
Food and Cosmetics Toxicology. Vol. 2, Pg. 327, 1964.

Dermal Toxicity:
skin-rabbit LD50 > 5000 mg/kg
Food and Cosmetics Toxicology. Vol. 13, Pg. 733, 1975.

Inhalation Toxicity:
Not determined

Safety in use information

Category:
fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
IFRA Critical Effect:
Carcinogenicity, genotoxicity by release of polynuclear hydrocarbons (PAH)
IFRA fragrance material specification:
Limit content of polynuclear aromatic hydrocarbons (PAH) resulting from the use of rectified oils according to Good Manufacturing Practice. If used alone or in combination with rectified birch tar oils, benzopyrene and 1,2-benzanthracene are to be used as markers for PAHs. The total concentration of both of these should not exceed 1 ppb in the final product.
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
dihydroeugenol Max. Found: 0.5 % and Reason: Sensitization
View the IFRA Standard
Recommendation for cade oil usage levels up to:
0.5000 % in the fragrance concentrate.
Recommendation for cade oil flavor usage levels up to:
not for flavor use.

Safety references

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):8013-10-3
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
SCCNFP:opinion
WISER:UN 1993
WGK Germany:2
juniperus oxycedrus l. tar oil
Chemidplus:0008013103
RTECS:NY9872000 for cas# 8013-10-3