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General Material Information

Preferred name spruce needle oil canada
Trivial Name Oils, spruce
Short Description tsuga canadensis leaf oil canada
CAS Number 8008-80-8
FEMA Number 3034
FDA UNII Q1J49L1A5O
COE Number 461
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 8008-93-3 ; SPRUCE NEEDLES AND TWIGS, OIL (PICEA SPP.)
Synonyms
  • hemlock needle oil (tsuga canadensis) canada
  • canadian hemlock oil canada
  • spruce oil canada
  • tsuga canadensis leaf oil canada
  • tsuga canadensis l. leaf oil
  • Oils, spruce
  • Spruce oil

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Other Information

FDA Substances Added to Food (formerly EAFUS):View
Export Tariff Code:3301.29.6000
Wikipedia:View
FAO:BASIC PRINCIPLES OF STEAM DISTILLATION

PhysChem Properties

Material listed in food chemical codex No
Specific gravity @ 25 °C
Pounds per Gallon 7.489 to 7.614
Refractive Index 1.467 to 1.4672 @ 20 °C
Optical Rotation -26 to -18
Acid Value 2 max KOH/g
Vapor Pressure 0.68 mmHg @ 25 °C
Flash Point TCC Value 42.22 °C TCC
Shelf life 24 months (or longer if stored properly.)
Storage notes Store in cool, dry place in tightly sealed containers, protected from heat and light.
Solubility
alcohol Yes
water, 7.061 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Woody
fir needle, woody, thujonic, herbal, terpenic, aldehydic, amber
Odor strength medium
Substantivity 24 hour(s) at 100.00 %
Luebke, William tgsc, (1988) At 100.00 %. fir needle woody thujone herbal terpenic aldehydic amber
Flavor Type: Woody
woody, herbal, green, aromatic, terpenic, thujonic, minty, amber
Uebke, William tgsc, (1988) Woody herbal green aromatic terpenic thujonic minty amber

Occurrences

Safety Information

Safety information

European information :
Most important hazard(s):
Xi - Irritant
R 10 - Flammable.
R 36 - Irritating to eyes.
R 43 - May cause sensitisation by skin contact.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Flammable liquids (Category 3), H226
Skin irritation (Category 2), H315
Chronic aquatic toxicity (Category 2), H411
GHS Label elements, including precautionary statements
Pictogramflame.jpgexclamation-mark.jpgenvironment.jpg
Signal word Warning
Hazard statement(s)
H226 - Flammable liquid and vapour
H315 - Causes skin irritation
H411 - Toxic to aquatic life with long lasting effects
Precautionary statement(s)
P210 - Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 - Keep container tightly closed.
P240 - Ground/bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P264 - Wash skin thouroughly after handling.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P332 + P313 - IF SKIN irritation occurs: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P370 + P378 - In case of fire: Use appropriate media to extinguish.
P391 - Collect spillage. Hazardous to the aquatic environment
P403 + P235 - Store in a well-ventilated place. Keep cool.
P501 - Dispose of contents/container in accordance with local/regional/national/international regulations.
Oral/Parenteral Toxicity:
oral-rat LD50 > 5000 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 117S, 1992.

Dermal Toxicity:
skin-rabbit LD50 > 5000 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 117S, 1992.

Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for spruce needle oil canada usage levels up to:
10.0000 % in the fragrance concentrate.
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: 2.000004.00000
beverages(nonalcoholic): -6.20000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: -44.00000
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -15.00000
fruit ices: -15.00000
gelatins / puddings: -1.00000
granulated sugar: --
gravies: --
hard candy: -11.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

EPI System: View
EPA Substance Registry Services (TSCA):8008-80-8
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 1197
WGK Germany:2
tsuga canadensis l. leaf oil
Chemidplus:0008008808