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General Material Information

Preferred name neroli oil bigarde
Trivial Name Essential oils, sour orange neroli
Short Description citrus bigaradia oil
CAS Number 8016-38-4
FEMA Number 2771
FDA UNII D4BGE91OXH
MDL MFCD01774445
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 8016-38-4 ; NEROLI, BIGARADE OIL (CITRUS AURANTIUM L.)
Synonyms
  • bigarade oil (citrus bigaradia)
  • bigarade orange ess. oil (for fragrance) (Robertet)
  • citrus bigaradia oil
  • neroli bigarade essential oil
  • neroli bigarade oil
  • neroli oil bigarade egypt
  • oil neroli bigarade
  • bitter orangeflower oil (citrus aurantium var amara) (bigarade)
  • Essential oils, sour orange neroli
  • Oils, neroli
  • Oils, essential, sour orange neroli
  • Orange-flower water
  • Orange-blossom oil
  • Citrus aurantium, amara, essential oil
  • Orange flower oil
  • Oil of orange blossom
  • Orange blossom oil
  • Sour orange neroli oil
  • Citrus aurantium amara flower oil
  • Citrus aurantium flower oil
  • Bitter orange flower oil
  • Oil of orange flowers
  • Neroli oil
  • Neroli

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Other Information

FDA Substances Added to Food (formerly EAFUS):View
Export Tariff Code:3301.29.6000
Typical G.C.
Wikipedia:View
FAO:BASIC PRINCIPLES OF STEAM DISTILLATION

PhysChem Properties

Material listed in food chemical codex No
Specific gravity @ 25 °C
Pounds per Gallon 7.123 to 7.231
Refractive Index 1.45 to 1.51 @ 20 °C
Flash Point TCC Value 67.78 °C TCC
Shelf life 12 months (or longer if stored properly.)
Storage notes Store in cool, dry place in tightly sealed containers, protected from heat and light.
Solubility
alcohol Yes
paraffin oil Yes
water, 4.581 mg/L @ 25 °C (est) Yes
water No
propylene glycol No
Stability
bath foam Unspecified
cream Unspecified
hair spray Unspecified
lotion Unspecified
powder Unspecified
soap Unspecified

Organoleptic Properties

Odor Type: Floral
sweet, floral, orangeflower, citrus, petitgrain, mandarin, herbal, fresh, jasmin, lavender
Odor strength medium
Substantivity 116 hour(s) at 100.00 %
Luebke, William tgsc, (1983) At 100.00 %. sweet floral orangeblossom citrus petitgrain mandarin herbal
Mosciano, Gerard P&F 22, No. 1, 57, (1997) Floral, citrus, fresh and refreshing with jasmine and lavender nuances
Flavor Type: Floral
fresh, floral, citrus, green, waxy, clean, herbal
Mosciano, Gerard P&F 22, No. 1, 57, (1997) At 5.00 ppm. Fresh, floral, citrus and green with a waxy and clean herbal nuance

Occurrences

Safety Information

Safety information

European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 4550 mg/kg
Food and Cosmetics Toxicology. Vol. 14, Pg. 813, 1976.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
IFRA Critical Effect:
Phototoxicity
IFRA Other Specification:
IFRA fragrance material specification:
Where the bergapten (5-methoxypsoralen) content of all relevant oils present in a compound has been determined, it is recommended that for applications on areas of skin exposed to sunshine, excluding bath preparations, soaps and other products which are washed off the skin, the total level of bergapten in the consumer products should not exceed 0.0015% (15 ppm). This is equivalent to 0.0075% (75 ppm) in a fragrance compound used at 20% in the consumer product. Where the level of bergapten has not been determined by appropriate methods, the limits specified in the guidelines on individual oils should apply. In those cases, where such oils are used in combination with other phototoxic ingredients, the additive effect has to be taken into consideration and the use levels have to be reduced accordingly. The sum of the concentrations of all phototoxic fragrance ingredients, expressed in % of their recommended maximum level in the consumer product, shall not exceed 100.
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
citral Max. Found: 0.2 % and Reason: Sensitization
farnesol Max. Found: 1.8 % and Reason: Sensitization
geraniol Max. Found: 2.8 % and Reason: Sensitization
methyl formyl anthranilate Max. Found: 0.03 % and Reason: Phototoxicity
phenyl acetonitrile Max. Found: 0.2 % and Reason: Release of cyanide
farnesal Max. Found: 0.07 % and Reason: Sensitization
Recommendation for neroli oil bigarde usage levels up to:
4.0000 % in the fragrance concentrate.
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -16.00000
beverages(nonalcoholic): -2.00000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: -14.00000
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -3.20000
fruit ices: -3.20000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -8.90000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):8016-38-4
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:1
citrus bigaradia oil
Chemidplus:0008016384
EPA/NOAA CAMEO:hazardous materials
RTECS:QQ0960000 for cas# 8016-38-4