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orange oil terpenes

General Material Information

Preferred name orange oil terpenes
Trivial Name Terpenes and Terpenoids, sweet orange-oil
Short Description orange terpenes
CAS Number 68647-72-3
FEMA Number 4850
FDA UNII Search
MDL MFCD00677562
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
Synonyms
  • oil orange terpenes ex-5-fold
  • orange oil c.p. terpenes
  • orange oil terpenes florida
  • orange oil terpenes italian
  • orange sesquiterpenes, natural
  • orange terpene SP
  • orange terpene ST
  • orange terpenes
  • orange terpenes (flavor or fragrance grade)
  • orange terpenes redistilled
  • orange terpenes, natural
  • Terpenes and Terpenoids, sweet orange-oil
  • Orange oil California, sweet, terpenes

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Literature & References

Canada Domestic Sub. List:68647-72-3
Pubchem (sid):135323834
Publications by PubMed
Phospholipids and terpenes modulate Caco-2 transport of açaí anthocyanins.
Encapsulation of liquids using a counter rotating twin screw extruder.
Synthesis and properties of cholesteryl 4-(Alkanoylamino)benzoates: liquid crystals and organogelators.
A sensitive method for determination of allergenic fragrance terpene hydroperoxides using liquid chromatography coupled with tandem mass spectrometry.
Isolation and biological activities of decanal, linalool, valencene, and octanal from sweet orange oil.
Nanoemulsion delivery systems: influence of carrier oil on β-carotene bioaccessibility.
Changes of peel essential oil composition of four Tunisian citrus during fruit maturation.
Neurite outgrowth of PC12 mutant cells induced by orange oil and d-limonene via the p38 MAPK pathway.
Monitoring of total type ii pyrethroid pesticides in citrus oils and water by converting to a common product 3-phenoxybenzoic acid.
Effect of orange oil on the oral absorption of enrofloxacin in rats.
Effectiveness of three solvents and two associations of solvents on gutta-percha and resilon.
A comparison of the stability of beverage cloud emulsions formulated with different gum acacia- and starch-based emulsifiers.
Anti-inflammatory effects of Myrtol standardized and other essential oils on alveolar macrophages from patients with chronic obstructive pulmonary disease.
Catalytic oxidation of concentrated orange oil phase by synthetic metallic complexes biomimetic to MMO enzyme.
Distribution of retinal cone photoreceptor oil droplets, and identification of associated carotenoids in crow (Corvus macrorhynchos).
Solvent capacity of different substances on gutta-percha and Resilon.
Microbial inhibitory and radical scavenging activities of cold-pressed terpeneless Valencia orange (Citrus sinensis) oil in different dispersing agents.
Ciprofloxacin-sensitive and ciprofloxacin-resistant Campylobacter jejuni are equally susceptible to natural orange oil-based antimicrobials.
Immunochemical screening of pesticides (simazine and cypermethrin) in orange oil.
Fumigant insecticidal activity and repellent effect of five essential oils and seven monoterpenes on first-instar nymphs of Rhodnius prolixus.
In vitro antilisterial effects of citrus oil fractions in combination with organic acids.
Orange essential oils antimicrobial activities against Salmonella spp.
Comparative SEM evaluation of three solvents used in endodontic retreatment: an ex vivo study.
Campylobacter and Arcobacter species sensitivity to commercial orange oil fractions.
Antimicrobial activity of commercial citrus-based natural extracts against Escherichia coli O157:H7 isolates and mutant strains.
Application of comprehensive two-dimensional liquid chromatography to elucidate the native carotenoid composition in red orange essential oil.
Effect of orange oil extract on the formosan subterranean termite (Isoptera: Rhinotermitidae).
The survival of three strains of Arcobacter butzleri in the presence of lemon, orange and bergamot essential oils and their components in vitro and on food.
Skin diseases in workers at a perfume factory.
In vitro evaluation of macrophage viability after incubation in orange oil, eucalyptol, and chloroform.
Dissolving efficacy of organic solvents on root canal sealers.
Biotransformation of citrus aromatics nootkatone and valencene by microorganisms.
Isolation and identification of terpene chlorohydrins found in cold-pressed orange oil.
High-speed characterization and analysis of orange oils with tandem-column stop-flow GC and time-of-flight MS.
In vitro study of effect of solvent on root canal retreatment.
Effect of different terpene-containing essential oils on permeation of estradiol through hairless mouse skin.
Effect of gutta-percha solvents at different temperatures on the calcium, phosphorus and magnesium levels of human root dentin.
In vitro study on the softening of gutta-percha cones in endodontic retreatment.
Inhibition of 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone carcinogenesis in mice by D-limonene and citrus fruit oils.
Inhibition of carcinogenesis by minor anutrient constituents of the diet.
The prevention of nitrosomethylurea-induced mammary tumors by d-limonene and orange oil.

Other Information

Export Tariff Code:3301.12.0000
FAO:BASIC PRINCIPLES OF STEAM DISTILLATION

PhysChem Properties

Material listed in food chemical codex No
Specific gravity @ 25 °C
Pounds per Gallon 6.948 to 7.006
Refractive Index 1.466 to 1.474 @ 20 °C
Flash Point TCC Value 44.44 °C TCC
Shelf life 12 months (or longer if stored properly.)
Storage notes Store in cool, dry place in tightly sealed containers, protected from heat and light.
Solubility
alcohol Yes
water, 4.581 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Citrus
fresh, juicy, sweet, orange
Odor strength medium
Substantivity 4 hour(s) at 100.00 %
Luebke, William tgsc, (1992) At 100.00 %. fresh juicy sweet orange
Arctander describes this staple of perfumery like this: “Fresh, light and sweet citrusy odor with strong resemblance to Orange peel oil. Commercial grade d-Limonene may be redistilled ‘Citrus Terpenes’ and will then carry more Orange-like odor than a highly purified Limonene. Poor tenacity.” Fresh, sweet, sharp, orange

Safety Information

Safety information

Preferred SDS: View
European information :
Most important hazard(s):
Xn N - Harmful, Dangerous for the environment.
R 10 - Flammable.
R 38 - Irritating to skin.
R 50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 65 - Harmful: may cause lung damage if swallowed.
S 02 - Keep out of the reach of children.
S 16 - Keep away from sources of ignition - No Smoking.
S 24 - Avoid contact with skin.
S 37 - Wear suitable gloves.
S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet.
S 62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
IFRA Critical Effect:
Phototoxicity
IFRA fragrance material specification:
Where the bergapten (5-methoxypsoralen) content of all relevant oils present in a compound has been determined, it is recommended that for applications on areas of skin exposed to sunshine, excluding bath preparations, soaps and other products which are washed off the skin, the total level of bergapten in the consumer products should not exceed 0.0015% (15 ppm). This is equivalent to 0.0075% (75 ppm) in a fragrance compound used at 20% in the consumer product. Where the level of bergapten has not been determined by appropriate methods, the limits specified in the guidelines on individual oils should apply. In those cases, where such oils are used in combination with other phototoxic ingredients, the additive effect has to be taken into consideration and the use levels have to be reduced accordingly. The sum of the concentrations of all phototoxic fragrance ingredients, expressed in % of their recommended maximum level in the consumer product, shall not exceed 100.
Recommendation for orange oil terpenes usage levels up to:
10.0000 % in the fragrance concentrate.
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 28
Click here to view publication 28
average usual ppmaverage maximum ppm
baked goods: 470.000005000.00000
beverages(nonalcoholic): 80.000001550.00000
beverages(alcoholic): 93.000001000.00000
breakfast cereal: 101.000001000.00000
cheese: 100.000001000.00000
chewing gum: 1943.0000020000.00000
condiments / relishes: 71.00000500.00000
confectionery froastings: 489.000005000.00000
egg products: 1000.000005000.00000
fats / oils: 43.00000500.00000
fish products: 38.00000180.00000
frozen dairy: 215.000001000.00000
fruit ices: 166.000001000.00000
gelatins / puddings: 323.000002000.00000
granulated sugar: 100.00000500.00000
gravies: 200.000001000.00000
hard candy: 507.000005000.00000
imitation dairy: 190.00000900.00000
instant coffee / tea: 113.000001000.00000
jams / jellies: 475.000005000.00000
meat products: 10.0000050.00000
milk products: 181.00000788.00000
nut products: 50.00000500.00000
other grains: 100.00000500.00000
poultry: 30.00000100.00000
processed fruits: 333.000001050.00000
processed vegetables: 100.00000500.00000
reconstituted vegetables: --
seasonings / flavors: 1738.000005000.00000
snack foods: 100.000001000.00000
soft candy: 449.000005000.00000
soups: 29.00000250.00000
sugar substitutes: 50.00000500.00000
sweet sauces: 440.000005000.00000

Safety references

EPI System: View
EPA Substance Registry Services (TSCA):68647-72-3
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 2319
WGK Germany:3
Chemidplus:0068647723