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clove oil terpenes

Clove oil terpenes are natural aromatic compounds from Syzygium aromaticum with a medium spicy scent widely used as fragrance agents.

General Material Description

Clove oil terpenes consist primarily of volatile organic compounds isolated from the buds and leaves of Syzygium aromaticum, commonly known as clove. These terpenes represent a complex mixture enriched in sesquiterpenes such as caryophyllene, which contribute to their characteristic medium-strength spicy odor profile. The oil appears as a liquid with refractive indices typically between 1.495 to 1.505 at 20°C and a specific gravity near 0.9 at 25°C. Clove oil terpenes are used extensively in the fragrance industry and are often referenced by synonyms including eugenia caryophyllata terpenes, clove leaf terpenes, and jambosa caryophyllus terpenes. For comprehensive chemical data and nomenclature, the PubChem database offers an established reference. These terpenes derive commonly from steam distillation of clove plant parts, a process well-documented in industrial applications for essential oil extraction.

Occurrence, Applicability & Potential Uses

Clove oil terpenes occur naturally in several parts of the clove plant, especially within the flower buds and leaves of Syzygium aromaticum. They contribute significantly to the plant’s aromatic properties and have been harnessed mainly as fragrance agents for a wide array of scent applications. This includes use in perfumes, soaps, and cosmetic formulations where their warm and spicy notes are desirable. According to the IFRA Code of Practice (Global), clove oil terpenes are approved for fragrance usage up to 10% concentration in fragrance concentrates, reflecting a balance between effective aroma impact and safety considerations. Although the terpenes are notable for flavor-related aroma profiles, they are generally not recommended for direct flavoring purposes. Additional uses include substitution for other spice-derived oils and incorporation in aroma blends resembling cinnamon, allspice, or pepper, as well as in products aiming for spicy or warm character notes.

Physico-Chemical Properties Summary

Clove oil terpenes exhibit a specific gravity ranging from 0.897 to 0.907 at 25°C, indicating a density slightly less than water and consistent with typical essential oil constituents. The refractive index falls between 1.495 and 1.505 at 20°C, which assists in verifying purity and quality. They display an optical rotation between -12° and -2°, reflecting the chiral nature of some terpene components. The flash point is measured at approximately 60°C (140°F), suggesting moderate volatility and flammability under certain conditions. These terpenes are soluble in alcohol and have limited water solubility, which is typical for hydrophobic organic compounds, thus influencing formulation choices in perfume and cosmetic products. Proper storage in cool, dry, and light-protected conditions can extend their shelf life beyond 24 months. Substantivity measurements show that their spicy odor sustains for multiple hours, making them durable components in fragrance compositions.

FAQ

What are clove oil terpenes and their primary characteristics?
Clove oil terpenes are a mixture of volatile organic compounds obtained mainly from the clove plant, Syzygium aromaticum. These terpenes include sesquiterpene compounds such as caryophyllene, contributing to their signature medium-strength spicy aroma. Used primarily as fragrance agents, they offer warm, spicy odor notes valuable in perfumery and aroma chemistry. The oil exhibits specific gravity around 0.9, refractive index near 1.5 at 20°C, and optical rotation from -12° to -2°, reflecting complex chemical properties typical of essential oil terpene fractions.
Where do clove oil terpenes naturally occur and how are they used?
These terpenes naturally occur in the flower buds and leaves of the clove tree, Syzygium aromaticum. Obtained via steam distillation, they are utilized predominantly as fragrance agents in various products such as perfumes and soaps. The IFRA Code of Practice allows their use up to 10% in fragrance concentrates. Although their aroma suggests flavor-related applications, direct use as flavoring agents is not common. They also serve as aromatic substitutes for other spices like allspice and cinnamon in perfumery and scent formulations.
What safety and regulatory information is relevant for clove oil terpenes?
Clove oil terpenes currently lack classification under OSHA's Hazard Communication Standard (29 CFR 1910), indicating no specific hazard labels or precautionary statements. The Research Institute for Fragrance Materials (RIFM) assesses these terpenes with no determined oral, dermal, or inhalation toxicity values reported. Usage recommendations note fragrance concentrations up to 10% per IFRA (Global) guidelines, with no flavor use approval. They are documented under CAS number 68917-29-3, with safety data available from multiple regulatory agencies including EFSA and EPA. Proper storage and handling according to recommended conditions minimize risk of degradation or hazard.

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Other Information

Export Tariff Code:3301.29.5045
Wikipedia:View
FAO:BASIC PRINCIPLES OF STEAM DISTILLATION

General Material Information

Preferred name clove oil terpenes
Trivial Name Terpenes and Terpenoids, clove-oil
Short Description syzygium aromaticum terpenes
CAS Number 68917-29-3
FDA UNII Search
Synonyms
  • caryophyllus aromaticus terpenes
  • clove leaf terpenes
  • clove terpenes
  • clove terpenes natural
  • eugenia aromatica terpenes
  • eugenia caryophyllata terpenes
  • eugenia caryophyllus terpenes
  • jambosa caryophyllus terpenes
  • myrtus caryophyllus terpenes
  • oil clove terpenes min. 70% caryophyllene
  • syzygium aromaticum terpenes
  • syzygium aromaticum l. terpenes
  • Terpenes and Terpenoids, clove-oil
  • Oils, clove leaf, terpenes
  • Terpenes and terpenoids, clove leaf oil
  • Clove leaf oil terpenes
  • Terpenes and Terpenoids, clove stem-oil
  • Clove stem oil terpenes

PhysChem Properties

Material listed in food chemical codex No
Specific gravity @ 25 °C
Pounds per Gallon 7.464 to 7.547
Refractive Index 1.495 to 1.505 @ 20 °C
Optical Rotation -12 to -2
Flash Point TCC Value 60 °C TCC
Shelf life 24 months (or longer if stored properly.)
Storage notes Store in cool, dry place in tightly sealed containers, protected from heat and light.
Solubility
alcohol Yes
water, 0.05011 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Spicy
fresh, clove, spicy, sweet
Odor strength medium
Substantivity 384 hour(s) at 100.00 %
Luebke, William tgsc, (1984) At 100.00 %. fresh clove caryophyllene sweet

Occurrences

Safety Information

Safety information

Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for clove oil terpenes usage levels up to:
10.0000 % in the fragrance concentrate.
Recommendation for clove oil terpenes flavor usage levels up to:
not for flavor use.

Safety references

European Food Safety Authority (EFSA) reference(s):

Conclusion on the peer review of the pesticide risk assessment of the active substance plant oils/clove oil
View page or View pdf

EPI System: View
EPA Substance Registry Services (TSCA):68917-29-3
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 1993
WGK Germany:3
syzygium aromaticum l. terpenes
Chemidplus:0068917293