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General Material Information

Preferred name petitgrain bigarade oil
Trivial Name Petitgrain leaf oil
Short Description essential oil obtained from the leaves of the sour orange, citrus aurantium, rutaceae
CAS Number 8014-17-3
Deleted CAS Number 347144-08-5
FEMA Number 2855
FDA UNII 59JDQ5VT0T
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 8014-17-3 ; PETITGRAIN, OIL (CITRUS AURANTIUM L.)
Synonyms
  • bigarade petitgrain oil
  • bitter orange leaf oil (citrus aurantium)
  • Bitter orange oil
  • Bitter orange oils
  • citrus aurantium l. leaf oil
  • citrus aurantium leaf oil (bigarade)
  • Citrus bigaradia oil
  • Citrus oils, Citrus bigaradia
  • essential oil obtained from the leaves of the sour orange, citrus aurantium, rutaceae
  • Essential oils, Citrus bigaradia
  • Essential oils, orange
  • Essential oils, orange, sour
  • FG 8855
  • Mandarin petitgrain oil
  • Oil of Pettitgrain
  • Oils, essential, orange, sour
  • Oils, petitgrain
  • Orange leaf water
  • Orange oil
  • petitgrain bigarade ess nat 01
  • petitgrain bigarade oil bio
  • petitgrain bigarade oil egypt
  • petitgrain bigarade oil tunisia
  • petitgrain bigarade tunis EO
  • Petitgrain mandarin oil
  • Petitgrain oil
  • petitgrain oil bigarade
  • petitgrain oil, bigarade
  • Petitgrain oil, Paraguay

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Other Information

FDA Substances Added to Food (formerly EAFUS):View
Export Tariff Code:3301.29.6000
Typical G.C.
Wikipedia:View
FAO:BASIC PRINCIPLES OF STEAM DISTILLATION

PhysChem Properties

Material listed in food chemical codex No
Acid Value 2 max KOH/g
Shelf life 24 months (or longer if stored properly.)
Storage notes Store in cool, dry place in tightly sealed containers, protected from heat and light.
Solubility
alcohol Yes
water, 20.12 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Floral
fresh, floral, sweet, orangeflower, woody, herbal, zesty, green
General comment At 100.00 %. fresh floral sweet orangflower woody herbal
Flavor Type: Citrus
citrus, floral, woody, herbal
General comment Petitgrain

Occurrences

Potential Uses

Applications
Odor purposes Bergamot, Fern, Jasmin, Lilac, Lily, Neroli
Cosmetic purposes Perfuming agents

Safety Information

Safety information

European information :
Most important hazard(s):
Xi - Irritant
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 > 5000 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 101S, 1992.

Dermal Toxicity:
skin-rabbit LD50 > 2000 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 101S, 1992.

Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
IFRA Critical Effect:
Phototoxicity
IFRA fragrance material specification:
Where the bergapten (5-methoxypsoralen) content of all relevant oils present in a compound has been determined, it is recommended that for applications on areas of skin exposed to sunshine, excluding bath preparations, soaps and other products which are washed off the skin, the total level of bergapten in the consumer products should not exceed 0.0015% (15 ppm). This is equivalent to 0.0075% (75 ppm) in a fragrance compound used at 20% in the consumer product. Where the level of bergapten has not been determined by appropriate methods, the limits specified in the guidelines on individual oils should apply. In those cases, where such oils are used in combination with other phototoxic ingredients, the additive effect has to be taken into consideration and the use levels have to be reduced accordingly. The sum of the concentrations of all phototoxic fragrance ingredients, expressed in % of their recommended maximum level in the consumer product, shall not exceed 100.
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
methyl N-methyl anthranilate Max. Found:
geraniol Max. Found: 2.4 % and Reason: Sensitization
(E)-2-hexen-1-al Max. Found: trace to
citral Max. Found: 0.65 % and Reason: Sensitization
citronellal Max. Found: 0.05 % and Reason: Sensitization
Recommendation for petitgrain bigarade oil usage levels up to:
15.0000 % in the fragrance concentrate.
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -17.00000
beverages(nonalcoholic): -1.50000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: -4.10000
condiments / relishes: -15.00000
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -1.40000
fruit ices: -1.40000
gelatins / puddings: -0.20000
granulated sugar: --
gravies: --
hard candy: -5.30000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

European Food Safety Authority (EFSA) reference(s):

Safety and efficacy of a feed additive consisting of an essential oil from the leaves of Citrus × aurantium L. (petitgrain bigarade oil) for use in all animal species (FEFANA asbl)
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):8014-17-3
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
citrus aurantium l. leaf oil
Chemidplus:0008014173