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bergamot oil terpenes

Bergamot oil terpenes are natural aromatic compounds from Citrus x bergamia peel oil, valued for their floral scent and use in fragrance formulations.

General Material Description

Bergamot oil terpenes comprise a complex mixture of terpenes and terpenoids primarily obtained from the peel oil of the bergamot orange (Citrus x bergamia). These volatile compounds contribute a distinctly floral and citrusy odor profile commonly employed in perfumery and flavoring contexts. This material is alternatively known under synonyms like "citrus aurantium bergamia peel oil terpenes" or simply "bergamot terpenes." Their chemical composition aligns with typical citrus peel oils rich in monoterpenes. As a natural extract, bergamot oil terpenes are derived through cold-pressing and steam distillation of bergamot fruit peels. More detailed chemical data is cataloged in sources such as PubChem. These terpenes serve as a key aroma source in fragrance and flavor industries, valued for their refreshing and floral notes.

Occurrence, Applicability & Potential Uses

Bergamot oil terpenes naturally occur in the peel of the bergamot fruit, a citrus hybrid cultivated mainly in the Mediterranean region. Their applications focus principally on use as fragrance agents in perfumes, colognes, and personal care products. According to IFRA (Global) guidelines, the use concentration of bergamot oil terpenes in fragrance formulations has specified limits to manage phototoxicity risks associated with compounds like bergapten. Besides perfumery, these terpenes are applied as odorants to emulate various citrus and floral notes such as lemon, mandarin, orange, and verbena, serving as replacements or enhancers in formulations. They also have limited application in flavoring, notably to mimic citrus peels and related nuances, although they are not generally recommended for flavor use due to regulatory constraints.

Physico-Chemical Properties Summary

Bergamot oil terpenes exhibit a specific gravity ranging from 0.84 to 0.86 at 25 °C and a refractive index between 1.469 and 1.473 at 20 °C. The flash point temperature measured by the Tag Closed Cup method is approximately 43 °C, indicating moderate flammability precautions are necessary during handling. The terpenes demonstrate solubility in alcohol, fixed oils, and mineral oil, but show limited solubility in water. Their shelf life is generally around 12 months when stored in cool, dry conditions with containers sealed and protected from heat and light. These physico-chemical characteristics influence their stability, blending behavior, and suitability for incorporation into various fragrance matrices and carrier systems.

FAQ

What are bergamot oil terpenes and where do they come from?
Bergamot oil terpenes are volatile aromatic compounds extracted from the peel oil of the bergamot orange, Citrus x bergamia. They belong to the class of terpenes and terpenoids, absorbing a characteristic floral and citrus aroma. The oleoresin is typically obtained through cold pressing or steam distillation of bergamot fruit peels, making them a natural product widely used in fragrance formulations.
How are bergamot oil terpenes used and what regulations apply to them?
These terpenes are primarily used as fragrance agents in perfumes, colognes, and cosmetic products to impart citrus and floral notes. Application concentrations are regulated by bodies such as IFRA (Global) to limit phototoxic components like bergapten, ensuring consumer safety especially in sun-exposed applications. Usage limits commonly allow up to 10% bergamot oil terpenes in fragrance concentrates. Although sometimes explored for flavor enhancement, they are generally not approved for flavor use under current guidelines.
What safety information is important when handling bergamot oil terpenes?
Bergamot oil terpenes are not classified under OSHA hazard communication standards for toxicity or hazards. However, IFRA standards highlight the potential for dermal sensitization and phototoxicity linked to trace compounds such as bergapten. Proper storage in sealed containers, away from heat and direct light, helps maintain product stability. Users should apply recommended use levels and handle the material with standard fragrance industry precautions to minimize sensitization risks.

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Other Information

Export Tariff Code:3301.11.0000
Wikipedia:View
FAO:BASIC PRINCIPLES OF STEAM DISTILLATION

General Material Information

Preferred name bergamot oil terpenes
Trivial Name Terpenes and Terpenoids, bergamot-oil
Short Description citrus x bergamia peel oil terpenes
CAS Number 68917-80-6
FDA UNII Search
Synonyms
  • bergamot oil terpenes italian
  • bergamot terpenes
  • citrus aurantium bergamia peel oil terpenes
  • citrus bergamia peel oil terpenes
  • citrus x bergamia peel oil terpenes
  • oil bergamot terpenes
  • citrus × bergamia peel oil terpenes
  • Terpenes and Terpenoids, bergamot-oil

PhysChem Properties

Material listed in food chemical codex No
Specific gravity @ 25 °C
Pounds per Gallon 6.99 to 7.156
Refractive Index 1.469 to 1.473 @ 20 °C
Flash Point TCC Value 43.33 °C TCC
Shelf life 12 months (or longer if stored properly.)
Storage notes Store in cool, dry place in tightly sealed containers, protected from heat and light.
Solubility
alcohol Yes
fixed oils Yes
mineral oil Yes
water, 20.12 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Floral
floral, bergamot
General comment At 100.00 %. floral bergamot

Occurrences

Safety Information

Safety information

Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
IFRA Critical Effect:
Dermal sensitization and systemic toxicity
IFRA fragrance material specification:
Where the bergapten (5-methoxypsoralen) content of all relevant oils present in a compound has been determined, it is recommended that for applications on areas of skin exposed to sunshine, excluding bath preparations, soaps and other products which are washed off the skin, the total level of bergapten in the consumer products should not exceed 0.0015% (15 ppm). This is equivalent to 0.0075% (75 ppm) in a fragrance compound used at 20% in the consumer product. Where the level of bergapten has not been determined by appropriate methods, the limits specified in the guidelines on individual oils should apply. In those cases, where such oils are used in combination with other phototoxic ingredients, the additive effect has to be taken into consideration and the use levels have to be reduced accordingly. The sum of the concentrations of all phototoxic fragrance ingredients, expressed in % of their recommended maximum level in the consumer product, shall not exceed 100.
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
citral Max. Found: 0.1 % and Reason: Sensitization
Recommendation for bergamot oil terpenes usage levels up to:
10.0000 % in the fragrance concentrate.
Recommendation for bergamot oil terpenes flavor usage levels up to:
not for flavor use.

Safety references

EPI System: View
EPA Substance Registry Services (TSCA):68917-80-6
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WISER:UN 2319
citrus × bergamia peel oil terpenes
Chemidplus:0068917806