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sweet petitgrain oil

Sweet petitgrain oil is a citrus-scented essential oil obtained from orange leaves, valued for its floral and citrus aroma and used in flavor and fragrance applications.

General Material Description

Sweet petitgrain oil is an essential oil extracted from the leaves of the Citrus sinensis L. Osbeck, commonly known as sweet orange. It is characterized by a clear to pale-colored liquid with a distinctive citrus and floral aroma, often described as fresh and green with petitgrain nuances. The oil is sometimes referenced under various synonyms such as sweet orange leaf oil, orange leaf oil, and Fructus citri sinensis essential oil. Classified as an essential oil, it is sourced through steam distillation of the orange tree's leaves and twigs rather than the fruit rind, differentiating it from sweet orange peel oil. It is widely used in flavor and fragrance industries due to its characteristic odor profile and versatile sensory attributes. For scientific reference, see its PubChem entry under citrus sinensis peel oil.

Occurrence, Applicability & Potential Uses

Sweet petitgrain oil naturally occurs in the leaves and twigs of the sweet orange tree (Citrus sinensis), contributing to the plant's aromatic profile. It has found broad applicability as a flavoring agent and fragrance ingredient, leveraged for its fresh citrus and floral scent. The oil is integrated into perfumes, personal care products, and food flavorings, where it imparts subtle citrus notes complemented by its petitgrain character. The FEMA (US) Expert Panel has evaluated sweet petitgrain oil and assigned it FEMA number 2825, confirming its general recognition as safe (GRAS) for flavor use within specified limits. Additionally, IFRA (Global) provides usage guidelines to ensure safety in fragrance applications, particularly regarding sensitization risks associated with some natural components. Its application potential also includes aromatherapy and other sensory uses, attributable to its appealing olfactory properties.

Physico-Chemical Properties Summary

Sweet petitgrain oil exhibits solubility in alcohol but is insoluble in water, features significant for its formulation in various solvent systems. This essential oil is a complex mixture predominantly composed of monoterpenes and oxygenated compounds, which contribute not only to its citrus-floral aroma but also influence its volatility and stability. Its relatively low water solubility dictates its use in oil-based or alcohol-based products rather than aqueous solutions. The oil's physicochemical characteristics, including its vapor pressure and partitioning behavior, affect its olfactory impact and evaporation rates in consumer products. Proper handling requires control of oxidation, as its linalool-rich composition can lead to peroxide formation if exposed to air without antioxidants, thus potentially altering sensory qualities and safety profiles.

FAQ

What is sweet petitgrain oil and what are its main properties?
Sweet petitgrain oil is an essential oil obtained by steam distillation of the leaves and small branches of the sweet orange tree (Citrus sinensis). It is known for its fresh, citrusy, and floral scent, often described as having petitgrain characteristics. The oil is a clear to pale liquid soluble in alcohol but insoluble in water and is used for its aromatic and flavoring qualities in various applications. It carries multiple synonyms reflecting its botanical origin, such as sweet orange leaf oil and orange peel oil, although it is chemically and organoleptically distinct from peel-derived oils.
How is sweet petitgrain oil used and where does it naturally occur?
Sweet petitgrain oil naturally occurs in the leaves and twigs of the sweet orange tree. It is widely used as a flavoring agent and fragrance ingredient in perfumes, cosmetics, and food flavor formulations. The oil imparts a citrusy and floral aroma, making it valuable in creating fresh, green, and vibrant scent profiles. Its use is guided by safety standards such as those established by FEMA (US) and IFRA (Global), ensuring its application within safe concentration limits in consumer products.
What are the regulations and safety considerations for sweet petitgrain oil?
Sweet petitgrain oil is evaluated by the FEMA (US) Expert Panel and assigned FEMA number 2825, attesting to its general recognition as safe (GRAS) when used within established limits for flavoring purposes. IFRA (Global) has issued guidelines addressing sensitization concerns, recommending that usage levels in fragrance concentrates do not exceed 8%. The oil may contain components such as citronellol and citral, which are restricted to certain maximum levels to minimize sensitization risk. Additionally, maintaining low peroxide values through antioxidant addition is recommended to preserve product stability and safety. No significant hazard classifications have been identified under OSHA standards.

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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General Material Information

Preferred name sweet petitgrain oil
Trivial Name Sweet orange peel oil, petitgrain
Short Description sweet petitgrain orange oil
CAS Number 8008-57-9
FEMA Number 2825
ECHA Number 600-006-9
FDA UNII Search
MDL MFCD00147798
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
Synonyms
  • sweet orange leaf oil
  • orange leaf oil
  • Sweet orange peel oil
  • Oils, orange, sweet
  • Sweet orange oil
  • Oil of sweet orange
  • Essential oils, orange, sweet
  • Oils, essential, orange, sweet
  • Citrus sinensis peel oil
  • Oils, sweet orange peel
  • Orange oil
  • Essential oils, orange
  • Fructus citri sinensis essential oil

PhysChem Properties

Material listed in food chemical codex No
Solubility
alcohol Yes
water No

Organoleptic Properties

Odor Type: Citrus
floral, petitgrain
General comment At 100.00 %. floral petitgrain
Flavor Type: Citrus
petitgrain
General comment Petitgrain

Safety Information

Safety information

Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
IFRA Critical Effect:
Sensitization
IFRA fragrance material specification:
Linalool and natural products known to be rich in linalool, such as bois de rose, coriander or ho wood oil, should only be used when the level of peroxides is kept to the lowest practical level. It is recommended to add antioxidants at the time of production of the raw material. The addition of 0.1% BHT or alpha-tocopherol for example has shown great efficiency. The maximum peroxide level for products in use should be 20 mmol/l.
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
citronellol Max. Found:
(E)-2-hexen-1-al Max. Found: trace to
citral Max. Found:
Recommendation for sweet petitgrain oil usage levels up to:
8.0000 % in the fragrance concentrate.
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -430.00000
beverages(nonalcoholic): -210.00000
beverages(alcoholic): -5.00000
breakfast cereal: -49.00000
cheese: --
chewing gum: -4200.00000
condiments / relishes: -32.00000
confectionery froastings: -190.00000
egg products: --
fats / oils: --
fish products: --
frozen dairy: -330.00000
fruit ices: -330.00000
gelatins / puddings: -1300.00000
granulated sugar: --
gravies: --
hard candy: -1000.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
citrus sinensis l. osbeck leaf oil
Chemidplus:0008008579
EPA/NOAA CAMEO:hazardous materials
RTECS:RI8600000 for cas# 8008-57-9