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siam benzoin resin

Siam benzoin resin is a natural balsamic-flavored resin from Styrax tonkinensis, widely applied in flavor and fragrance formulations.

General Material Description

Siam benzoin resin is a natural balsamic resin obtained from the Styrax tonkinensis tree. It forms as a fragrant, typically brownish solid or crystalline gum with a distinctive sweet vanilla and woody odor profile. The resin is known by several synonyms including anthostyrax tonkinensis resin and benzoe siam. In sensory terms, it exhibits a medium-strength balsamic scent with powdery undertones, making it valuable in perfumery and flavouring. Chemically classified as a natural gum resin, it is sourced primarily through the tapping of Styrax tonkinensis trees native to Southeast Asia. For authoritative reference, it links to PubChem. Its sensory and chemical properties support its use as a flavoring and fragrance agent derived from natural sources.

Occurrence, Applicability & Potential Uses

Siam benzoin resin occurs naturally as a secretion from the Styrax tonkinensis tree, prevalent in regions such as Southeast Asia. It is utilized extensively in fragrance formulations due to its characteristic sweet, vanilla-like balsamic aroma, which also provides fixative properties enhancing scent longevity. The resin substitutes for benzoin absolute in both perfumery and flavoring applications. It appears in complex scent profiles including floral, woody, oriental, and incense-type fragrances as well as in flavor notes. Its usage conforms to standards such as FEMA (US) guidelines governing flavor and fragrance materials. Additional roles include incorporation in products like soaps and classic perfume compositions such as Je Reviens, Shalimar, and Vol de Nuit.

Physico-Chemical Properties Summary

Siam benzoin resin exhibits moderate solubility characteristics, being soluble in benzyl benzoate and slightly soluble in water under ambient conditions (estimated 11.61 mg/L at 25 °C) but insoluble in bulk water. Its flash point is approximately 212 °F (100 °C), indicating a moderate risk concerning flammability during handling. The resin's physical state as a semi-solid or crystalline gum facilitates easy formulation into oils and solvents commonly used in fragrance and flavor preparations. These physico-chemical traits influence its compatibility with other formulation components and determine appropriate handling, storage, and usage protocols within industrial and consumer products.

FAQ

What is siam benzoin resin and what are its main characteristics?
Siam benzoin resin is a natural balsamic resin sourced from the Styrax tonkinensis tree, notable for its medium-strength sweet vanilla and woody aroma. It appears as a crystalline or gum-like solid and is widely used in flavor and fragrance applications due to its distinctive balsamic scent. Known synonyms include benzoin siam resin and anthostyrax tonkinensis resin. Its fragrance profile includes sweet, powdery notes making it a valued material in perfumery and flavor formulations.
How is siam benzoin resin obtained and what are its typical uses?
The resin is collected through tapping the Styrax tonkinensis tree, which exudes the fragrant gum that hardens into crystallized resin. It serves primarily as a flavoring and fragrance agent, often employed as a fixative to prolong scent duration in perfumes. The resin acts as a replacement for benzoin absolute in various applications, contributing to floral, oriental, and woody scent accords. It also finds use in cosmetic products like soaps and has traditional roles in classic perfume compositions.
What safety and regulatory considerations apply to the use of siam benzoin resin?
Siam benzoin resin is classified under standards such as FEMA (US), where it is recognized for use in flavor and fragrance formulations with recommended usage levels in fragrance concentrates up to 8%. It is designated as harmful if swallowed (European classification Xn; R22) and requires handling precautions such as avoiding eye contact and the use of protective clothing. Regulatory resources including RIFM and IFRA provide safety and use guidelines, and the resin is listed on various chemical registries. Safety data indicate precautions but do not report acute toxicity via skin or inhalation under normal use.

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Other Information

FDA Substances Added to Food (formerly EAFUS):View
Export Tariff Code:3301.30.0000
FDA Listing of Food Additive Status:View
Wikipedia:View
Wikipedia2:View2
FAO:BENZOE TONKINENSIS
FAO:SOFT RESINS AND BALSAMS

General Material Information

Trivial Name siam benzoin resin
Short Description benzoin resin
CAS Number 9000-72-0
FEMA Number 2133
ECHA Number 232-556-7
FDA UNII Search
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 9000-05-9 ; BENZOIN, RESIN (STYRAX SPP.)
Synonyms
  • anthostyrax tonkinensis resin
  • siam benzoin crystals
  • siam benzoin gum
  • benzoin liquid resin
  • benzoin resin
  • benzoin siam crystals
  • benzoin siam liquid resin 50% in BB
  • benzoin siam resin
  • benzoin siam resin (styrax tonkinensis craib ex hartwiss)
  • styrax hypoglaucus resin
  • styrax macrothyrsus resin
  • styrax subniveus resin
  • styrax tonkinensis resin
  • styrax tonkinensis craib ex hartwiss resin
  • Resins, Siam gum benzoin
  • Gum benzoin, Siam
  • Indochina benzoin
  • Siam benzoin
  • Tong-King benzoin
  • Benzoin gum, Siam
  • Siam gum benzoin
  • Gums and Mucilages, Siam gum benzoin
  • Gums, Siam gum benzoin
  • Benzoe Siam

PhysChem Properties

Material listed in food chemical codex No
Flash Point TCC Value 100 °C TCC
Solubility
benzyl benzoate Yes
water, 11.61 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Balsamic
sweet, vanilla, balsamic, woody, powdery
Odor strength medium
Substantivity 400 hour(s) at 100.00 %
General comment At 100.00 %. sweet vanilla balsam woody powdery
Flavor Type: Balsamic
benzoin, balsamic, spicy
General comment Benzoin

Occurrences

Safety Information

Safety information

European information :
Most important hazard(s):
Xn - Harmful.
R 22 - Harmful if swallowed.
S 02 - Keep out of the reach of children.
S 25 - Avoid contact with eyes.
S 36 - Wear suitable protective clothing.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
Recommendation for siam benzoin resin usage levels up to:
8.0000 % in the fragrance concentrate.
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -26.00000
beverages(nonalcoholic): -15.00000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: -110.00000
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -5.10000
fruit ices: -5.10000
gelatins / puddings: -10.00000
granulated sugar: --
gravies: --
hard candy: -8.70000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

EPI System: View
EPA Substance Registry Services (TSCA):9000-72-0
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
styrax tonkinensis craib ex hartwiss resin
Chemidplus:0009000720