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tolu balsam resin

Tolu balsam resin is an oleoresin obtained from the bark of the balsam tolu tree, valued for its medium-strength balsamic odor and application in flavor and fragrance industries.

General Material Description

Tolu balsam resin is an oleoresin extracted from the bark exudate of the balsam tolu tree, scientifically known as Myroxylon balsamum L., belonging to the Leguminosae family. This resin appears as a complex natural mixture characterized by a medium-strength balsamic odor with sweet, woody, and balsam notes. Its chemical composition is non-specific due to its complex plant origin. It is also known under several synonyms such as Myroxylon toluiferum resin and balsam of tolu. Tolu balsam resin is primarily sourced from the tropical regions where the balsam tolu tree grows, and it is obtained through incision and collection of the tree’s bark exudate. For further chemical reference, Tolu balsam is linked to the PubChem database. This resin serves as a raw material in flavor and fragrance applications due to its distinctive sensory properties.

Occurrence, Applicability & Potential Uses

Tolu balsam resin naturally occurs as a secretion from the bark of the Myroxylon balsamum L. tree in tropical regions of Central and South America. In practical applications, it is widely utilized as a flavor and fragrance agent, appreciated for contributing a medium-strength balsamic odor and flavor. It finds use in tobacco, balsam, stephanotis, and other fragrance formulations, as well as in flavoring components. Additionally, it has cosmetic applications serving as a film former, hair conditioning agent, and general fragrance ingredient. Regulatory guidelines, including IFRA (Global) standards, govern its usage levels to manage sensitization risks tied to certain resin components.

Physico-Chemical Properties Summary

Tolu balsam resin exhibits solubility in various solvents, including ethyl alcohol, castor oil, mineral oil, and water with an estimated solubility of 9.269 mg/L at 25 °C. Its compatibility with lipophilic and hydrophilic media allows versatility in formulation development. The resin maintains stability across a pH range of approximately 4.5 to 9.5, which supports its use in diverse product types. The oleoresin's medium balsamic odor has a substantivity of about 400 hours at 20% concentration, underscoring its persistence in fragrance applications. Such physicochemical traits influence its performance when integrated into flavor or cosmetic products, affecting texture, scent longevity, and solubilization.

FAQ

What is tolu balsam resin and where does it come from?
Tolu balsam resin is a natural oleoresin obtained from the bark exudate of the balsam tolu tree, Myroxylon balsamum L., native to tropical areas of Central and South America. It is collected by tapping the tree bark, producing a resinous substance renowned for its balsamic odor.
How is tolu balsam resin used in industry and what are its sensory characteristics?
Industrially, tolu balsam resin serves as a flavor and fragrance agent, imparting a medium-strength balsamic aroma with sweet and woody nuances. It is used in tobacco, various fragrance blends, and cosmetic products as a film former and hair conditioning agent. Its solubility in diverse solvents facilitates formulation in both aqueous and oily systems.
What are the regulatory considerations and safety information associated with tolu balsam resin?
Regulatory frameworks, including IFRA (Global), regulate the use of tolu balsam resin to limit exposure to sensitizing components such as cinnamaldehyde and eugenol. It is classified as an irritant with the potential to cause skin sensitization. Usage levels in fragrance concentrates are recommended up to 4% to minimize risk. While comprehensive toxicity data are limited, precautionary measures include wearing protective clothing and avoiding direct skin contact.

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Other Information

FDA Substances Added to Food (formerly EAFUS):View
Export Tariff Code:3301.30.0000
Wikipedia:View

General Material Information

Preferred name tolu balsam resin
Trivial Name Tolu balsam
Short Description oleoresin (balsam tolu) obtained from the bark exudate of balsam tolu tree, myroxylon balsamum l., leguminosae
Formula unspecified
CAS Number 9000-64-0
FEMA Number 3070
ECHA Number 232-550-4
FDA UNII Search
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 9000-64-0 ; TOLU, BALSAM, GUM (MYROXYLON SPP.)
Synonyms
  • myroxylon toluiferum resin
  • oleoresin (balsam tolu) obtained from the bark exudate of balsam tolu tree, myroxylon balsamum l., leguminosae
  • tolu balsam gum
  • tolu balsam soluble resin
  • tolu balsam soluble resin 50% in BB
  • tolu balsam soluble resin 50% in DEP
  • myroxylon toluiferum l. resin
  • Tolu balsam
  • Balsams, tolu
  • Balsam tolu
  • Tolu
  • Tolu balsams
  • Balsam of tolu
  • Myroxylon balsamum balsam
  • Myroxylon toluiferum balsam

PhysChem Properties

Material listed in food chemical codex No
Solubility
biosoft ea-8, 9% Yes
castor oil, Yes
chloroform, .07% Yes
dimethyl sulfoxide, 17% Yes
duponol waqe, 24% Yes
ethyl alcohol 40a, 19% Yes
isopropyl alcohol, .8% Yes
isopropyl myristate, Yes
isopropyl palmitate, Yes
mineral oil, light Yes
olive oil, Yes
poly-solv de, 12% Yes
poly-solv em, 32% Yes
polyethylene glycol 400, 12% Yes
propylene glycol, 13% Yes
sipon lls, 31% Yes
solulan 98, 1% Yes
tween 40, 4% Yes
water, 53% Yes
water, 9.269 mg/L @ 25 °C (est) Yes
Stability
ph from 4.5 - 9.5 Unspecified

Organoleptic Properties

Odor Type: Balsamic
sweet, balsamic, woody
Odor strength medium
Substantivity 400 hour(s) at 20.00 %
Luebke, William tgsc, (1981) At 100.00 %. sweet balsam woody
Flavor Type: Balsamic
tolu balsam
General comment Tolu balsam

Occurrences

Potential Uses

Applications
Odor purposes Balsam , Stephanotis , Tobacco , Tolu balsam
Cosmetic purposes Film formers , Fragrance , Hair conditioning

Safety Information

Safety information

European information :
Most important hazard(s):
Xi - Irritant
R 43 - May cause sensitisation by skin contact.
S 02 - Keep out of the reach of children.
S 36 - Wear suitable protective clothing.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
cinnamaldehyde Max. Found: 0.1 % and Reason: Sensitization
cinnamyl alcohol Max. Found: 0.03 % and Reason: Sensitization
eugenol Max. Found: 0.02 % and Reason: Sensitization
benzaldehyde Max. Found: 0.01 % and Reason: Sensitization
benzyl alcohol Max. Found: 0.04 % and Reason: Sensitization
benzyl benzoate Max. Found: 2.10 % and Reason: Sensitization
benzyl cinnamate Max. Found: 0.60 % and Reason: Sensitization
isoeugenol Max. Found: 0.02 % and Reason: Sensitization
Recommendation for tolu balsam resin usage levels up to:
4.0000 % in the fragrance concentrate.
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -8.00000
beverages(nonalcoholic): -2.60000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -13.00000
fruit ices: -13.00000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -5.20000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

EPI System: View
Daily Med:search
EPA Substance Registry Services (TSCA):9000-64-0
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
myroxylon toluiferum l. resin
Chemidplus:0009000640