Preferred name | nonanal (aldehyde C-9) |
Trivial Name | Nonanal |
Short Description | pelargonaldehyde |
Formula | C9 H18 O |
CAS Number | 124-19-6 |
Deleted CAS Number | 918959-88-3 |
FEMA Number | 2782 |
Flavis Number | 5.025 |
ECHA Number | 204-688-5 |
FDA UNII | 2L2WBY9K6T |
Nikkaji Number | J5.547F |
Beilstein Number | 1236701 |
MDL | MFCD00007030 |
COE Number | 114 |
xLogP3-AA | 3.30 (est) |
Bio Activity Summary | External link |
NMR Predictor | External link |
JECFA Food Flavoring | 101 nonanal |
FDA Patent | No longer provide for the use of these seven synthetic flavoring substances |
FDA Mainterm | 124-19-6 ; NONANAL |
Synonyms |
|
Google Scholar | Start search |
Google Books | Start search |
Google Patents | Start search |
Perfumer & Flavorists | Start search |
EU Patents | Start search |
PubMeb | Start search |
NCBI | Start search |
nonanal | |
NIST Chemistry WebBook: | Search Inchi |
Canada Domestic Sub. List: | 124-19-6 |
Pubchem (cid): | 31289 |
Pubchem (sid): | 134975056 |
Flavornet: | 124-19-6 |
Pherobase: | View |
(IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
Videos: | The Periodic Table of Videos |
tgsc: | Atomic Weights use for this web site |
(IUPAC): | Periodic Table of the Elements |
FDA Substances Added to Food (formerly EAFUS): | View |
CHEBI: | View |
CHEMBL: | View |
KEGG (GenomeNet): | C17253 |
HMDB (The Human Metabolome Database): | Search |
FooDB: | FDB003303 |
Export Tariff Code: | 2912.19.5000 |
Typical G.C. | |
VCF-Online: | VCF Volatile Compounds in Food |
ChemSpider: | View |
Wikipedia: | View |
Formulations/Preparations: grade: technical, fcc. |
Material listed in food chemical codex | Yes |
Molecular weight | 142.24165344238 |
Specific gravity | @ 25 °C |
Pounds per Gallon | 6.815 to 6.881 |
Specific gravity | @ 20 °C |
Pounds per Gallon | 6.831 to 6.898 |
Refractive Index | 1.421 to 1.426 @ 20 °C |
Boiling Point | 92 to 93°C @ 22 mm Hg |
Boiling Point | 191 to 193°C @ 760 mm Hg |
Acid Value | 10 max KOH/g |
Vapor Pressure | 0.532 mmHg @ 25 °C |
Flash Point TCC Value | 63 °C TCC |
logP (o/w) | 3.461 est |
Shelf life | 12 months (or longer if stored properly.) |
Storage notes | Store in cool, dry place in tightly sealed containers, protected from heat and light. store under nitrogen. |
Solubility | |
alcohol | Yes |
dipropylene glycol | Yes |
fixed oils | Yes |
paraffin oil, slightly cloudy | Yes |
propylene glycol | Yes |
water, 96 mg/L @ 25 °C (exp) | Yes |
water, 131.6 mg/L @ 25 °C (est) | Yes |
glycerin | No |
Stability | |
cream | Unspecified |
deodorant spray | Unspecified |
hair spray | Unspecified |
non-discoloring in most media | Unspecified |
powder | Unspecified |
shampoo | Unspecified |
Odor Type: Aldehydic | |
waxy, aldehydic, rose, fresh, orris, orange peel, fatty, peely, citrus, green, lemon peel, cucumber | |
Odor strength | high , recommend smelling in a 10.00 % solution or less |
Substantivity | 276 hour(s) at 100.00 % |
Luebke, William tgsc, (1982) | At 10.00 % in dipropylene glycol. waxy aldehydic rose fresh orris orange peel fatty peely |
Mosciano, Gerard P&F 26, No. 3, 80, (2001) | At 1.00 %. Waxy, aldehydic, citrus, with a fresh slightly green lemon peel like nuance, and a cucumber fattiness |
Flavor Type: Aldehydic | |
aldehydic, citrus, cucumber, melon, rindy, potato raw potato, oily, nutty, coconut | |
Mosciano, Gerard P&F 26, No. 3, 80, (2001) | At 3.00 - 10.00 ppm. Effervescent, aldehydic citrus, cucumber and melon rindy, with raw potato and oily nutty and coconut like nuances |
For an intense orange character in citrus and other flavors. | Fatty citrus |
General comment | Waxy fatty citrus peel floral green |
(data available) |
Applications | |
Odor purposes | Acacia , Aldehydic , Apricot , Baby powder , Cedar , Cinnamon , Citrus , Clary sage oil replacer , Coconut , Coconut tropical coconut , Cologne , Cucumber , Floral , Geranium , Ginger , Green grass , Heliotrope , Jasmin , Lemon , Lemongrass , Lily , Lime , Magnolia , Mandarin , Mango , Melon , Mimosa , Neroli , Orange , Orange bitter orange peel , Orange blossom , Orchid , Orris , Peach , Petitgrain , Poppy red poppy , Powder , Rain , Reseda , Rose , Rose red rose , Tangerine , Tea green tea , Tuberose , Ylang ylang |
Flavoring purposes | Macadamia , Orange bitter orange peel , Walnut |
Other purposes | Aimant , Amour-amour , Diffusion , Joy |
Cosmetic purposes | Perfuming agents |
Preferred SDS: View | |
European information : | |
Most important hazard(s): | |
Xi N - Irritant, Dangerous for the environment. | |
R 38 - Irritating to skin. R 52/53 - Harmful to qauatic organisms, may cause long-term adverse effects in the aquatic environment. S 02 - Keep out of the reach of children. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing. S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet. | |
Hazards identification | |
Classification of the substance or mixture | |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
Flammable liquids (Category 4), H227 Skin irritation (Category 2), H315 Eye irritation (Category 2A), H319 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 | |
GHS Label elements, including precautionary statements | |
Pictogram | ![]() |
Signal word | Warning |
Hazard statement(s) | |
H227 - Combustible liquid H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation | |
Precautionary statement(s) | |
P210 - Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash skin thouroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P302 + P352 - IF ON SKIN: wash with plenty of soap and water. P304 + P340 - IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P321 - Specific treatment (see supplemental first aid instructions on this msds). P332 + P313 - IF SKIN irritation occurs: Get medical advice/attention. P337 + P313 - IF eye irritation persists: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P403 + P233 - Store in a well-ventilated place. Keep container tightly closed. P403 + P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/ container to an approved waste disposal plant. | |
Human Experience: | |
1 % solution: no irritation or sensitization. | |
Oral/Parenteral Toxicity: | |
oral-rat LD50 > 5000 mg/kg National Technical Information Service. Vol. OTS0534476 | |
Dermal Toxicity: | |
skin-rabbit LDLo 5000 mg/kg National Technical Information Service. Vol. OTS0534468 | |
Inhalation Toxicity: | |
inhalation-rat LC > 9500 mg/m3/4H National Technical Information Service. Vol. OTS0534471 |
Category: | |||
flavor and fragrance agents | |||
RIFM Fragrance Material Safety Assessment: Search | |||
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
Recommendation for nonanal (aldehyde C-9) usage levels up to: | |||
1.0000 % in the fragrance concentrate. | |||
Structure Class: | I | ||
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). | |||
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library | |||
publication number: 3 | |||
Click here to view publication 3 | |||
average usual ppm | average maximum ppm | ||
baked goods: | - | 2.30000 | |
beverages(nonalcoholic): | - | 1.30000 | |
beverages(alcoholic): | - | - | |
breakfast cereal: | - | - | |
cheese: | - | - | |
chewing gum: | 0.20000 | 38.00000 | |
condiments / relishes: | - | - | |
confectionery froastings: | - | - | |
egg products: | - | - | |
fats / oils: | - | - | |
fish products: | - | - | |
frozen dairy: | - | 1.30000 | |
fruit ices: | - | 1.30000 | |
gelatins / puddings: | - | 6.00000 | |
granulated sugar: | - | - | |
gravies: | - | - | |
hard candy: | - | 4.10000 | |
imitation dairy: | - | - | |
instant coffee / tea: | - | - | |
jams / jellies: | - | - | |
meat products: | - | - | |
milk products: | - | - | |
nut products: | - | - | |
other grains: | - | - | |
poultry: | - | - | |
processed fruits: | - | - | |
processed vegetables: | - | - | |
reconstituted vegetables: | - | - | |
seasonings / flavors: | - | - | |
snack foods: | - | - | |
soft candy: | - | - | |
soups: | - | - | |
sugar substitutes: | - | - | |
sweet sauces: | - | - |
European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 3, Revision 1 (FGE.03Rev1): Acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated or unsaturated aldehydes, an ester of a hemiacetal and an orthoester of formic acid, from chemical groups 1, 2 & 4 Commission Regulation (EC) No 1565/2000 of 18 July 2000) [1] - Scientific Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)on a request from the Commission View page or View pdf |
Flavouring Group Evaluation 61 (FGE.61): Consideration of aliphatic acyclic acetals evaluated by JECFA (57th meeting) structurally related to acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated aldehydes, and an orthoester of formic acid evaluated by EFSA in FGE.03 (2004) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) View page or View pdf |
Flavouring Group Evaluation 61, Revision 1 (FGE.61Rev1): Consideration of aliphatic acetals evaluated by JECFA (57th meeting) structurally related to acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated aldehydes and one orthoester of formic acid evaluated View page or View pdf |
Scientific Opinion on the safety and efficacy of straight-chain primary aliphatic alcohols/aldehydes/acids, acetals and esters with esters containing saturated alcohols and acetals containing saturated aldehydes (chemical group 1) when used as flavourings for all animal species View page or View pdf |
EPI System: View |
Chemical Carcinogenesis Research Information System:Search |
AIDS Citations:Search |
Cancer Citations:Search |
Toxicology Citations:Search |
EPA Substance Registry Services (TSCA):124-19-6 |
EPA ACToR:Toxicology Data |
EPA Substance Registry Services (SRS):Registry |
Laboratory Chemical Safety Summary :31289 |
National Institute of Allergy and Infectious Diseases:Data |
WISER:UN 3082 |
WGK Germany:2 |
nonanal |
Chemidplus:0000124196 |
EPA/NOAA CAMEO:hazardous materials |
RTECS:RA5700000 for cas# 124-19-6 |