| Preferred name | strawberry glycidate 2 |
| Trivial Name | ethyl 3-phenyloxirane-2-carboxylate |
| Short Description | ethyl 3-phenylglycidate |
| Formula | C11 H12 O3 |
| CAS Number | 121-39-1 |
| CAS Number | 121-39-1 (RR) |
| CAS Number | 121-39-1 (RS) |
| CAS Number | 2272-55-1 |
| CAS Number | 121-39-1 (SS) |
| FEMA Number | 2454 |
| Flavis Number | 16.018 |
| ECHA Number | 204-467-3 |
| FDA UNII | 2VVS520ZWM |
| Nikkaji Number | J122.448D |
| Beilstein Number | 0163394 |
| MDL | MFCD00005123 |
| COE Number | 11844 |
| xLogP3-AA | 1.70 (est) |
| Bio Activity Summary | External link |
| NMR Predictor | External link |
| JECFA Food Flavoring | 1576 ethyl 3-phenylglycidate |
| FDA Patent | No longer provide for the use of these seven synthetic flavoring substances |
| FDA Mainterm | 121-39-1 ; ETHYL 3-PHENYLGLYCIDATE |
| Synonyms |
|
| Google Scholar | Start search |
| Google Books | Start search |
| Google Patents | Start search |
| Perfumer & Flavorists | Start search |
| EU Patents | Start search |
| PubMeb | Start search |
| NCBI | Start search |
| ethyl 3-phenyloxirane-2-carboxylate | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 121-39-1 |
| Pubchem (cid): | 8469 |
| Pubchem (sid): | 134975712 |
| ethyl (2R,3R)-3-phenyloxirane-2-carboxylate | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 121-39-1 |
| Pubchem (cid): | 719701 |
| Pubchem (sid): | 35396986 |
| ethyl (2R,3S)-3-phenyloxirane-2-carboxylate | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 121-39-1 |
| Pubchem (cid): | 719704 |
| Pubchem (sid): | 35396989 |
| ethyl (2S,3R)-3-phenyloxirane-2-carboxylate | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 2272-55-1 |
| Pubchem (cid): | 256043 |
| Pubchem (sid): | 120976 |
| ethyl (2S,3S)-3-phenyloxirane-2-carboxylate | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 121-39-1 |
| Pubchem (cid): | 719706 |
| Pubchem (sid): | 35396991 |
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| FDA Substances Added to Food (formerly EAFUS): | View |
| CHEMBL: | View |
| HMDB (The Human Metabolome Database): | HMDB31623 |
| FooDB: | FDB009407 |
| Export Tariff Code: | 2918.99.4700 |
| ChemSpider: | View |
| Material listed in food chemical codex | Yes |
| Molecular weight | 192.21423339844 |
| Specific gravity | @ 25 °C |
| Pounds per Gallon | 9.311 to 9.378 |
| Specific gravity | @ 20 °C |
| Pounds per Gallon | 9.33 to 9.397 |
| Refractive Index | 1.515 to 1.52 @ 20 °C |
| Acid Value | 1 max KOH/g |
| Vapor Pressure | 0.002 mmHg @ 25 °C |
| Flash Point TCC Value | 100 °C TCC |
| logP (o/w) | 2.333 |
| Shelf life | 12 months (or longer if stored properly.) |
| Storage notes | Store in cool, dry place in tightly sealed containers, protected from heat and light. |
| Solubility | |
| alcohol | Yes |
| water, 320.1 mg/L @ 25 °C (est) | Yes |
| water | No |
| Stability | |
| alcoholic lotion | Unspecified |
| antiperspirant | Unspecified |
| deo stick | Unspecified |
| detergent perborate | Unspecified |
| fabric softener | Unspecified |
| liquid detergent | Unspecified |
| shampoo | Unspecified |
| soap | Unspecified |
| Odor Type: Fruity | |
| sweet, strawberry, berry, floral, tropical, honey, rose | |
| Odor strength | medium |
| Substantivity | 312 hour(s) at 100.00 % |
| Luebke, William tgsc, (1992) | At 100.00 %. sweet strawberry berry floral tropical |
| Mosciano, Gerard P&F 19, No. 3, 51, (1994) | Sweet, berry, strawberry, honey, floral and rosy |
| Flavor Type: Fruity | |
| sweet, fruity, berry, fruit dried fruit, floral | |
| Mosciano, Gerard P&F 19, No. 3, 51, (1994) | At 30.00 ppm. Sweet, fruity and berry with a dried fruit and floral nuance |
| General comment | Sweet fruity berry dried fruit floral |
| Applications | |
| Odor purposes | Banana , Currant , Fruit , Honey , Plum , Strawberry |
| Other purposes | Jam |
| Cosmetic purposes | Perfuming agents |
| Preferred SDS: View | |
| European information : | |
| Most important hazard(s): | |
| Xi - Irritant | |
| R 36 - Irritating to eyes. R 52/53 - Harmful to qauatic organisms, may cause long-term adverse effects in the aquatic environment. S 02 - Keep out of the reach of children. S 25 - Avoid contact with eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing. S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet. | |
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| None found. | |
| GHS Label elements, including precautionary statements | |
| Pictogram | |
| Hazard statement(s) | |
| None found. | |
| Precautionary statement(s) | |
| None found. | |
| Human Experience: | |
| 4 % solution: no irritation or sensitization. | |
| Oral/Parenteral Toxicity: | |
| oral-rat LD50 (Shelanski & Moldovan, 1973d) oral-rat LD50 2300 mg/kg Food and Cosmetics Toxicology. Vol. 13, Pg. 101, 1975. | |
| Dermal Toxicity: | |
| Not determined | |
| Inhalation Toxicity: | |
| Not determined | |
| Category: | |||
| flavor and fragrance agents | |||
| RIFM Fragrance Material Safety Assessment: Search | |||
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
| Recommendation for strawberry glycidate 2 usage levels up to: | |||
| 10.0000 % in the fragrance concentrate. | |||
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 97.00 (μg/capita/day) | ||
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 96.00 (μg/capita/day) | ||
| Modified Theoretical Added Maximum Daily Intake (mTAMDI): | ND (μg/person/day) | ||
| Threshold of Concern: | 90 (μg/person/day) | ||
| Structure Class: | III | ||
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). | |||
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library | |||
| publication number: 3 | |||
| Click here to view publication 3 | |||
| average usual ppm | average maximum ppm | ||
| baked goods: | - | 20.00000 | |
| beverages(nonalcoholic): | - | 4.60000 | |
| beverages(alcoholic): | - | - | |
| breakfast cereal: | - | - | |
| cheese: | - | - | |
| chewing gum: | - | - | |
| condiments / relishes: | - | - | |
| confectionery froastings: | - | - | |
| egg products: | - | - | |
| fats / oils: | - | - | |
| fish products: | - | - | |
| frozen dairy: | - | 12.00000 | |
| fruit ices: | - | 12.00000 | |
| gelatins / puddings: | 10.00000 | 70.00000 | |
| granulated sugar: | - | - | |
| gravies: | - | - | |
| hard candy: | - | 18.00000 | |
| imitation dairy: | - | - | |
| instant coffee / tea: | - | - | |
| jams / jellies: | - | - | |
| meat products: | - | - | |
| milk products: | - | - | |
| nut products: | - | - | |
| other grains: | - | - | |
| poultry: | - | - | |
| processed fruits: | - | - | |
| processed vegetables: | - | - | |
| reconstituted vegetables: | - | - | |
| seasonings / flavors: | - | - | |
| snack foods: | - | - | |
| soft candy: | - | - | |
| soups: | - | - | |
| sugar substitutes: | - | - | |
| sweet sauces: | - | - | |
| European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): |
| Flavouring Group Evaluation 31 (FGE.31) - One Epoxide from Chemical Group 32 [1] - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food View page or View pdf |
| Flavouring Group Evaluation 82 (FGE.82)[1] - Consideration of Epoxides evaluated by JECFA (65th meeting) - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food (AFC) View page or View pdf |
| Scientific Opinion on Flavouring Group Evaluation 82, Revision 1 (FGE.82Rev1): Consideration of Epoxides evaluated by the JECFA (65th meeting) View page or View pdf |
| EPI System: View |
| Chemical Carcinogenesis Research Information System:Search |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA Substance Registry Services (TSCA):121-39-1 |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :8469 |
| National Institute of Allergy and Infectious Diseases:Data |
| WGK Germany:2 |
| ethyl 3-phenyloxirane-2-carboxylate |
| Chemidplus:0000121391 |
| EPA/NOAA CAMEO:hazardous materials |
| RTECS:MB4970000 for cas# 121-39-1 |
| ethyl (2R,3R)-3-phenyloxirane-2-carboxylate |
| ethyl (2R,3S)-3-phenyloxirane-2-carboxylate |
| ethyl (2S,3R)-3-phenyloxirane-2-carboxylate |
| ethyl (2S,3S)-3-phenyloxirane-2-carboxylate |