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ethyl cinnamate

Chemical Structure

General Material Information

Preferred name ethyl cinnamate
Trivial Name Ethyl cinnamate
Short Description ethyl 3-phenyl-2-propenoate
Formula C11 H12 O2
CAS Number 103-36-6
FEMA Number 2430
ECHA Number 203-104-6
FDA UNII C023P3M5JJ
Beilstein Number 0775541
MDL MFCD00009189
COE Number 323
Bio Activity Summary External link
NMR Predictor External link
JECFA Food Flavoring 659 ethyl cinnamate
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 103-36-6 ; ETHYL CINNAMATE
Synonyms
  • cinnamic acid ethyl ester
  • ethyl 3-phenyl acrylate
  • ethyl 3-phenyl propenoate
  • ethyl 3-phenyl-2-propenoate
  • ethyl 3-phenylacrylate
  • ethyl 3-phenylprop-2-enoate
  • ethyl benzylidene acetate
  • ethyl beta-phenyl acrylate
  • nat. ethyl cinnamate
  • ethyl cinnamate (natural)
  • ethyl cinnamate FCC
  • ethyl cinnamate natural
  • ethyl phenyl acrylate
  • 3-phenyl-2-propenoic acid ethyl ester
  • 3-phenyl-2-propenoic acid, ethyl ester
  • 3-phenyl-acrylic acid, ethyl ester
  • 2-propenoic acid, 3-phenyl-, ethyl ester
  • 2-Propenoic acid, 3-phenyl-, ethyl ester
  • Cinnamic acid, ethyl ester
  • Ethyl benzylideneacetate
  • 3-Phenyl-2-propenoic acid ethyl ester
  • NSC 6773
  • SemaSORB 9827

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Other Information

(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
CHEMBL:View
KEGG (GenomeNet):C06359
HMDB (The Human Metabolome Database):HMDB33834
FooDB:FDB012002
YMDB (Yeast Metabolome Database):YMDB01689
Export Tariff Code:2916.39.7900
Typical G.C.
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
Wikipedia:View

Suppliers

Advanced Biotech Alfrebro
Ambles Nature et Chimie Anhui Haibei
Apple Flavor & Fragrance Augustus Oils
Aurochemicals Axxence Aromatic
Beijing Lys Chemicals Berjé
BOC Sciences Charkit Chemical
Citrus and Allied Essences Diffusions Aromatiques
Elan Inc. Ernesto Ventós
Excellentia International ExtraSynthese
Fleurchem Foreverest Resources
Global Essence H. Interdonati, Inc.
Indenta Group Indukern F&F
Jiangyin Healthway K.L. Koh Enterprise
Keva Lluch Essence
M&U International Mane
Moellhausen Nagar Haveli Perfumes & Aromatics
Natural Advantage Naturamole
Pearlchem Corporation Penta International
Phoenix Aromas & Essential Oils Prodasynth
R C Treatt & Co Ltd Reincke & Fichtner
Riverside Aromatics Sarchem Laboratories
Sigma-Aldrich SRS Aromatics
Sunaux International Symrise
Taytonn ASCC TCI AMERICA
Tengzhou Xiang Yuan Aroma Chemicals The Good Scents Company
The John D. Walsh Company The Lermond Company
The Perfumers Apprentice U. K. Aromatics and Chemicals
United International Vigon International
WEN International Advanced Biotech. Inc.
Alfrebro LLC/ Archer Daniels Midland Company Augustus Oils Ltd
Axxence Aromatic GmbH Beijing Lys Chemicals Co, LTD.
Berje Inc. Charkit Chemical Corporation
Fleurchem, Inc. Foreverest Resources Ltd.
Global Essence Inc. Indukern, S.A. F&F Ingredients Division
Jiangyin Healthway International Trade Co., Ltd Lluch Essence S.L.
M&U International LLC Moellhausen S.P.A.
Penta International Corporation Riverside Aromatics Ltd.
SRS Aromatics Ltd Symrise AG
Taytonn ASCC Pte Ltd The John D. Walsh Company, Inc
R C Treatt and Co Ltd Qingdao Free Trade Zone United International Co Ltd
Ernesto Ventós S.A.

PhysChem Properties

Material listed in food chemical codex Yes
Molecular weight 176.21504211426
Specific gravity @ 25 °C
Pounds per Gallon 8.695 to 8.72
Refractive Index 1.559 to 1.561 @ 20 °C
Melting Point 6 to 7.5°C @ 760 mm Hg
Boiling Point 271 to 272°C @ 760 mm Hg
Boiling Point 158 to 159°C @ 24 mm Hg
Acid Value 1 max KOH/g
Vapor Pressure 0.00327 mmHg @ 25 °C
Vapor Density 6
Flash Point TCC Value 110 °C TCC
logP (o/w) 2.99
Shelf life 24 months (or longer if stored properly.)
Storage notes Store in cool, dry place in tightly sealed containers, protected from heat and light.
Solubility
alcohol Yes
fixed oils Yes
water, 160.6 mg/L @ 25 °C (est) Yes
water No
glycerin No
Stability
non-discoloring in most media Unspecified

Organoleptic Properties

Odor Type: Balsamic
sweet, balsamic, fruity, spicy, powdery, berry, plum, cinnamyl
Odor strength medium
Substantivity 400 hour(s) at 100.00 %
Luebke, William tgsc, (1982) At 100.00 %. sweet balsam fruity spicy powdery berry plum
Mosciano, Gerard P&F 23, No. 2, 43, (1998) Sweet, balsamic, spice, cinnamic, fruity and powdery
Flavor Type: Balsamic
balsamic, powdery, fruity, berry, spicy, sweet, green
Mosciano, Gerard P&F 23, No. 2, 43, (1998) At 20.00 ppm. Balsamic, powdery, fruity, berry, punch, spice, sweet and green
General comment Sweet fruity spice powdery vanilla floral
Useful in: brown cocoa, brown others, fruity red, fruity yellow, fruity tropical, sweet others, alcoholics. Cinnamon, sweet, balsamic, fruity

Occurrences

Safety Information

Safety information

Preferred SDS: View
European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral (Category 4), H302
GHS Label elements, including precautionary statements
Pictogramexclamation-mark.jpg
Signal word Warning
Hazard statement(s)
H302 - Harmful if swallowed
Precautionary statement(s)
P264 - Wash skin thouroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P301 + P312 - IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P330 - Rinse mouth.
P501 - Dispose of contents/ container to an approved waste disposal plant.
Human Experience:
4 % solution: no irritation or sensitization.
Oral/Parenteral Toxicity:
oral-mouse LD50 4000 mg/kg
Voprosy Pitaniya. Problems of Nutrition. Vol. 33(5), Pg. 48, 1974.

oral-guinea pig LD50 4000 mg/kg
Voprosy Pitaniya. Problems of Nutrition. Vol. 33(5), Pg. 48, 1974.

oral-rat LD50 4000 mg/kg
Voprosy Pitaniya. Problems of Nutrition. Vol. 33(5), Pg. 48, 1974.

Dermal Toxicity:
skin-rabbit LD50 > 5000 mg/kg
Food and Cosmetics Toxicology. Vol. 12, Pg. 719, 1974.

Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
maximum skin levels for fine fragrances:
0.1300 % and are based on the assumption that the fragrance mixture is used at 20% in a consumer product (IFRA Use Level Survey).(IFRA, 2001)
Recommendation for ethyl cinnamate usage levels up to:
8.0000 % in the fragrance concentrate.
use level in formulae for use in cosmetics:
0.0130 %
Dermal Systemic Exposure in Cosmetic Products:
0.0003 mg/kg/day (IFRA, 2001)
Maximised Survey-derived Daily Intakes (MSDI-EU): 89.00 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 70.00 (μg/capita/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -12.00000
beverages(nonalcoholic): -4.10000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: 11.0000040.00000
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -8.80000
fruit ices: -8.80000
gelatins / puddings: -2.40000
granulated sugar: --
gravies: --
hard candy: -9.50000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 15 (FGE.15): Aryl-substituted saturated and unsaturated primary alcohol/aldehyde/acid/ester derivatives from chemical group 22 (Commission Regulation (EC) No 1565/2000 of 18 July 2000)
View page or View pdf

Flavouring Group Evaluation 55 (FGE.55): Consideration of phenyl-substituted aliphatic alcohols and related aldehydes and esters evaluated by JECFA (63rd meeting) structurally related to phenethyl alcohol, aldehyde, esters and related phenylacetic acid esters evaluated by EFSA in FGE.14 (2005) and aryl-substituted saturated and unsaturated primary alcohol/aldehyde/acid/ester derivatives evaluated by EFSA in FGE.15 (2005) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)
View page or View pdf

Flavouring Group Evaluation 15, Revision 1 (FGE.15Rev1) - Aryl-substituted saturated and unsaturated primary alcohol/aldehyde/acid/ester derivatives from chemical group 22 - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 68 (FGE.68): Consideration of cinnamyl alcohol and related flavouring agents evaluated by JECFA (55th meeting) evaluated by EFSA in FGE.15Rev1 (2008)
View page or View pdf

Safety and efficacy of aryl-substituted primary alcohol, aldehyde, acid, ester and acetal derivatives belonging to chemical group 22 when used as flavourings for all animal species
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):103-36-6
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :7649
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:1
ethyl 3-phenylprop-2-enoate
Chemidplus:0000103366
RTECS:GD9010000 for cas# 103-36-6