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guaethol allyl ether

Guaethol allyl ether is a fragrance compound featuring a medium floral odor with spicy, carnation-like woody notes used primarily in perfumery.

General Material Description

Guaethol allyl ether, also known under synonyms such as carnotene, guaethol allyl ethyl ether, and guaiacyl allyl ethyl ether, is a chemical fragrance ingredient characterized by a clear to pale liquid appearance. It belongs to a class of allyl ethers derived from guaiacol structures and imparts a distinctive floral odor profile with spicy and woody undertones. The compound is referenced in chemical databases such as PubChem and is chiefly sourced through synthetic organic processes designed to control purity and olfactory consistency. It is used mainly in perfumery and fragrance applications where complex floral nuances are desired.

Occurrence, Applicability & Potential Uses

This compound does not occur naturally in large amounts but is manufactured for commercial fragrance use. It provides a medium-strong floral note reminiscent of carnation, enriched with spicy and woody accents. Guaethol allyl ether finds its primary application as a fragrance agent in perfumery formulations and related products. It contributes substantivity, lasting approximately 128 hours at full concentration, supporting sustained olfactory impact. Regulatory guidance from IFRA (Global) permits usage levels up to 1.0000 % in fragrance concentrates, emphasizing controlled and safe application. Not recommended for flavor use, it remains specialized for olfactory enhancement in cosmetic and personal care formulations.

Physico-Chemical Properties Summary

Guaethol allyl ether exhibits specific gravity values ranging from 1.0228 to 1.0288 at 25 °C, indicating a density slightly greater than water. Its refractive index varies between 1.5195 and 1.5255 at 20 °C, consistent with aromatic ether compounds. The compound is soluble in alcohol solvents but insoluble in water, reflecting its nonpolar and moderately hydrophobic character. The flash point is measured at 210 °F (approximately 99 °C), signifying moderate volatility and underlying flammability considerations. These properties influence its behavior during formulation, favoring incorporation into alcohol-based matrices and requiring standard handling precautions for flammable liquids.

FAQ

What is guaethol allyl ether and what are its primary characteristics?
Guaethol allyl ether is a synthetic fragrance chemical known for its medium-strength floral odor, which combines spicy, woody, and carnation-like notes. It serves predominantly as a fragrance agent, valued for its sustained smell longevity and complex olfactory profile. Known also as carnotene or guaiacol allyl ethyl ether, it appears as a clear liquid and is structurally classified within allyl ethers containing guaiacol moieties.
How is guaethol allyl ether used and what standards govern its application?
Primarily utilized in perfumery, guaethol allyl ether imparts floral and spicy aroma tones to fragrance compositions. Its physical properties support its integration into alcohol-based fragrance formulations. Usage levels are regulated under the IFRA Code of Practice (Global), which recommends a maximum concentration of 1.0000 % in fragrance concentrates. The compound is not intended for flavor applications. These regulations ensure safe and effective deployment in cosmetic and personal care products.
What safety information and handling precautions exist for guaethol allyl ether?
No specific hazard classifications or precautionary statements are identified under OSHA regulation 29 CFR 1910. The compound does not have established oral, dermal, or inhalation toxicity profiles. Nonetheless, its flash point near 99 °C indicates flammability risks requiring appropriate storage and handling to avoid ignition sources. IFRA guidelines provide safety recommendations for its use in fragrance, underscoring the importance of observing concentration limits for consumer safety.

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Other Information

General Material Information

Trivial Name guaethol allyl ether
Short Description carnothene
Synonyms
  • carnothene
  • guaiacol allyl ethyl ether
  • guaiacyl allyl ethyl ether

PhysChem Properties

Material listed in food chemical codex No
Specific gravity @ 25 °C
Pounds per Gallon 8.511 to 8.561
Refractive Index 1.5195 to 1.5255 @ 20 °C
Flash Point TCC Value 98.89 °C TCC
Solubility
alcohol Yes
water No

Organoleptic Properties

Odor Type: Floral
clean, spicy, carnation, sweet, woody
Odor strength medium
Substantivity 128 hour(s) at 100.00 %
Luebke, William tgsc, (1985) At 100.00 %. clean deep spicy carnation sweet woody

Potential Uses

Applications
Odor purposes Carnation , Herbal , Spice , Woody

Safety Information

Safety information

Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
fragrance agents
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for guaethol allyl ether usage levels up to:
1.0000 % in the fragrance concentrate.
Recommendation for guaethol allyl ether flavor usage levels up to:
not for flavor use.

Safety references

None found