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cinnamyl formate

Chemical Structure

General Material Information

Preferred name cinnamyl formate
Trivial Name Cinnamyl formate
Short Description 3-phenyl-2-propen-1-yl formate
Formula C10 H10 O2
CAS Number 104-65-4
FEMA Number 2299
Flavis Number 9.085
ECHA Number 203-223-3
FDA UNII 896AGS89RD
Nikkaji Number J35.356F
Beilstein Number 1860334
MDL MFCD00021048
COE Number 352
NMR Predictor External link
JECFA Food Flavoring 649 cinnamyl formate
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 104-65-4 ; CINNAMYL FORMATE
Synonyms
  • cinnamyl alcohol formate
  • cinnamyl formate FCC
  • cinnamyl formate natural
  • cinnamyl methanoate
  • formic acid cinnamyl ester
  • 3-phenyl allyl formate
  • gamma- phenyl allyl formate
  • 3-phenyl-2-propen-1-ol formate
  • 3-phenyl-2-propen-1-yl formate
  • 3-phenylprop-2-en-1-yl formate
  • 3-phenylprop-2-enyl formate
  • 2-propen-1-ol, 3-phenyl-, formate
  • 3-phenylprop-2-enyl formate
  • 2-Propen-1-ol, 3-phenyl-, 1-formate
  • Cinnamyl alcohol, formate
  • 2-Propen-1-ol, 3-phenyl-, formate
  • γ-Phenylallyl formate
  • 3-Phenyl-2-propen-1-yl formate
  • NSC 21737
  • 3-Phenyl-2-propen-1-ol formate

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Other Information

(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
HMDB (The Human Metabolome Database):HMDB40577
FooDB:FDB020358
Export Tariff Code:2915.13.0000
Typical G.C.
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View

PhysChem Properties

Material listed in food chemical codex Yes
Molecular weight 162.18809509277
Specific gravity @ 25 °C
Pounds per Gallon 8.962 to 9.003
Refractive Index 1.55 to 1.556 @ 20 °C
Boiling Point 250 to 254°C @ 760 mm Hg
Acid Value 2 max KOH/g
Vapor Pressure 0.02 mmHg @ 20 °C
Flash Point TCC Value 110 °C TCC
logP (o/w) 2.101 est
Solubility
alcohol Yes
fixed oils Yes
water, 725.1 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Balsamic
balsamic, fruity, floral, green, herbal, cinnamyl, narcissus
Odor strength medium
Substantivity 244 hour(s) at 100.00 %
Luebke, William tgsc, (1985) At 100.00 %. balsam fruity floral green herbal cinnamyl narcissus
Flavor Type: Spicy
spicy, balsamic, cinnamon, cinnamyl, fusel, winey
Luebke, William tgsc, (1985) Spicy balsamic cinnamon cinnamyl fusel winey

Occurrences

Potential Uses

Applications
Odor purposes Apple, Balsam, Bergamot, Cassia, Cinnamon, Date, Lavender, Oriental, Pear, Rose, Sandalwood, Vetiver
Other purposes Modifier
Cosmetic purposes Perfuming agents

Safety Information

Safety information

Preferred SDS: View
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
4 % solution: no irritation or sensitization.
Oral/Parenteral Toxicity:
oral-rat LD50 2900 mg/kg
Food and Cosmetics Toxicology. Vol. 14, Pg. 719, 1976.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
maximum skin levels for fine fragrances:
0.0100 % and are based on the assumption that the fragrance mixture is used at 20% in a consumer product (IFRA Use Level Survey).(IFRA, 2001)
Recommendation for cinnamyl formate usage levels up to:
1.0000 % in the fragrance concentrate.
use level in formulae for use in cosmetics:
0.0400 %
Dermal Systemic Exposure in Cosmetic Products:
0.0010 mg/kg/day (IFRA, 2001)
Maximised Survey-derived Daily Intakes (MSDI-EU): 1.80 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 17.00 (μg/capita/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -8.00000
beverages(nonalcoholic): -1.30000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: -0.60000
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -9.10000
fruit ices: -9.10000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -6.90000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Flavouring Group Evaluation 214: alpha,beta-Unsaturated aldehydes and precursors from chemical subgroup 3.1 of FGE.19: Cinnamyl derivatives[1]
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 68 (FGE.68): Consideration of cinnamyl alcohol and related flavouring agents evaluated by JECFA (55th meeting) evaluated by EFSA in FGE.15Rev1 (2008)
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):104-65-4
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :7712
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
3-phenylprop-2-enyl formate
Chemidplus:0000104654
RTECS:UD5530000 for cas# 104-65-4