tonka undecanone

General Material Information

Preferred name	tonka undecanone
Trivial Name	6-Ethylideneoctahydro-5,8-methano-2H-1-benzopyran-2-one
Short Description	florex (Firmenich)
Formula	C12 H16 O2
CAS Number	69486-14-2
FDA UNII	Search
Nikkaji Number	J441.311C
xLogP3-AA	1.70 (est)
NMR Predictor	External link
Synonyms	6-ethylidene octahydro-5,8-methano-2H-1-benzopyran-2-one 3-oxa-10-ethylidene tricyclo(6.2.1.0)undecan-4-one 9-ethylidene-3-oxatricyclo(6.2.1.02,7)undecane-4-one 6-and 7-ethylideneoctahydro-5,8-methano-2H-1-benzopyran-2-one 6-or-7-ethylideneoctahydro-5,8-methano[2h]-1-benzopyran-2-one floralex florex (Firmenich) 5,8-methano-2H-1-benzopyran-2-one, 6-ethylideneoctahydro- 9-ethylidene-3-oxatricyclo(6.2.1.02,7)undecane-4-one 5,8-Methano-2H-1-benzopyran-2-one, 6-ethylideneoctahydro- 6-Ethylideneoctahydro-5,8-methano-2H-1-benzopyran-2-one

(IUPAC):	Atomic Weights of the Elements 2011 (pdf)
Videos:	The Periodic Table of Videos
tgsc:	Atomic Weights use for this web site
(IUPAC):	Periodic Table of the Elements
HMDB (The Human Metabolome Database):	Search
ChemSpider:	View

Azelis UK	BOC Sciences
Ernesto Ventós	Firmenich
Indukern F&F	Liaison Carbone
Lluch Essence	Penta International
Perfumery Laboratory	Azelis UK Ltd.
Firmenich Inc.	Indukern, S.A. F&F Ingredients Division
Lluch Essence S.L.	Penta International Corporation
Ernesto Ventós S.A.

Material listed in food chemical codex	No
Molecular weight	192.25791931152
Boiling Point	332 to 333°C @ 760 mm Hg
Acid Value	1 max KOH/g
Vapor Pressure	0.00011 mmHg @ 25 °C
Flash Point TCC Value	139.44 °C TCC
logP (o/w)	2.427 est
Solubility
alcohol	Yes
water, 1100 mg/L @ 25 °C (est)	Yes
Stability
APC: traces - 0.1%	Unspecified
candle: traces - 0.1%	Unspecified
detergent: traces - 0.5%	Unspecified
fine fragrances: traces - 0.5%	Unspecified
shampoo: traces - 0.5%	Unspecified
shower gel: traces - 0.1%	Unspecified
soap: traces - 0.5%	Unspecified
softener: traces - 0.5%	Unspecified

Odor Type: Tonka
sweet, spicy, balsamic, tonka, woody, tobacco, green
Odor strength	medium , recommend smelling in a 10.00 % solution or less
Substantivity	336 hour(s) at 100.00 %
Luebke, William tgsc, (1985)	At 10.00 % in dipropylene glycol. sweet spicy balsam tonka woody tobacco green
It can be used in all types of perfumes but has especially interesting effects in white florals, citrus and fruity accords.	A very powerful and tenacious balsamic, Tonka-like note with a unique tangy quality. It has a sweet yet tart character that suggests tobacco and coconut with a green nuance
General comment	Diffuse, powerful, balsamic with a touch of beans is thin and a unique astringent

Applications	fragrance agents
Odor purposes	Balsam, Coconut, Fern, Green, Powder, Rose, Sandalwood, Tobacco, Tonka bean, Vanilla, Woody
Other purposes	Diffusion, Fixer
Cosmetic purposes	Perfuming agents


Hazards identification

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements

Pictogram

Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Category:
fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for tonka undecanone usage levels up to:
	0.5000 % in the fragrance concentrate.

Recommendation for tonka undecanone flavor usage levels up to:
	not for flavor use.

AIDS Citations:Search

Cancer Citations:Search

Toxicology Citations:Search

EPA Substance Registry Services (TSCA):69486-14-2

EPA Substance Registry Services (SRS):Registry

Laboratory Chemical Safety Summary :6437737

National Institute of Allergy and Infectious Diseases:Data

9-ethylidene-3-oxatricyclo(6.2.1.02,7)undecane-4-one

Chemidplus:0069486142