We have found 46587 results matching your criteria.
Please wait while we search...
  1. 1.
    General Material Information
  2. 2.
    PhysChem Properties
  3. 3.
    Occurrences
  4. 4.
    Organoleptic Properties
  5. 5.
    Suppliers
  6. 6.
    Potential Uses
  7. 7.
    Regulatory & Documentation
  8. 8.
    Safety Information
  9. 9.
    Other Information
  10. 10.
    Blenders & Components
  11. 11.
    Literature & References

ethyl benzoyl acetate

Chemical Structure

General Material Information

Preferred name ethyl benzoyl acetate
Trivial Name Ethyl benzoylacetate
Short Description ethylbenzoyl acetate
Formula C11 H12 O3
CAS Number 94-02-0
FEMA Number 2423
Flavis Number 9.476
ECHA Number 202-295-3
FDA UNII K8CHJ4MKM0
Nikkaji Number J60.326K
Beilstein Number 0389944
MDL MFCD00009196
COE Number 627
Bio Activity Summary External link
NMR Predictor External link
JECFA Food Flavoring 834 ethylbenzoyl acetate
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 94-02-0 ; ETHYL BENZOYLACETATE
Synonyms
  • acetic acid, benzoyl-, ethyl ester
  • beta-oxo- benzene propanoic acid ethyl ester
  • benzenepropanoic acid, b-oxo-, ethyl ester
  • benzoyl acetic acid ethyl ester
  • benzoylacetic acid ethyl ester
  • benzoylacetic acid, ethyl ester
  • 1-ethoxy-3-phenyl propane-1,3-dione
  • 1-ethoxy-3-phenylpropane-1,3-dione
  • ethyl 3-oxo-3-phenyl propanoate
  • ethyl 3-oxo-3-phenylpropanoate
  • ethyl 3-oxo-3-phenylpropionate
  • ethyl 3-phenyl-3-oxopropanoate
  • ethyl benzoyl acetate FCC
  • ethyl benzoylacetate
  • ethyl beta-oxobenzene propanoate
  • ethylbenzoyl acetate
  • 3-oxo-3-phenyl-propionic acid ethyl ester
  • Benzenepropanoic acid, β-oxo-, ethyl ester
  • Ethyl β-oxobenzenepropanoate
  • 1-Ethoxy-3-phenylpropane-1,3-dione
  • β-Oxobenzenepropanoic acid ethyl ester
  • 3-Oxo-3-phenylpropionic acid ethyl ester
  • NSC 227214
  • NSC 6774
  • 3-Oxo-3-phenylpropanoic acid ethyl ester
  • Ethyl 2-benzoylacetate
  • 3-Phenyl-3-oxopropanoic acid ethyl ester

US / EU / FDA / JECFA / FEMA / Scholar / Patents

Google Scholar Start search
Google Books Start search
Google Patents Start search
Perfumer & Flavorists Start search
EU Patents Start search
PubMeb Start search
NCBI Start search

Other Information

(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
CHEMBL:View
HMDB (The Human Metabolome Database):HMDB40268
FooDB:FDB019986
Export Tariff Code:2918.30.3000
ChemSpider:View

PhysChem Properties

Material listed in food chemical codex No
Molecular weight 192.21423339844
Specific gravity @ 25 °C
Pounds per Gallon 9.261 to 9.344
Refractive Index 1.528 to 1.533 @ 20 °C
Boiling Point 265 to 270°C @ 760 mm Hg
Boiling Point 147 to 148°C @ 11 mm Hg
Acid Value 2 max KOH/g
Vapor Pressure 0.008 mmHg @ 25 °C
Vapor Density 6.6
Flash Point TCC Value 63.89 °C TCC
logP (o/w) 1.87
Solubility
alcohol Yes
water, 1212 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Fruity
fruity, cherry, naphthyl, hawthorn, cumin, phenolic, almond, spicy, woody, cherry maraschino cherry, sweet
Odor strength medium
Substantivity 346 hour(s) at 100.00 %
Luebke, William tgsc, (2021) At 100.00 %. fruity cherry naphthyl hawthorn cumin phenolic almond spicy woody maraschino cherry
Mosciano, Gerard P&F 20, No. 3, 63, (1995) Sweet, fruity, naphthyl- and acetophenone-like notes, phenolic and cherry pit notes
Flavor Type: Fruity
fruity, cherry, berry, cumin, jammy, tropical, grape, violet, woody, sweet
Luebke, William tgsc, (2021) Fruity cherry berry cumin jammy tropical grape violet woody
Mosciano, Gerard P&F 20, No. 3, 63, (1995) At 10.00 ppm. Sweet, fruity, cherry, berry-like with woody, jammy notes

Potential Uses

Applications
Flavoring purposes Brandy, Cherry, Grape, Raspberry, Whiskey
Cosmetic purposes Perfuming agents

Safety Information

Safety information

Preferred SDS: View
European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-mouse LD50 6800 mg/kg
"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 65, 1982.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for ethyl benzoyl acetate usage levels up to:
1.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.012 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 140.00 (μg/capita/day)
Threshold of Concern:1800 (μg/person/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -10.00000
beverages(nonalcoholic): -0.70000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -5.00000
fruit ices: -5.00000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -10.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 16 (FGE.16): Aromatic ketones from chemical group 21 (Commission Regulation (EC) No 1565/2000 of 18 July 2000)
View page or View pdf

Flavouring Group Evaluation 16, Revision 1 (FGE.16Rev1)[1]: Aromatic ketones from chemical group 21- Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food
View page or View pdf

Flavouring Group Evaluation 69, (FGE.69)[1] - Consideration of aromatic substituted secondary alcohols, ketones and related esters evaluated by JECFA (57th meeting) structurally related to aromatic ketones from chemical group 21 evaluated by EFSA in FGE.16 (2006) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food
View page or View pdf

Flavouring Group Evaluation 16, Revision 2 (FGE.16Rev2): Aromatic ketones from chemical group 21
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 69, Revision 1 (FGE.69Rev1): consideration of aromatic substituted secondary alcohols, ketones and related esters evaluated by JECFA (57th meeting), structurally related to aromatic ketones from chemical group 21 evaluated by EFSA in FGE.16Rev2
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):94-02-0
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :7170
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
ethyl 3-oxo-3-phenylpropanoate
Chemidplus:0000094020
RTECS:AF4878000 for cas# 94-02-0