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ethyl methyl anthranilate

Chemical Structure

General Material Information

Preferred name ethyl methyl anthranilate
Trivial Name Ethyl 2-(methylamino)benzoate
Short Description ethyl N-methylanthranilate
Formula C10 H13 N O2
CAS Number 35472-56-1
FEMA Number 4116
Flavis Number 9.765
FDA UNII HQ8T25BTTC
Nikkaji Number J169.109K
MDL MFCD11174593
COE Number 632
Bio Activity Summary External link
NMR Predictor External link
JECFA Food Flavoring 1546 ethyl N-methylanthranilate
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 35472-56-1 ; ETHYL N-METHYLANTHRANILATE
Synonyms
  • benzoic acid, 2-(methylamino)-, ethyl ester
  • ethyl 2-(methyl amino) benzoate
  • ethyl 2-(methylamino)benzoate
  • ethyl 2-methylaminobenzoate
  • ethyl N-methylanthranilate
  • 2-( methyl amino) benzoic acid ethyl ester
  • Anthranilic acid, N-methyl-, ethyl ester
  • NSC 408328

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Literature & References

ethyl 2-methylaminobenzoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:35472-56-1
Pubchem (cid):101365
Pubchem (sid):135058656
Publications by Info
anthranilate derivatives

Other Information

(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
HMDB (The Human Metabolome Database):HMDB33763
FooDB:FDB011905
Export Tariff Code:2922.49.3800
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View

PhysChem Properties

Material listed in food chemical codex No
Molecular weight 179.21900939941
Specific gravity @ 25 °C
Pounds per Gallon
Acid Value 1 max KOH/g
Vapor Pressure 0.009 mmHg @ 25 °C
Flash Point TCC Value 116.67 °C TCC
logP (o/w) 3.224 est
Solubility
alcohol Yes
water, very slightly Yes
water, 83.89 mg/L @ 25 °C (est) Yes

Organoleptic Properties

Odor Type: Fruity
sweet, mandarin, petitgrain
General comment At 100.00 %. soft sweet mandarin petitgrain

Occurrences

Potential Uses

Applications
Odor purposes Fruit, Jasmin, Mandarin, Neroli, Orange blossom, Petitgrain
Flavoring purposes Fruit tropical fruit
Other purposes Topnotes

Safety Information

Safety information

Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for ethyl methyl anthranilate usage levels up to:
4.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.028 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.04 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI): 2300 (μg/person/day)
Threshold of Concern:1800 (μg/person/day)
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 22
Click here to view publication 22
average usual ppmaverage maximum ppm
baked goods: 10.0000050.00000
beverages(nonalcoholic): --
beverages(alcoholic): --
breakfast cereal: 5.0000025.00000
cheese: 7.0000035.00000
chewing gum: --
condiments / relishes: 2.0000025.00000
confectionery froastings: 10.0000050.00000
egg products: --
fats / oils: 5.0000025.00000
fish products: 2.0000010.00000
frozen dairy: 7.0000035.00000
fruit ices: 10.0000050.00000
gelatins / puddings: --
granulated sugar: --
gravies: 5.0000025.00000
hard candy: --
imitation dairy: 7.0000035.00000
instant coffee / tea: --
jams / jellies: --
meat products: 5.0000025.00000
milk products: 7.0000035.00000
nut products: --
other grains: 5.0000025.00000
poultry: 2.0000010.00000
processed fruits: 7.0000035.00000
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: 5.0000025.00000
snack foods: 20.00000100.00000
soft candy: --
soups: 5.0000025.00000
sugar substitutes: --
sweet sauces: 5.0000025.00000
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i).
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.
average usage mg/kgmaximum usage mg/kg
Dairy products, excluding products of category 02.0 (01.0): 7.0000035.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0): 5.0000025.00000
Edible ices, including sherbet and sorbet (03.0): 10.0000050.00000
Processed fruit (04.1): 7.0000035.00000
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): --
Confectionery (05.0): 10.0000050.00000
Chewing gum (05.3): --
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 5.0000025.00000
Bakery wares (07.0): 10.0000050.00000
Meat and meat products, including poultry and game (08.0): 2.0000010.00000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): 2.0000010.00000
Eggs and egg products (10.0): --
Sweeteners, including honey (11.0): --
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 5.0000025.00000
Foodstuffs intended for particular nutritional uses (13.0): 10.0000050.00000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): --
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 10.0000050.00000
Ready-to-eat savouries (15.0): 20.00000100.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): 5.0000025.00000

Safety references

European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Flavouring Group Evaluation 84, (FGE.84)[1] - Consideration of Anthranilate derivatives evaluated by JECFA (65th meeting) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :101365
National Institute of Allergy and Infectious Diseases:Data
ethyl 2-methylaminobenzoate
Chemidplus:0035472561