We have found
46590
results matching your criteria.
Please wait while we search...
ethyl safranate
Ethyl safranate is a cyclohexadiene ester noted for its floral and spicy rose scent, widely used in fragrance formulations to impart fruity and woody notes.
General Material Description
Ethyl safranate is a synthetic ester derived from 2,6,6-trimethyl cyclohexa-1,3-diene-1-carboxylic acid and ethanol, with molecular formula C12H18O2. It appears as a colorless to pale yellow liquid with a pronounced floral aroma featuring spicy rose, fresh apple, and woody nuances. This compound is also known under numerous synonyms such as cristalone, ethyl damascate, and oriental ester. Classified as a fragrance agent, ethyl safranate's sensory profile is complex and diffusive, making it valuable for perfume and toiletry formulation. Sourced mostly through chemical synthesis, it is listed in chemical databases such as PubChem. Its versatile scent profile facilitates use in diverse fragrance categories.
Occurrence, Applicability & Potential Uses
Ethyl safranate naturally occurs in small quantities in Atalantia monophylla and related plant species. It is principally applied as a perfuming agent imparting floral, fruity, oriental, and woody notes. Its spicy rose and subtle saffron aspects contribute complexity and depth in fragrance compositions. According to the IFRA Code of Practice (Global), usage levels in fragrance concentrates are recommended up to 5%. Its solubility in alcohol and stability in detergent formulations enhance its applicability beyond traditional fine fragrances, extending potential uses to toiletries and household products requiring lasting floral-oriental odors.
Physico-Chemical Properties Summary
Ethyl safranate exhibits a moderate molecular weight of approximately 194.27 g/mol with a molecular formula C12H18O2. It shows a vapor pressure of 0.027 mmHg at 25 °C, indicating low volatility suitable for sustained fragrance delivery. The estimated logP value near 3.8 suggests lipophilicity favoring solubility in organic solvents like alcohols, while water solubility remains limited but measurable. Its flash point is about 85 °C (185 °F), necessitating standard precautions during handling and storage. The material maintains shelf stability of 24 months or longer under cool, dry, and light-protected conditions, supporting reliable formulation use.
FAQ
What is ethyl safranate and what are its key characteristics?
Ethyl safranate is an ester compound known chemically as ethyl 2,6,6-trimethylcyclohexa-1,3-diene-1-carboxylate. It possesses a complex floral fragrance with spicy rose, fresh apple, and woody notes, making it valuable in fragrance creation. The compound is recognized for its intensity and long-lasting aroma, often described as natural and fresh. It is also referred to by synonyms such as cristalone and oriental ester. Its molecular structure and chemical properties classify it as an organic ester used primarily in perfuming agents.
Where does ethyl safranate occur naturally and how is it used in products?
Ethyl safranate is found naturally, though in low amounts, in plants like Atalantia monophylla. Beyond natural occurrence, it is commercially synthesized for consistent quality and availability. The compound is widely utilized in perfume and toiletry products due to its stability and ability to impart floral, fruit, and oriental aroma profiles. Its solubility in alcohol enables use in alcohol-based perfumes, and its stability extends usage to detergents and household products requiring persistent scent character. Usage levels are regulated, especially in fragrance concentrates, to optimize scent impact and safety.
What safety standards and regulations apply to ethyl safranate in fragrance use?
Ethyl safranate is regulated under the IFRA Code of Practice (Global), which recommends maximum usage levels of 5% in fragrance concentrates to ensure consumer safety during typical product use. It is not authorized for flavor applications. Safety assessments, such as those by the Research Institute for Fragrance Materials (RIFM), indicate no classified hazards under OSHA standards in the United States. Proper storage involves keeping containers sealed and protected from heat and light to maintain stability. Regulatory listings include CAS number 35044-59-8 and ECHA pre-registration number 252-335-9 in the European Union.
US / EU / FDA / JECFA / FEMA / Scholar / Patents
| Google Scholar | Start search |
| Google Books | Start search |
| Google Patents | Start search |
| Perfumer & Flavorists | Start search |
| EU Patents | Start search |
| PubMeb | Start search |
| NCBI | Start search |
Other Information
| (IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| HMDB (The Human Metabolome Database): | Search |
| Export Tariff Code: | 2918.23.9000 |
| VCF-Online: | VCF Volatile Compounds in Food |
| ChemSpider: | View |
General Material Information
| Preferred name | ethyl safranate |
| Trivial Name | Ethyl safranate |
| Short Description | cyclohexa-1,3-diene-1-carboxylic acid, 2,6,6-trimethyl-, ethyl ester |
| Formula | C12 H18 O2 |
| CAS Number | 35044-59-8 |
| ECHA Number | 252-335-9 |
| FDA UNII | FZ10F6BJB5 |
| Nikkaji Number | J289.889F |
| xLogP3-AA | 2.90 (est) |
| NMR Predictor | External link |
| Synonyms |
|
Suppliers
PhysChem Properties
| Material listed in food chemical codex | No |
| Molecular weight | 194.27386474609 |
| Vapor Pressure | 0.027 mmHg @ 25 °C |
| Flash Point TCC Value | 85 °C TCC |
| logP (o/w) | 3.831 est |
| Shelf life | 24 months (or longer if stored properly.) |
| Storage notes | Store in cool, dry place in tightly sealed containers, protected from heat and light. |
| Solubility | |
| alcohol | Yes |
| water, 10.94 mg/L @ 25 °C (est) | Yes |
| water | No |
Organoleptic Properties
| Odor Type: Floral | |
| fresh, natural, herbal, rose, apple, woody | |
| Odor strength | high , recommend smelling in a 10.00 % solution or less |
| Substantivity | 164 hour(s) at 100.00 % |
| Luebke, William tgsc, (1989) | At 10.00 % in dipropylene glycol. fresh natural herbal damascon rose apple woody |
| Ethyl Safranate is a complex diffusive spicy rose with apple cider and spicy aspects. This rich and versatile ingredient is used in a wide range of fragrance types, from floral through to fruity, particularly apple. Ethyl Safranate gives body and radiance in Fine Fragrance and Toiletries, but is also unexpectedly stable in detergents, thus broadening the possibilities for use. | Floral, Rose, Fruity, Apple, Spicy |
| General comment | Intense and diffusive, natural, fresh, damascone, rose, apple, with woody aspects; longlasting |
Occurrences
| (data available) |
Potential Uses
| Applications | |
| Odor purposes | Floral , Fruit , Herbal , Oriental , Rose , Saffron , Spice , Woody |
| Other purposes | Arpege , L'air du temps , Natural |
| Cosmetic purposes | Perfuming agents |
Safety Information
Safety information
| Hazards identification | |
| Classification of the substance or mixture | |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
| None found. | |
| GHS Label elements, including precautionary statements | |
| Pictogram | |
| Hazard statement(s) | |
| None found. | |
| Precautionary statement(s) | |
| None found. | |
| Oral/Parenteral Toxicity: | |
| Not determined | |
| Dermal Toxicity: | |
| Not determined | |
| Inhalation Toxicity: | |
| Not determined | |
Safety in use information
| Category: | |||
| fragrance agents | |||
| RIFM Fragrance Material Safety Assessment: Search | |||
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
| Recommendation for ethyl safranate usage levels up to: | |||
| 5.0000 % in the fragrance concentrate. | |||
| Recommendation for ethyl safranate flavor usage levels up to: | |||
| not for flavor use. | |||
Safety references
| EPI System: View |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA Substance Registry Services (TSCA):35044-59-8 |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :118201 |
| National Institute of Allergy and Infectious Diseases:Data |
| WGK Germany:2 |
| ethyl 2,6,6-trimethylcyclohexa-1,3-diene-1-carboxylate |
| Chemidplus:0035044598 |