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    General Material Information
  2. 2.
    PhysChem Properties
  3. 3.
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  4. 4.
    Organoleptic Properties
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  6. 6.
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    Literature & References

cinnamon acrolein

General Material Information

Preferred name cinnamon acrolein
Trivial Name 3-(furan-2-yl)-2-methylprop-2-enal
Short Description 2-methyl-3-(2-furyl)acrolein
Formula C8 H8 O2
CAS Number 874-66-8
CAS Number 108576-21-2
CAS Number 874-66-8 (Z)
FEMA Number 2704
Flavis Number 13.046
ECHA Number 212-866-9
FDA UNII 65U4YZ14MX
Nikkaji Number J689.163B
COE Number 11878
NMR Predictor External link
JECFA Food Flavoring 1498 2-methyl-3-(2-furyl)acrolein
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 874-66-8 ; 2-METHYL-3-(2-FURYL)ACROLEIN
Synonyms
  • 3-furan-2-yl-2-methylprop-2-enal
  • 3-( furan-2-yl)-2-methylprop-2-enal
  • 3-(2-furanyl)-2-methyl-2-propenal
  • 2-furfurylidene propionaldehyde
  • furfurylidene-2-propanal
  • 3-(2-furyl) methacryl aldehyde
  • 3-(2-furyl)-2-methyl prop-2-enal
  • 3-(2-furyl)-2-methylacrylaldehyde
  • 3-(2-furyl)-2-methylprop-2-enal
  • alpha- methyl furyl acrolein
  • 2-methyl-3-(2-furyl) acrolein
  • 2-methyl-3-(2-furyl)-2-propenal
  • 2-methyl-3-(2-furyl)acrolein
  • 2-methyl-3-(2-furyl)propenal
  • 2-methyl-3-furyl acrolein
  • 2-methyl-3-furyl acrolein so called
  • 2-methyl-3,2-furyl propenal
  • 2-methyl-3(2-furyl) acrolein
  • 2-methyl-3(2-furyl)acrolein
  • alpha- methyl-beta-(2-furyl) acrolein
  • alpha- methyl-beta-furyl acrolein
  • 2-propenal, 3-(2-furanyl)-2-methyl-

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Literature & References

3-(furan-2-yl)-2-methylprop-2-enal
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:874-66-8
Pubchem (cid):61228
Pubchem (sid):43118514
(E)-3-(furan-2-yl)-2-methylprop-2-enal
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:108576-21-2
Pubchem (cid):6210220
Pubchem (sid):42910720
(Z)-3-furan-2-yl-2-methylprop-2-enal
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:874-66-8
Pubchem (cid):6435828
Pubchem (sid):197491
Publications by Info
substances containing furan substitution

Other Information

(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
HMDB (The Human Metabolome Database):HMDB38176
FooDB:FDB017415
Export Tariff Code:2932.19.0090
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
EFSA Update of results on the monitoring of furan levels in food:Read Report
EFSA Previous report: Results on the monitoring of furan levels in food:Read Report
EFSA Report of the CONTAM Panel on provisional findings on furan in food:Read Report

PhysChem Properties

Material listed in food chemical codex No
Molecular weight 136.15016174316
Specific gravity @ 25 °C
Pounds per Gallon 9.053 to 9.145
Refractive Index 1.48 to 1.61 @ 20 °C
Acid Value 3 max KOH/g
Vapor Pressure 0.113 mmHg @ 25 °C
Vapor Density 4.6
Flash Point TCC Value 101.67 °C TCC
logP (o/w) 1.741 est
Solubility
alcohol Yes
water, 2865 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Spicy
spicy, cinnamon, woody, herbal, cassia, medicinal
General comment At 10.00 % in dipropylene glycol. spice cinnamon woody herbal
Mosciano, Gerard P&F 22, No. 2, 69, (1997) Spicy, cassia, cinnamon and woody with herbal, medicinal nuances
Flavor Type: Spicy
spicy, cinnamon, cassia, woody
Mosciano, Gerard P&F 22, No. 2, 69, (1997) At 10.00 ppm. Spicy, cinnamon, cassia and woody with a red-hot candy naunce
Used in cinnamon and spice flavors. Spicy
Used in spicy, fruit and nut flavours, for bakery at 15ppm, non-alcoholic beverages at 4ppm, confectionery and desserts 3ppm, and alcoholic beverages at 1ppm. Spicy

Occurrences

Potential Uses

Applications
Odor purposes Blackberry, Cassia, Cinnamon, Clove, Coffee, Herbal, Mace, Peanut, Raspberry, Spice, Woody
Flavoring purposes Cola, Fruit tropical fruit, Nut

Safety Information

Safety information

European information :
Most important hazard(s):
Xn - Harmful.
R 22 - Harmful if swallowed.
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 02 - Keep out of the reach of children.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 1400 mg/kg
SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE SKIN AND APPENDAGES (SKIN): HAIR: OTHER GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 3, 1990.

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for cinnamon acrolein usage levels up to:
0.5000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.24 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 6.00 (μg/capita/day)
Structure Class: III
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -0.92000
beverages(nonalcoholic): -0.60000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -0.65000
fruit ices: -0.65000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -0.68000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Flavouring Group Evaluation 67 (FGE.67): Consideration of 40 furan-substituted aliphatic hydrocarbons, alcohols, aldehydes, ketones, carboxylic acids and related esters, sulfides, disulfides and ethers evaluated by JECFA at the 65th meeting (JECFA, 2006b) and re-evaluated at the 69th meeting (JECFA, 2009c)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 67, Revision 1 (FGE.67Rev.1): Consideration of 40 furan-substituted aliphatic hydrocarbons, alcohols, aldehydes, ketones, carboxylic acids and related esters, sulfides, disulfides and ethers evaluated by JECFA at the 65th meeting (JECFA, 2006b) and re-evaluated at the 69th meeting (JECFA, 2009c)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 222 (FGE.222): Consideration of genotoxicity data on representatives for alpha,beta-unsaturated furyl derivatives with the a,ß-unsaturation in the side chain from subgroup 4.6 of FGE.19 by EFSA
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 67, Revision 3 (FGE.67Rev3): consideration of 23 furan-substituted compounds evaluated by JECFA at the 55th, 65th, 69th and 86th meetings
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):874-66-8
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :61228
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
3-(furan-2-yl)-2-methylprop-2-enal
Chemidplus:0000874668
(E)-3-(furan-2-yl)-2-methylprop-2-enal
(Z)-3-furan-2-yl-2-methylprop-2-enal