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peony alcohol

Peony alcohol is a floral fragrance compound known for its medium strength and lasting mimosa and rose notes, used primarily in perfuming agents.
Chemical Structure

General Material Description

Peony alcohol, chemically designated as 2-(2-methylphenyl)ethanol and listed under CAS number 19819-98-8, is an aromatic alcohol commonly used in fragrance compositions. This compound presents as a liquid with a molecular formula of C9H12O and molecular weight of 136.19 g/mol. Its scent profile is characterized by natural floral notes reminiscent of peony, rose, mimosa, and green earthy undertones. Known also under multiple synonyms like 2-methylbenzene ethanol and ortho-methyl 2-phenethyl alcohol, peony alcohol is primarily sourced and synthesized for use in perfuming agents. More information on its detailed chemical characteristics is accessible via controlled-vocabulary databases such as PubChem. It occurs as a stable compound under standard storage conditions and is typically incorporated in complex fragrance blends.

Occurrence, Applicability & Potential Uses

Peony alcohol is not directly found as a significant natural metabolite but is an established synthetic fragrance ingredient derived through chemical synthesis methods. It is applied extensively in the fragrance industry to provide floral complexity, contributing aldehydic, peony, rose, and mimosa nuances to diverse scent formulations. In perfumery, it serves as a medium-strength odorant with high substantivity, maintaining scent presence for extended periods. Its uses extend to creating bouquet and floral accords resembling azalea, cherry blossom, and dahlia notes. Recognized under the IFRA (Global) Code of Practice, peony alcohol conforms to recommended maximum usage levels up to 5% in fragrance concentrates. Although not authorized for flavoring purposes, its olfactory qualities make it valuable for fragrance agents and cosmetic perfuming applications.

Physico-Chemical Properties Summary

Peony alcohol exhibits physical properties that influence its practical use in formulations. It has a melting point range from 1 to 2 °C and boils between 243 and 244 °C at atmospheric pressure (760 mm Hg), indicating moderate volatility suitable for sustained aromatic release. The compound possesses a logP value of approximately 2.11, reflecting moderate hydrophobicity and balanced solubility characteristics. It is soluble in alcohol and has an estimated water solubility of about 4399 mg/L at 25 °C, which aids its integration into various solvent systems. Vapor pressure is low at 0.017 mmHg at 25 °C, contributing to its stability and longevity in fragrance compositions. Its flash point is measured at 199 °F (about 93 °C), indicating safe handling under typical storage conditions. Proper storage in cool, dry, and tightly sealed containers protected from heat and light extends its shelf life beyond 24 months. Stability tests show compatibility with diverse formulations including shampoos, soaps, detergents, and fabric softeners.

FAQ

What is peony alcohol and what are its common synonyms?
Peony alcohol is a floral fragrance compound chemically known as 2-(2-methylphenyl)ethanol with CAS number 19819-98-8. It is widely recognized by various synonyms including 2-methylphenethyl alcohol, 2-methylbenzeneethanol, and ortho-methyl 2-phenethyl alcohol. It possesses a medium-strength floral scent reminiscent of peony, mimosa, and rose, and is primarily used in perfuming applications.
Where is peony alcohol used and how is it applied in products?
Peony alcohol is mainly employed as a fragrance agent within the perfume and cosmetic industries. Its medium strength and lasting floral notes make it valuable for blending into bouquet and floral accords such as azalea, cherry blossom, and dahlia. The compound is used in formulations including perfumes, shampoos, soaps, and fabric softeners, where it contributes to floral and natural scent profiles. It is stable under standard storage and compatible with various product types.
What regulations govern the use of peony alcohol and how is it sourced?
Peony alcohol is regulated under the IFRA (Global) Code of Practice, which recommends usage levels of up to 5.0% in fragrance concentrates. It is not authorized for use in flavor applications. The compound is primarily synthesized for industrial use, with safety evaluations indicating it is an irritant to skin and eyes, necessitating proper handling precautions. Comprehensive safety data is available through regulatory agencies and fragrance safety databases, ensuring compliance and informed use.

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Other Information

(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
CHEMBL:View
HMDB (The Human Metabolome Database):Search
Export Tariff Code:2906.29.6000
ChemSpider:View

General Material Information

Preferred name peony alcohol
Trivial Name 2-(2-Methylphenyl)ethanol
Short Description peomosa (IFF)
Formula C9 H12 O
CAS Number 19819-98-8
ECHA Number 243-349-6
FDA UNII VX8700JGJP
Nikkaji Number J149.931I
MDL MFCD00044241
NMR Predictor External link
Synonyms
  • benzeneethanol, 2-methyl-
  • 2-o- cresyl ethanol
  • 2-ortho- cresyl ethanol
  • 2-o- cresylethanol
  • 2-ortho- cresylethanol
  • o- methyl 2-phenethyl alcohol
  • ortho- methyl 2-phenethyl alcohol
  • o- methyl 2-phenyl ethyl alcohol
  • ortho- methyl 2-phenyl ethyl alcohol
  • 2-methyl benzene ethanol
  • 2-(2-methyl phenyl) ethanol
  • 2-methylbenzeneethanol
  • 2-methylphenethyl alcohol
  • o- methylphenethyl alcohol
  • 2-methylphenethylalcohol
  • 2-(2-methylphenyl)ethan-1-ol
  • 2-(2-methylphenyl)ethanol
  • peomosa (IFF)
  • phenethyl alcohol, o-methyl-
  • 2-ortho- tolyl ethanol
  • 2-o- tolylethanol
  • 2-Methylbenzeneethanol
  • 2-(2-Methylphenyl)ethanol
  • o-Methylphenethyl alcohol
  • 2-Methylphenethyl alcohol
  • NSC 409882
  • 2-(o-Tolyl)ethanol
  • Peomosa
  • 2-(o-Tolyl)ethan-1-ol
  • 2-(2-Methylphenyl)ethan-1-ol

PhysChem Properties

Material listed in food chemical codex No
Molecular weight 136.19383239746
Melting Point 1 to 2°C @ 760 mm Hg
Boiling Point 243 to 244°C @ 760 mm Hg
Vapor Pressure 0.017 mmHg @ 25 °C
Flash Point TCC Value 92.78 °C TCC
logP (o/w) 2.11
Shelf life 24 months (or longer if stored properly.)
Storage notes Store in cool, dry place in tightly sealed containers, protected from heat and light.
Solubility
alcohol Yes
water, 4399 mg/L @ 25 °C (est) Yes
water No
Stability
acid cleaner Unspecified
alcoholic lotion Unspecified
antiperspirant Unspecified
deo stick Unspecified
detergent Unspecified
fabric softener Unspecified
hard surface cleaner Unspecified
shampoo Unspecified
soap Unspecified

Organoleptic Properties

Odor Type: Floral
natural, floral, rose, peony, waxy, mimosa, green, earthy, cyclamen
Odor strength medium
Substantivity 400 hour(s) at 100.00 %
Luebke, William tgsc, (1992) At 100.00 %. natural floral rose peony waxy mimosa
General comment Natural floral, peony, mimosa, rose, green, earthy, wet, cyclamen

Safety Information

Safety information

Preferred SDS: View
European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 - Wear suitable gloves and eye/face protection.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for peony alcohol usage levels up to:
5.0000 % in the fragrance concentrate.
Recommendation for peony alcohol flavor usage levels up to:
not for flavor use.

Safety references

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):19819-98-8
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :88267
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
2-(2-methylphenyl)ethanol
Chemidplus:0019819988