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cassis oxime 10%

Chemical Structure

General Material Information

Preferred name cassis oxime 10%
Trivial Name 2,4,4,7-Tetramethyl-6,8-nonadien-3-one oxime
Short Description labienoxime 10% (Givaudan)
Formula C13 H23 N O
CAS Number 81783-01-9
ECHA Number 279-817-1
FDA UNII Search
xLogP3-AA 4.50 (est)
NMR Predictor External link
Synonyms
  • labienoxime 10% (Givaudan)
  • 2,4,4,7-tetramethyl-6,8-nonadiene-3-one oxime 10%
  • 2,4,4,7-tetramethylnona-6,8-dien-3-one oxime 10%
  • (NE)-N-[(6E)-2,4,4,7-tetramethylnona-6,8-dien-3-ylidene]hydroxylamine
  • (NE)-N-[(6E)-2,4,4,7-tetramethylnona-6,8-dien-3-ylidene]hydroxylamine
  • 6,8-Nonadien-3-one, 2,4,4,7-tetramethyl-, oxime
  • 2,4,4,7-Tetramethyl-6,8-nonadien-3-one oxime
  • Labienoxime
  • Labienone Oxime
  • 2,4,4,7-Tetramethylnona-6,8-dien-3-one oxime

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Literature & References

(NE)-N-[(6E)-2,4,4,7-tetramethylnona-6,8-dien-3-ylidene]hydroxylamine
NIST Chemistry WebBook:Search Inchi
Pubchem (cid):6365812
Pubchem (sid):135249739
Publications by US Patents
4,426,321 - Odorant alkadienyl ketones, alcohols and oximes

Other Information

(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
HMDB (The Human Metabolome Database):HMDB36031
FooDB:FDB014850
ChemSpider:View

PhysChem Properties

Material listed in food chemical codex No
Molecular weight 209.33250427246
Flash Point TCC Value 100 °C TCC
logP (o/w) 4.14
Solubility
alcohol Yes
water, 0.6053 mg/L @ 25 °C (est) Yes
Stability
alcoholic - good Unspecified
antiperspirant spray - good Unspecified
APC (pH = 10) - good Unspecified
candles - good Unspecified
damp fabric - good Unspecified
dry fabric - moderate Unspecified
liquid bleach - poor Unspecified
pH = 2 - moderate Unspecified
powder detergent - good Unspecified
powder detergent + activator - good Unspecified
soap - good Unspecified
toiletries - good Unspecified

Organoleptic Properties

Odor Type: Floral
currant bud black currant bud, green, grapefruit, herbal, rose, sage
Odor strength high , recommend smelling in a 10.00 % solution or less
Substantivity 168 hour(s) at 100.00 %
Luebke, William tgsc, (2008) At 10.00 % in dipropylene glycol. cassis green grapefruit herbal rose oxide
Labienoxime surprises with its natural, fresh, cassis, sage flower character. As a modifier, it blends well with accords where a fresh fruity, green aspect is needed - for example, citrus, modern lily-of-the-valley, lavender. Compared to other products in this olfactive register, Labienoxime is more linear and tenacious, including on fabric, and lacks the typical sulphury aspect. Blackcurrant, Grapefruit, Green, Sage flower
The material combines exceptionally well with a range of fruity materials, adding depth and tenacity. A superior grapefruit accord can be made when it is used with Methyl Pamplemousse and Paradisamide for example. It can add complexity and realism to peach accords with Nectarate, Nectaryl, gamma-decalactone, undecalactone and dodecalactone; or to pineapple accords with allyl hexanoate, allyl heptanoate, Manzanate and allyl cyclohexyl propionate. Blackcurrant-bud, citrus-grapefruit, green-sage. Powerful

Safety Information

Safety information

Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for cassis oxime 10% usage levels up to:
0.5000 % in the fragrance concentrate.
Recommendation for cassis oxime 10% flavor usage levels up to:
not for flavor use.
Maximised Survey-derived Daily Intakes (MSDI-EU): 0.13 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI): 3900 (μg/person/day)
Threshold of Concern:1800 (μg/person/day)
Structure Class: I

Safety references

European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Scientific Opinion on Flavouring Group Evaluation 20, Revision 2 (FGE.20Rev2): Benzyl alcohols, benzaldehydes, a related acetal, benzoic acids, and related esters from chemical groups 23 and 30
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):81783-01-9
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :6365812
National Institute of Allergy and Infectious Diseases:Data
(NE)-N-[(6E)-2,4,4,7-tetramethylnona-6,8-dien-3-ylidene]hydroxylamine
Chemidplus:0081783019