Preferred name | naphthalene |
Trivial Name | Naphthalene |
Short Description | moth balls |
Formula | C10 H8 |
CAS Number | 91-20-3 |
Deleted CAS Number | 72931-45-4 |
ECHA Number | 202-049-5 |
FDA UNII | 2166IN72UN |
Nikkaji Number | J2.839H |
Beilstein Number | 1421310 |
MDL | MFCD00001742 |
COE Number | 11014 |
Bio Activity Summary | External link |
NMR Predictor | External link |
Synonyms |
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NCBI | Start search |
naphthalene | |
NIST Chemistry WebBook: | Search Inchi |
Canada Domestic Sub. List: | 91-20-3 |
Pubchem (cid): | 931 |
Pubchem (sid): | 134971441 |
Flavornet: | 91-20-3 |
Pherobase: | View |
(IUPAC): | Atomic Weights of the Elements 2011 (pdf) |
Videos: | The Periodic Table of Videos |
tgsc: | Atomic Weights use for this web site |
(IUPAC): | Periodic Table of the Elements |
CHEBI: | View |
CHEMBL: | View |
UM BBD: | Search |
KEGG (GenomeNet): | C00829 |
HMDB (The Human Metabolome Database): | HMDB29751 |
FooDB: | FDB000954 |
YMDB (Yeast Metabolome Database): | YMDB01393 |
Export Tariff Code: | 2707.40.0000 |
MedlinePlusSupp: | View |
Typical G.C. | |
VCF-Online: | VCF Volatile Compounds in Food |
ChemSpider: | View |
Wikipedia: | View |
Formulations/Preparations: •trade names: naphthalin, tar camphor •available as flakes, cubes, spheres and powder. •trade names: tar camphor; moth balls; moth flakes; white tar; nci-c52904; mighty 150; camphor tar; mighty rdi; rcra waste number u165; un 1334; un 2304. •dezodorator •albocarbon |
Material listed in food chemical codex | No |
Molecular weight | 128.17376708984 |
Melting Point | 80 to 82°C @ 760 mm Hg |
Boiling Point | 217 to 219°C @ 760 mm Hg |
Boiling Point | 124 to 125°C @ 50 mm Hg |
Vapor Pressure | 0.159 mmHg @ 25 °C |
Vapor Density | 4.4 |
Flash Point TCC Value | 78.89 °C TCC |
logP (o/w) | 3.3 |
Solubility | |
alcohol | Yes |
water, 142.1 mg/L @ 25 °C (est) | Yes |
water, 31 mg/L @ 25 °C (exp) | Yes |
Odor Type: Pungent | |
pungent, dry, resinous | |
General comment | At 10.00 % in benzyl benzoate. pungent dry tarry |
(data available) |
Applications | |
Odor purposes | Acacia |
Cosmetic purposes | Not used anymore |
Preferred SDS: View | |
European information : | |
Most important hazard(s): | |
Xn N - Harmful, Dangerous for the environment. | |
R 22 - Harmful if swallowed. R 40 - Possible risks of irreversable effects. R 50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S 02 - Keep out of the reach of children. S 20/21 - When using do not eat, drink or smoke. S 37/39 - Wear suitable gloves and eye/face protection. S 46 - If swallowed, seek medical advice immediately and show this container or label. S 60 - This material and its container must be disposed of as hazardous waste. S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet. | |
Hazards identification | |
Classification of the substance or mixture | |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |
None found. | |
GHS Label elements, including precautionary statements | |
Pictogram | |
Hazard statement(s) | |
None found. | |
Precautionary statement(s) | |
None found. | |
Oral/Parenteral Toxicity: | |
oral-rat LD50 > 2000 mg/kg Study not available (Hazleton France, 1990a; Hazleton oral-rat LD50 > 2000 mg/kg No information on study design (Vaughn & Keeler, 1976) oral-rat LD50 [sex: M,F] 2400 mg/kg 5 animals per dose group (Birch, 1978a) oral-rat LD50 [sex: M,F] 2800 mg/kg 5 animals per dose group (Birch, 1978b) oral-rat LD50 [sex: M,F] 1900 mg/kg 5 animals per dose group. 10% solution in corn oil. (Birch, 1978c) oral-rat LD50 2000 mg/kg Study not available (Hazleton France, 1990c) gavage-rat LD50 [sex: F] 9430 mg/kg (Carpenter et al., 1949) gavage-mouse LD50 [sex: M,F] M:533 F:710 mg/kg (Shopp et al., 1984) oral-cat LDLo 1000 mg/kg "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935. oral-child LDLo 100 mg/kg "Toxicology and Biochemistry of Aromatic Hydrocarbons," Gerarde, H., New York, Elsevier, 1960Vol. -, Pg. 228, 1960. oral-dog LDLo 400 mg/kg "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935. oral-guinea pig LD50 1200 mg/kg BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 47(11), Pg. 78, 1982. unreported-human LDLo 29 mg/kg Yakkyoku. Pharmacy. Vol. 31, Pg. 1499, 1980. unreported-man LDLo 74 mg/kg "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970. intraperitoneal-mouse LD50 150 mg/kg National Technical Information Service. Vol. AD691-490 intravenous-mouse LD50 100 mg/kg U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#00203 oral-mouse LD50 316 mg/kg Weisheng Dulixue Zazhi. Journal of Health Toxicology. Vol. 4, Pg. 243, 1990. oral-rabbit LDLo 3000 mg/kg "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935. oral-rat LD50 490 mg/kg "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 89, 1982. | |
Dermal Toxicity: | |
skin-rabbit LD50 > 20000 mg/kg National Technical Information Service. Vol. AD-A062-138 subcutaneous-mouse LD50 969 mg/kg BEHAVIORAL: TREMOR Toho Igakkai Zasshi. Journal of Medical Society of Toho University. Vol. 20, Pg. 772, 1973. skin-rat LD50 > 2500 mg/kg Toxicology and Applied Pharmacology. Vol. 14, Pg. 515, 1969. | |
Inhalation Toxicity: | |
inhalation-rat LC50 > 340 mg/m3/1H BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE BIOFAX Industrial Bio-Test Laboratories, Inc., Data Sheets. Vol. 16-4/1970 |
Category: | |||
fragrance agents | |||
RIFM Fragrance Material Safety Assessment: Search | |||
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice | |||
Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.013 (μg/capita/day) | ||
Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 3900 (μg/person/day) | ||
Threshold of Concern: | 90 (μg/person/day) | ||
Structure Class: | III | ||
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). | |||
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. | |||
average usage mg/kg | maximum usage mg/kg | ||
Dairy products, excluding products of category 02.0 (01.0): | 7.00000 | 35.00000 | |
Fats and oils, and fat emulsions (type water-in-oil) (02.0): | 5.00000 | 25.00000 | |
Edible ices, including sherbet and sorbet (03.0): | 10.00000 | 50.00000 | |
Processed fruit (04.1): | 7.00000 | 35.00000 | |
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | - | - | |
Confectionery (05.0): | 10.00000 | 50.00000 | |
Chewing gum (05.3): | - | - | |
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 5.00000 | 25.00000 | |
Bakery wares (07.0): | 10.00000 | 50.00000 | |
Meat and meat products, including poultry and game (08.0): | 2.00000 | 10.00000 | |
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | 2.00000 | 10.00000 | |
Eggs and egg products (10.0): | - | - | |
Sweeteners, including honey (11.0): | - | - | |
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 5.00000 | 25.00000 | |
Foodstuffs intended for particular nutritional uses (13.0): | 10.00000 | 50.00000 | |
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | 5.00000 | 25.00000 | |
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 10.00000 | 50.00000 | |
Ready-to-eat savouries (15.0): | 20.00000 | 100.00000 | |
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | 5.00000 | 25.00000 |
European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 25, (FGE.25)[1] - Aliphatic and aromatic hydrocarbons from chemical group 31 - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food View page or View pdf |
Flavouring Group Evaluation 78 (FGE.78)[1] - Consideration of Aliphatic and alicyclic and aromatic hydrocarbons evaluated by JECFA (63rd meeting) structurally related to aliphatic and aromatic hydrocarbons evaluated by EFSA in FGE.25 - Scientific Opinion of the Panel on Food Additives,Flavourings, Processing Aids and Materials in Contact with Food (AFC) View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 25Rev1: Aliphatic and aromatic hydrocarbons from chemical group 31 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 78, Revision 1 (FGE.78Rev1): Consideration of aliphatic and alicyclic and aromatic hydrocarbons evaluated by JECFA (63rd meeting) structurally related to aliphatic and aromatic hydrocarbons evaluated by EFSA in FGE.25Rev2 View page or View pdf |
Scientific Opinion on Flavouring Group Evaluation 25, Revision 2 (FGE.25Rev2): Aliphatic and aromatic hydrocarbons from chemical group 31 View page or View pdf |
Scientific opinion on Flavouring Group Evaluation 25, Revision 3 (FGE.25Rev3): Aliphatic hydrocarbons from chemical group 31 View page or View pdf |
EPI System: View |
EPA-Iris:IRIS |
ClinicalTrials.gov:search |
Daily Med:search |
NIOSH International Chemical Safety Cards:search |
NIOSH Pocket Guide:search |
Chemical Carcinogenesis Research Information System:Search |
AIDS Citations:Search |
Cancer Citations:Search |
Toxicology Citations:Search |
Carcinogenic Potency Database:Search |
EPA GENetic TOXicology:Search |
EPA Substance Registry Services (TSCA):91-20-3 |
EPA ACToR:Toxicology Data |
EPA Substance Registry Services (SRS):Registry |
Laboratory Chemical Safety Summary :931 |
National Institute of Allergy and Infectious Diseases:Data |
SCCNFP:opinion |
WISER:UN 1334 |
WGK Germany:3 |
naphthalene |
Chemidplus:0000091203 |
EPA/NOAA CAMEO:hazardous materials |
RTECS:91-20-3 |