We have found 46587 results matching your criteria.
Please wait while we search...
  1. 1.
    General Material Information
  2. 2.
    PhysChem Properties
  3. 3.
    Occurrences
  4. 4.
    Organoleptic Properties
  5. 5.
    Suppliers
  6. 6.
    Potential Uses
  7. 7.
    Regulatory & Documentation
  8. 8.
    Safety Information
  9. 9.
    Other Information
  10. 10.
    Blenders & Components
  11. 11.
    Literature & References

ethyl (Z)-4-heptenoate

Chemical Structure

General Material Information

Preferred name ethyl (Z)-4-heptenoate
Trivial Name Ethyl (4Z)-4-heptenoate
Short Description ethyl cis-4-heptenoate
Formula C9 H16 O2
CAS Number 39924-27-1
FEMA Number 3975
Flavis Number 9.922
ECHA Number 254-702-9
FDA UNII 27Y1FYY1BV
Nikkaji Number J2.214.284D
NMR Predictor External link
JECFA Food Flavoring 1281 ethyl cis-4-heptenoate
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 39924-27-1 ; ETHYL 4-HEPTENOATE, CIS-
Synonyms
  • ethyl (4Z)-hept-4-enoate
  • ethyl (Z)-hept-4-enoate
  • ethyl cis-4-heptenoate
  • (4Z)- ethylheptenoate
  • 4-heptenoic acid, ethyl ester, (4Z)-
  • 4-heptenoic acid, ethyl ester, (Z)-
  • 4-Heptenoic acid, ethyl ester, (4Z)-
  • 4-Heptenoic acid, ethyl ester, (Z)-
  • Ethyl (4Z)-4-heptenoate

US / EU / FDA / JECFA / FEMA / Scholar / Patents

Google Scholar Start search
Google Books Start search
Google Patents Start search
Perfumer & Flavorists Start search
EU Patents Start search
PubMeb Start search
NCBI Start search

Literature & References

ethyl (Z)-hept-4-enoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:39924-27-1
Pubchem (cid):5362816
Pubchem (sid):135065001
Publications by US Patents
3,953,377 - Ethyl-2-trans-4-cis undecadienoate, ethyl-2-trans-4-cis dodecadienoate and ethyl-2-decadienoate perfume compositions

Other Information

(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
HMDB (The Human Metabolome Database):HMDB32265
FooDB:FDB009388
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View

PhysChem Properties

Material listed in food chemical codex No
Molecular weight 156.22491455078
Specific gravity @ 25 °C
Pounds per Gallon 7.381 to 7.464
Refractive Index 1.428 to 1.431 @ 20 °C
Acid Value 1 max KOH/g
Vapor Pressure 1.24 mmHg @ 25 °C
Flash Point TCC Value 57.22 °C TCC
logP (o/w) 2.896 est
Solubility
alcohol Yes
water, 158.9 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Fruity
green, apple green apple, fruity, tropical, grape skin, papaya, passion fruit, pineapple
Luebke, William tgsc, (2017) At 100.00 %. green green apple fruity tropical grape skin papaya passion fruit pineapple
Flavor Type: Fruity
fruity, passion fruit, green, tropical, apple, mango, vegetable
Luebke, William tgsc, (2017) Fruity passion fruit green tropical apple mango vegetable
General comment Bitter green apple or vegetable

Occurrences

Potential Uses

Applications
Odor purposes Fruit

Safety Information

Safety information

Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for ethyl (Z)-4-heptenoate usage levels up to:
2.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU): 3.40 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 4.00 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI): ND (μg/person/day)
Threshold of Concern:1800 (μg/person/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 20
Click here to view publication 20
average usual ppmaverage maximum ppm
baked goods: 15.0000030.00000
beverages(nonalcoholic): 8.0000012.00000
beverages(alcoholic): 8.0000012.00000
breakfast cereal: --
cheese: --
chewing gum: 40.0000080.00000
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: 10.0000015.00000
fruit ices: 8.0000012.00000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: 12.0000020.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: 10.0000015.00000
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Flavouring Group Evaluation 62 (FGE.62) Consideration of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05 (2005) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06 (2004) (Commission Regulation (EC) No 1565/2000 of 18 July 2000)
View page or View pdf

Flavouring Group Evaluation 62 Rev1 (FGE.62 Rev1): Consideration of of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st and 68th meeting) structurally related to branched- and straight-chain unsaturated carboxylic acids and esters of these with aliphatic saturated alcohols evaluated by EFSA in FGE.05Rev2 (2010) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06Rev1 (2008)
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :5362816
National Institute of Allergy and Infectious Diseases:Data
ethyl (Z)-hept-4-enoate
Chemidplus:0039924271