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General Material Information

Trivial Name spirogalbanone (Givaudan)
Short Description 4-penten-1-one, 1-spiro[4.5]dec-7-en-7-yl-
Formula C15 H22 O
CAS Number 224031-70-3
CAS Number 224031-71-4
FDA UNII Search
NMR Predictor External link
Synonyms
  • 4-penten-1-one, 1-spiro[4.5]dec-7-en-7-yl-
  • 1-spiro(4.5)-6-decen-7-yl-4-penten-1-one and 1-spiro(4.5)-7-decen-7-yl-4-penten-1-one
  • 1-spiro(4.5)-7-decen-7-yl-4-penten-1-one and 1-spiro(4.5)-6-decen-7-yl-4-penten-1-one
  • 1-( spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one

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Other Information

PhysChem Properties

Material listed in food chemical codex No
Molecular weight 218.33953857422
Boiling Point 331 to 332°C @ 760 mm Hg
Vapor Pressure 0.000153 mmHg @ 25 °C
Flash Point TCC Value 140.1 °C TCC
logP (o/w) 4.004 est
Solubility
alcohol Yes
water No

Organoleptic Properties

Odor Type: Green
green, galbanum, fruity, pineapple
General comment At 1.00 % in dipropylene glycol. green galbanum fruity pineapple
Spirogalbanone is a powerful green galbanum note, accompanied by fruit facets. As such, Spirogalbanone has the same olfactive profile as classical green galbanum molecules but it differentiates itself thanks to its outstanding substantivity. In addition to its fresh green galbanum volume, its excellent stability allows for use in all applications, especially in those where performance and substantivity are sought. Green, Galbanum, Fruity, Pineapple, Powerful
Arcadi Boix Camps wrote extensively, and enthusiastically, about Spirogalbanone in 2009. He points out that although the odour is very similar to that of materials such as Allyl Amyl Glycolate, Dynascone, Pharaone, Galbaniff and neobutenone it has the advantage that while the latter four last two or three days on a smelling strip, Spirogalbanone lasts about two weeks. This, he says, “is a supreme characteristic, a radical difference.” he goes on to point out that it “imparts an important synergistic effect” on those other materials, acting as a fixative for them. Furthermore he says it is “very clean and extremely diffusive” when compared to galbanum absolute or resinoid. Green-galbanum, fruity-pineapple. Powerful and substantive

Potential Uses

Applications
Odor purposes Green

Safety Information

Safety information

Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral (Category 5), H303
Skin corrosion/irritation (Category 3), H316
Skin sensitisation (Category 1), H317
Acute aquatic toxicity (Category 1), H400
Chronic aquatic toxicity (Category 1), H410
GHS Label elements, including precautionary statements
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Signal word Danger
Hazard statement(s)
H303 - May be harmfulif swallowed
H316 - Causes mild skin irritation
H317 - May cause an allergic skin reaction
H400 - Very toxic to aquatic life
H410 - Very toxic to aquatic life with long lasting effects
Precautionary statement(s)
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 - Wash skin thouroughly after handling.
P272 - Contaminated work clothing should not be allowed out of the workplace.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 - IF ON SKIN: wash with plenty of soap and water.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P333 + P313 - IF SKIN irritation or rash occurs: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P391 - Collect spillage. Hazardous to the aquatic environment
P501 - Dispose of contents/ container to an approved waste disposal plant.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for spirogalbanone (Givaudan) usage levels up to:
0.5000 % in the fragrance concentrate.
Recommendation for spirogalbanone (Givaudan) flavor usage levels up to:
not for flavor use.

Safety references

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):224031-70-3
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one
Chemidplus:224031703
1-(spiro[4.5]dec-6-en-7-yl)pent-4-en-1-one
Chemidplus:224031714