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ethyl 5-formyl oxydecanoate

Ethyl 5-formyl oxydecanoate is a synthetic ester flavoring agent known for imparting dairy-like flavor notes in food products.

General Material Description

Ethyl 5-formyl oxydecanoate is a synthetic organic ester with the molecular formula C13H24O4. It appears as a clear liquid and is characterized by dairy-like aromatic notes used primarily in flavor applications. This compound belongs to the class of fatty acid esters, specifically the ethyl ester of decanoic acid modified with a formyl oxy group at the 5-position. Known synonyms include decanoic acid, 5-(formyloxy)-, ethyl ester and ethyl 5-(formyloxy)decanoate. It is typically produced via chemical synthesis rather than natural extraction. Comprehensive chemical information is accessible through databases such as PubChem, supporting its identification and characterization. This compound is utilized in food flavoring formulations to enhance dairy impressions.

Occurrence, Applicability & Potential Uses

Ethyl 5-formyl oxydecanoate is employed mainly as a flavoring agent in the food industry, providing a creamy, dairy flavor note that enhances the sensory profile of various products. It is not a naturally occurring compound but is synthesized for use in formulated flavors. Its applications include addition to baked goods, dairy product analogues, beverages, confectionery frostings, and other processed foodstuffs where a rich, dairy-type aroma is desired. Regulatory evaluations, including its FEMA (US) number 4765, provide guidance on safe usage levels across multiple food categories, ensuring its appropriateness as a food additive. The compound's integration into flavor blends assists in replicating or enhancing natural dairy flavors in processed foods.

Physico-Chemical Properties Summary

Ethyl 5-formyl oxydecanoate exhibits physical and chemical properties relevant to its use in flavor formulations. It has an estimated molecular weight of approximately 244.33 g/mol and a moderate lipophilicity, indicated by its log P value around 3.5, which suggests good solubility in organic solvents such as alcohol. Its solubility in water is low, approximately 17.16 mg/L at 25 °C, which favors partitioning into lipid phases in food matrices. The compound's flash point is approximately 285 °F, reflecting its volatility under elevated temperatures. These properties influence its stability, delivery, and perception in various food systems, typically favoring fat-rich or alcoholic environments for optimal flavor release.

FAQ

What is ethyl 5-formyl oxydecanoate and what are its primary characteristics?
Ethyl 5-formyl oxydecanoate is a synthetic ester compound classified as a flavoring agent. It possesses a molecular formula of C13H24O4 and is recognized for imparting dairy-like aroma notes in food products. This compound is typically used to enhance creamy or milky sensory profiles in various applications and is produced through chemical synthesis. It is also known by several synonyms including ethyl 5-(formyloxy)decanoate. Its properties and structure make it suitable for incorporation into complex flavor blends.
How is ethyl 5-formyl oxydecanoate used and where is it commonly applied?
Ethyl 5-formyl oxydecanoate is utilized predominantly as a flavoring agent in the food industry to provide dairy-related sensory characteristics. It finds application in a range of products such as baked goods, dairy analogues, beverages (both alcoholic and non-alcoholic), confectionery frostings, and frozen dairy items. The compound is added at regulated concentrations consistent with FEMA (US) guidelines to achieve the desired flavor impact without compromising safety. Its physico-chemical properties enable its effective blending into fat-containing and alcoholic food matrices.
What regulatory standards govern the use of ethyl 5-formyl oxydecanoate and how is its safety assessed?
Ethyl 5-formyl oxydecanoate is evaluated and listed under FEMA (US) number 4765, indicating its recognition as a flavoring substance with specified safe usage limits. Regulatory assessments cover its application in various food categories with recommended maximum concentrations to ensure consumer safety. Safety data, including hazard classifications, indicate no significant hazards under OSHA HCS (29 CFR 1910). While certain toxicity data remain undetermined, expert panels have reviewed available information supporting its general recognition as safe (GRAS) status within recommended levels. Detailed references and toxicology data are accessible through authoritative databases such as EPA ACToR and PubChem.

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Other Information

General Material Information

Trivial Name ethyl 5-formyl oxydecanoate
Short Description ethyl 5-formyloxydecanoate
Formula C13 H24 O4
CAS Number 1367348-37-5
FEMA Number 4765
FDA UNII ZOI80LUX0P
xLogP3-AA 3.40 (est)
NMR Predictor External link
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
Synonyms
  • decanoic acid, 5-(formyloxy)-, ethyl ester
  • ethyl 5-(formyloxy)decanoate
  • ethyl 5-formyloxydecanoate

PhysChem Properties

Material listed in food chemical codex No
Molecular weight 244.33108520508
Flash Point TCC Value 140.3 °C TCC
logP (o/w) 3.56 est
Solubility
alcohol Yes
water, 17.16 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Flavor Type: Dairy
dairy

Safety Information

Safety information

Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavoring agents
Recommendation for ethyl 5-formyl oxydecanoate usage levels up to:
not for fragrance use.
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 26
Click here to view publication 26
average usual ppmaverage maximum ppm
baked goods: 120.00000300.00000
beverages(nonalcoholic): 5.0000050.00000
beverages(alcoholic): 5.0000050.00000
breakfast cereal: --
cheese: 10.00000100.00000
chewing gum: --
condiments / relishes: --
confectionery froastings: 5.0000050.00000
egg products: 5.0000050.00000
fats / oils: 100.00000200.00000
fish products: --
frozen dairy: 120.00000300.00000
fruit ices: --
gelatins / puddings: 120.00000300.00000
granulated sugar: --
gravies: 40.0000080.00000
hard candy: --
imitation dairy: 10.00000100.00000
instant coffee / tea: 5.0000050.00000
jams / jellies: --
meat products: --
milk products: 10.00000100.00000
nut products: 5.0000050.00000
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: 5.0000050.00000
snack foods: --
soft candy: 100.00000200.00000
soups: 5.0000050.00000
sugar substitutes: --
sweet sauces: 1.000002.00000

Safety references

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :71468629
National Institute of Allergy and Infectious Diseases:Data
ethyl 5-(formyloxy)decanoate
Chemidplus:1367348375