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petitgrain mandarin oil terpeneless

Petitgrain mandarin oil terpeneless is an essential oil derived from mandarin leaves offering fruity flavor and floral odor, used primarily in flavor and fragrance formulations.

General Material Description

Petitgrain mandarin oil terpeneless is an essential oil obtained from the leaves of Citrus reticulata blanco mandarin. It is known for its distinctive fruity flavor and floral odor profile characterized primarily by the presence of dimethyl anthranilate. The oil is recognized under various synonyms, including mandarin leaf oil terpeneless and citrus reticulata blanco var. mandarin leaf oil terpeneless. This terpeneless variant has reduced terpene content, enhancing its suitability for specific flavor and fragrance applications. It appears as a clear liquid with specific gravity ranging from 1.11 to 1.131 at 25 °C and a refractive index between 1.573 to 1.58 at 20 °C. For further chemical reference, see its controlled vocabulary entry at PubChem. The oil is mainly derived via steam distillation from mandarin leaves and is utilized widely within food-grade flavoring and perfumery sectors.

Occurrence, Applicability & Potential Uses

Petitgrain mandarin oil terpeneless occurs naturally in mandarin trees, especially in their leaves. This oil finds broad applicability in both flavor and fragrance industries as an ingredient imparting aldehydic, bergamot-like, chypre, fern, forest, neroli, and oriental aromatic characteristics. Compliance with FEMA (US) standards ensures its acceptance for use in food flavorings, while IFRA (Global) guidelines address its application in fragrances, particularly noting restrictions related to phototoxic components such as bergapten. Its utility extends to complex perfumery formulations and flavor enhancement in beverages, baked goods, and confections, among others.

Physico-Chemical Properties Summary

Petitgrain mandarin oil terpeneless exhibits physical properties influencing its formulation and stability. It has a flash point of 196 °F (approximately 91 °C), indicating moderate volatility and flammability risk; careful handling and storage below this temperature optimize safety. The oil’s specific gravity at 25 °C ranges from 1.11 to 1.131, heavier than water, which does not dissolve it, though it is soluble in alcohol and has limited solubility in water (~20 mg/L at 25 °C). Its refractive index between 1.573 and 1.58 at 20 °C aids in quality control and identification. The shelf life is typically 12 months or longer when stored properly away from heat and light, preserving its aromatic and flavor integrity. These properties necessitate consideration in formulation design, especially for fragrance blends requiring solubility and volatility balance.

FAQ

What is petitgrain mandarin oil terpeneless and how is it used?
Petitgrain mandarin oil terpeneless is an essential oil extracted from the leaves of the mandarin tree (Citrus reticulata blanco). It is characterized by a fruity flavor and floral odor profile primarily due to the compound dimethyl anthranilate. This terpeneless form has reduced amounts of terpene compounds, enhancing its stability and suitability for certain applications. It is commonly employed as a flavoring agent to impart fresh, citrusy notes and in perfumery for its aldehydic and chypre olfactory qualities.
Where does petitgrain mandarin oil terpeneless come from and what are its main characteristics?
This oil originates from mandarin leaves collected mainly through steam distillation processes. It naturally contains phototoxic furocoumarins, especially bergapten, though in controlled amounts. The oil is a clear liquid with specific gravity between 1.11 and 1.131 at 25 °C and a refractive index ranging from 1.573 to 1.58 at 20 °C. It is soluble in alcohol and exhibits limited water solubility. These physical and chemical properties influence its use in formulation, especially in flavor and fragrance products requiring particular volatility and solubility profiles.
What safety regulations govern the use of petitgrain mandarin oil terpeneless in products?
The use of petitgrain mandarin oil terpeneless is subject to safety assessments and standards such as IFRA (International Fragrance Association) and FEMA (Flavor and Extract Manufacturers Association, US). IFRA guidelines note the presence of phototoxic components, recommending usage levels not exceeding 2% in fragrance concentrates to mitigate risks. It is classified as an irritant to skin and eyes and may cause sensitization by inhalation or skin contact, necessitating protective measures during handling. Flavor uses recognize it as Generally Recognized As Safe (GRAS) at specified concentrations. Users should follow all relevant regulatory documentation and safety assessments for responsible application.

US / EU / FDA / JECFA / FEMA / Scholar / Patents

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Other Information

Export Tariff Code:3301.19.0000
Wikipedia:View

General Material Information

Preferred name petitgrain mandarin oil terpeneless
Trivial Name Petitgrain mandarin oil, leaf terpeneless
Short Description citrus reticulata blanco mandarin leaf oil terpeneless
CAS Number 8014-17-3
FEMA Number 2854
FDA UNII Search
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 977051-67-4 ; PETITGRAIN, MANDARIN, OIL (CITRUS RETICULATA BLANCO VAR. MANDARIN)
Synonyms
  • citrus reticulata blanco mandarin leaf oil terpeneless
  • citrus reticulata blanco var. mandarin leaf oil terpeneless
  • mandarin oil petitgrain terpeneless natural
  • oil mandarin petitgrain terpeneless (natural dimethyl anthranilate 98%)
  • mandarin petitgrain oil terpeneless
  • Petitgrain oil
  • Oils, petitgrain
  • Essential oils, orange, sour
  • Oils, essential, orange, sour
  • Essential oils, Citrus bigaradia
  • Oil of Pettitgrain
  • Mandarin petitgrain oil
  • Petitgrain mandarin oil
  • Orange leaf water
  • Bitter orange oil
  • Orange oil
  • FG 8855
  • Essential oils, orange
  • Bitter orange oils
  • Citrus bigaradia oil
  • Citrus oils, Citrus bigaradia
  • Petitgrain oil, Paraguay

PhysChem Properties

Material listed in food chemical codex No
Specific gravity @ 25 °C
Pounds per Gallon 9.236 to 9.411
Refractive Index 1.573 to 1.58 @ 20 °C
Flash Point TCC Value 91.11 °C TCC
Shelf life 12 months (or longer if stored properly.)
Solubility
alcohol Yes
water, 20.12 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Floral
mandarin, grape
General comment At 100.00 %. dimethyl anthranilate grape
Flavor Type: Fruity
petitgrain, mandarin
General comment Petitgrain

Occurrences

Potential Uses

Applications
Odor purposes Aldehydic , Bergamot , Chypre , Fern , Forest , Neroli , Oriental

Safety Information

Safety information

European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
R 42/43 - May cause sensitization by inhalation and skin contact.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 - Wear suitable gloves and eye/face protection.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 > 5000 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 101S, 1992.

Dermal Toxicity:
skin-rabbit LD50 > 2000 mg/kg
Food and Chemical Toxicology. Vol. 30, Pg. 101S, 1992.

Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
IFRA Critical Effect:
Phototoxicity
IFRA fragrance material specification:
The following essential oils contain small amounts of phototoxic furocoumarins. These levels are not high enough to require special restrictions if used alone, but if used in combination with one or the other phototoxic essential oil, attention should be paid that the total level of bergapten (5-MOP) in the consumer product does not exceed 15 ppm. It is the responsibility of fragrance manufacturers to ensure that the level is observed. Typical levels of 5-MOP are the following: Petitgrain Mandarin oil - 50 ppm.
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
methyl N-methyl anthranilate Max. Found: 80.00 % and Reason: Phototoxicity and potential for nitrosamine formation
citral Max. Found: 0.16 % and Reason: Sensitization
citronellal Max. Found: 0.1 % and Reason: Sensitization
Recommendation for petitgrain mandarin oil terpeneless usage levels up to:
2.0000 % in the fragrance concentrate.
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -11.00000
beverages(nonalcoholic): -4.30000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -4.10000
fruit ices: -4.10000
gelatins / puddings: -0.43000
granulated sugar: --
gravies: --
hard candy: -4.50000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):8014-17-3
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
citrus reticulata blanco var. mandarin leaf oil terpeneless
Chemidplus:0008014173