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General Material Information

Preferred name bitter orange peel oil terpeneless
Trivial Name Oils, orange, sour, terpene-free
Short Description bitter citrus aurantium peel oil terpeneless
CAS Number 68916-02-9
FEMA Number 2823
FDA UNII Search
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 68916-04-1 ; ORANGE PEEL, BITTER, OIL (CITRUS AURANTIUM L.)
Synonyms
  • bitter citrus aurantium peel oil terpeneless
  • oil bitter orange terpeneless extra
  • orange bitter terpeneless
  • bitter orange peel oil bitter terpeneless
  • Oils, orange, sour, terpene-free

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Other Information

Export Tariff Code:3301.12.0000
Wikipedia:View

PhysChem Properties

Material listed in food chemical codex No
Specific gravity @ 25 °C
Pounds per Gallon 7.256 to 7.339
Refractive Index 1.4645 to 1.4745 @ 20 °C
Flash Point TCC Value 76.67 °C TCC
Solubility
alcohol Yes
water, 1860 mg/L @ 25 °C (est) Yes
Stability
soap Unspecified

Organoleptic Properties

Odor Type: Citrus
sweet, juicy, floral, aldehydic, orange, woody, orange bitter orange
General comment At 100.00 %. sweet juicy floral aldehydic orange
Mosciano, Gerard P&F 18, No. 6, 33, (1993) Sweet, juicy, floral, aldehydic orange with woody citron nuances
Flavor Type: Citrus
sweet, juicy, peely, aldehydic, floral
Mosciano, Gerard P&F 18, No. 6, 33, (1993) At 50.00 ppm. Sweet, juicy, peely, with aldehydic and floral nuances

Occurrences

Potential Uses

Applications
Odor purposes Aldehydic, Amber, Bergamot, Citrus, Fern, Floral, Grapefruit, Green, Orange, Oriental, Violet, Woody
Flavoring purposes Tea, Wine madeira wine
Other purposes Fixer, Leaf

Safety Information

Safety information

European information :
Most important hazard(s):
Xi - Irritant
R 38 - Irritating to skin.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
IFRA Critical Effect:
Phototoxicity
IFRA fragrance material specification:
Where the bergapten (5-methoxypsoralen) content of all relevant oils present in a compound has been determined, it is recommended that for applications on areas of skin exposed to sunshine, excluding bath preparations, soaps and other products which are washed off the skin, the total level of bergapten in the consumer products should not exceed 0.0015% (15 ppm). This is equivalent to 0.0075% (75 ppm) in a fragrance compound used at 20% in the consumer product. Where the level of bergapten has not been determined by appropriate methods, the limits specified in the guidelines on individual oils should apply. In those cases, where such oils are used in combination with other phototoxic ingredients, the additive effect has to be taken into consideration and the use levels have to be reduced accordingly. The sum of the concentrations of all phototoxic fragrance ingredients, expressed in % of their recommended maximum level in the consumer product, shall not exceed 100.
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
citral Max. Found: 10.00 % and Reason: Sensitization
limits in the finished product for - "leave on the skin contact":
1.2500 % Restriction.
Recommendation for bitter orange peel oil terpeneless usage levels up to:
5.0000 % in the fragrance concentrate.
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -110.00000
beverages(nonalcoholic): -67.00000
beverages(alcoholic): -4.00000
breakfast cereal: --
cheese: --
chewing gum: -500.00000
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -71.00000
fruit ices: -71.00000
gelatins / puddings: -300.00000
granulated sugar: --
gravies: --
hard candy: -150.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

EPI System: View
EPA Substance Registry Services (TSCA):68916-02-9
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
citrus aurantium l. peel oil bitter terpeneless
Chemidplus:0068916029