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General Material Information

Preferred name terpeneless mandarin oil
Trivial Name Oils, mandarin, terpene-free
Short Description citrus reticulata blanco var. mandarin oil terpeneless
CAS Number 68917-20-4
FEMA Number 2718
FDA UNII Search
MDL MFCD00017183
FDA Patent No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm 8008-31-9 ; MANDARIN, OIL (CITRUS RETICULATA BLANCO)
Synonyms
  • citrus reticulata blanco var. mandarin oil terpeneless
  • dimethyl anthranilate natural (mandarin oil terpeneless)
  • mandarin oil terpeneless
  • Oils, mandarin, terpene-free

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Other Information

PhysChem Properties

Material listed in food chemical codex No
Melting Point 16 to 19°C @ 760 mm Hg
Boiling Point 253 to 255°C @ 760 mm Hg
Flash Point TCC Value 110 °C TCC
logP (o/w) 2.81
Solubility
alcohol Yes
water, 257 mg/L @ 25 °C (est) Yes
water No

Organoleptic Properties

Odor Type: Floral
mandarin
General comment At 100.00 %. dimethyl anthranilate mandarin
Flavor Type: Citrus
mandarin
General comment Mandarin

Occurrences

Safety Information

Safety information

European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
Hazards identification
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
Pictogram
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 3380 mg/kg

intravenous-mouse LD50 180 mg/kg

Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in use information

Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
IFRA Critical Effect:
Phototoxicity
IFRA fragrance material specification:
The following essential oils contain small amounts of phototoxic furocoumarins. These levels are not high enough to require special restrictions if used alone, but if used in combination with one or the other phototoxic essential oil, attention should be paid that the total level of bergapten (5-MOP) in the consumer product does not exceed 15 ppm. It is the responsibility of fragrance manufacturers to ensure that the level is observed. Typical levels of 5-MOP are the following: Mandarin oil cold pressed - 250 ppm.
contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only)
citral Max. Found: 10.5 % and Reason: Sensitization
geraniol Max. Found: 0.2 % and Reason: Sensitization
dimethyl anthranilate Max. Found: 10.00 % and Reason: Phototoxicity and potential for nitrosamine formation
citronellal Max. Found: 3.00 % and Reason: Sensitization
Recommendation for terpeneless mandarin oil usage levels up to:
5.0000 % in the fragrance concentrate.
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
average usual ppmaverage maximum ppm
baked goods: -17.00000
beverages(nonalcoholic): -5.10000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -5.00000
fruit ices: -5.00000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -18.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: -4.00000
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --

Safety references

European Food Safety Authority (EFSA) reference(s):

Safety and efficacy of a feed additive consisting of expressed mandarin oil from the fruit peels of Citrus reticulata Blanco for use in all animal species (FEFANA asbl)
View page or View pdf

EPI System: View
Chemical Carcinogenesis Research Information System:Search
EPA Substance Registry Services (TSCA):68917-20-4
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:1
citrus reticulata blanco var. mandarin oil terpeneless
Chemidplus:0068917204